DOI: 10.1002/bbpc.19750790111. The Influence of Chemical Exchange on NMR Spin Lattice Relaxation

The Influence of Chemical Exchange on NMR Spin Lattice Relaxation

10.1002/bbpc.19750790111

Crossref journal-article

Wiley

Berichte der Bunsengesellschaft für physikalische Chemie (311)

Abstract

AbstractA method is presented for the determination of chemical rate constants from spin‐lattice relaxation times T1. The exchange rate of water molecules between the inner‐hydration sphere of nickel ions and the bulk has thus been obtained in Ni(NO3)2 solutions. The results indicate a nitrate inner‐sphere complex with a stability constant of about 0.2 M−1. The ratio of the Ni2+ ion‐water proton distances in the first and second hydration layers is estimated. A combined T1 — T2 technique is proposed which improves the accuracy of the measurement of fast chemical reactions.

Bibliography

Strehlow, H., & Frahm, J. (1975). The Influence of Chemical Exchange on NMR Spin Lattice Relaxation. Berichte Der Bunsengesellschaft FÃ¼r Physikalische Chemie, 79(1), 57â62. Portico.

Authors 2

H. Strehlow (first)
J. Frahm (additional)

References 24 Referenced 27

10.1063/1.1734254
10.1063/1.1726215
10.1063/1.1696165
10.1016/0022-2364(71)90040-0
10.1016/0022-2364(73)90046-2
J.Jen Dissertation Göttingen1973;
10.1016/0001-8716(74)80009-X
10.1016/B978-1-4832-3114-3.50008-8
{'key': 'e_1_2_1_6_3', 'first-page': '521', 'volume-title': 'Techniques of Chemistry', 'author': 'Swift T. J.', 'year': '1974'} / Techniques of Chemistry by Swift T. J. (1974)
10.1063/1.1744152
10.1016/0001-8716(74)80014-3
10.1063/1.1734121
10.1063/1.1725295
{'key': 'e_1_2_1_10_2', 'first-page': '63', 'volume-title': 'Techniques of Chemistry', 'author': 'Eigen M.', 'year': '1974'} / Techniques of Chemistry by Eigen M. (1974)
10.1002/bbpc.19630670911
10.1002/ijch.197300043
{'key': 'e_1_2_1_11_2', 'volume-title': 'Stability Constants of Metal‐Ion Complexes', 'author': 'Sillén G. L.', 'year': '1964'} / Stability Constants of Metal‐Ion Complexes by Sillén G. L. (1964)
{'key': 'e_1_2_1_11_3', 'volume-title': 'Stability Constants of Metal‐Ion Complexes', 'year': '1971'} / Stability Constants of Metal‐Ion Complexes (1971)
10.1063/1.1726589
W.Knoche to be published.
10.1351/pac196920010093
10.1063/1.1725581
10.1080/10739147108543300
{'key': 'e_1_2_1_17_2', 'first-page': '1157', 'volume-title': 'Magnetic Resonance and Relaxation', 'author': 'Fiat D.', 'year': '1967'} / Magnetic Resonance and Relaxation by Fiat D. (1967)

Dates

Type	When
Created	13 years ago (Sept. 4, 2012, 10:36 a.m.)
Deposited	1 year, 10 months ago (Oct. 19, 2023, 10:49 a.m.)
Indexed	1 year, 7 months ago (Jan. 17, 2024, 5:39 a.m.)
Issued	50 years, 8 months ago (Jan. 1, 1975)
Published	50 years, 8 months ago (Jan. 1, 1975)
Published Online	15 years, 4 months ago (May 5, 2010)
Published Print	50 years, 8 months ago (Jan. 1, 1975)

Funders 0

None

BibTeX

@article{Strehlow_1975, title={The Influence of Chemical Exchange on NMR Spin Lattice Relaxation}, volume={79}, ISSN={0005-9021}, url={http://dx.doi.org/10.1002/bbpc.19750790111}, DOI={10.1002/bbpc.19750790111}, number={1}, journal={Berichte der Bunsengesellschaft für physikalische Chemie}, publisher={Wiley}, author={Strehlow, H. and Frahm, J.}, year={1975}, month=jan, pages={57–62} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        1,
        17
      ]
    ],
    "date-time": "2024-01-17T10:39:01Z",
    "timestamp": 1705487941262
  },
  "reference-count": 24,
  "publisher": "Wiley",
  "issue": "1",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2010,
            5,
            5
          ]
        ],
        "date-time": "2010-05-05T00:00:00Z",
        "timestamp": 1273017600000
      },
      "content-version": "vor",
      "delay-in-days": 12908,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1975,
        1
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>A method is presented for the determination of chemical rate constants from spin\u2010lattice relaxation times <jats:italic>T</jats:italic><jats:sub>1</jats:sub>. The exchange rate of water molecules between the inner\u2010hydration sphere of nickel ions and the bulk has thus been obtained in Ni(NO<jats:sub>3</jats:sub>)<jats:sub>2</jats:sub> solutions. The results indicate a nitrate inner\u2010sphere complex with a stability constant of about 0.2 M<jats:sup>\u22121</jats:sup>. The ratio of the Ni<jats:sup>2+</jats:sup> ion\u2010water proton distances in the first and second hydration layers is estimated. A combined <jats:italic>T</jats:italic><jats:sub>1</jats:sub> \u2014 <jats:italic>T</jats:italic><jats:sub>2</jats:sub> technique is proposed which improves the accuracy of the measurement of fast chemical reactions.</jats:p>",
  "DOI": "10.1002/bbpc.19750790111",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2012,
        9,
        4
      ]
    ],
    "date-time": "2012-09-04T14:36:12Z",
    "timestamp": 1346769372000
  },
  "page": "57-62",
  "source": "Crossref",
  "is-referenced-by-count": 27,
  "title": "The Influence of Chemical Exchange on NMR Spin Lattice Relaxation",
  "prefix": "10.1002",
  "volume": "79",
  "author": [
    {
      "given": "H.",
      "family": "Strehlow",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "J.",
      "family": "Frahm",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2010,
        5,
        5
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_1_2_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1734254"
    },
    {
      "key": "e_1_2_1_2_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1726215"
    },
    {
      "key": "e_1_2_1_2_4",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1696165"
    },
    {
      "key": "e_1_2_1_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-2364(71)90040-0"
    },
    {
      "key": "e_1_2_1_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-2364(73)90046-2"
    },
    {
      "key": "e_1_2_1_5_2",
      "unstructured": "J.Jen Dissertation G\u00f6ttingen1973;"
    },
    {
      "key": "e_1_2_1_5_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0001-8716(74)80009-X"
    },
    {
      "key": "e_1_2_1_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/B978-1-4832-3114-3.50008-8"
    },
    {
      "key": "e_1_2_1_6_3",
      "first-page": "521",
      "volume-title": "Techniques of Chemistry",
      "author": "Swift T. J.",
      "year": "1974"
    },
    {
      "key": "e_1_2_1_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1744152"
    },
    {
      "key": "e_1_2_1_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0001-8716(74)80014-3"
    },
    {
      "key": "e_1_2_1_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1734121"
    },
    {
      "key": "e_1_2_1_9_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1725295"
    },
    {
      "key": "e_1_2_1_10_2",
      "first-page": "63",
      "volume-title": "Techniques of Chemistry",
      "author": "Eigen M.",
      "year": "1974"
    },
    {
      "key": "e_1_2_1_10_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/bbpc.19630670911"
    },
    {
      "key": "e_1_2_1_10_4",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ijch.197300043"
    },
    {
      "key": "e_1_2_1_11_2",
      "volume-title": "Stability Constants of Metal\u2010Ion Complexes",
      "author": "Sill\u00e9n G. L.",
      "year": "1964"
    },
    {
      "key": "e_1_2_1_11_3",
      "volume-title": "Stability Constants of Metal\u2010Ion Complexes",
      "year": "1971"
    },
    {
      "key": "e_1_2_1_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1726589"
    },
    {
      "key": "e_1_2_1_13_2",
      "unstructured": "W.Knoche to be published."
    },
    {
      "key": "e_1_2_1_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1351/pac196920010093"
    },
    {
      "key": "e_1_2_1_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1725581"
    },
    {
      "key": "e_1_2_1_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1080/10739147108543300"
    },
    {
      "key": "e_1_2_1_17_2",
      "first-page": "1157",
      "volume-title": "Magnetic Resonance and Relaxation",
      "author": "Fiat D.",
      "year": "1967"
    }
  ],
  "container-title": "Berichte der Bunsengesellschaft f\u00fcr physikalische Chemie",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fbbpc.19750790111",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/bbpc.19750790111",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        19
      ]
    ],
    "date-time": "2023-10-19T14:49:31Z",
    "timestamp": 1697726971000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/bbpc.19750790111"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1975,
        1
      ]
    ]
  },
  "references-count": 24,
  "journal-issue": {
    "issue": "1",
    "published-print": {
      "date-parts": [
        [
          1975,
          1
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/bbpc.19750790111"
  ],
  "URL": "http://dx.doi.org/10.1002/bbpc.19750790111",
  "relation": {},
  "ISSN": [
    "0005-9021",
    "0005-9021"
  ],
  "subject": [],
  "container-title-short": "Ber Bunsenges Phys Chem",
  "published": {
    "date-parts": [
      [
        1975,
        1
      ]
    ]
  }
}