DOI: 10.1002/bbpc.19730770209. Nuclear Magnetic Relaxation Study of Glycerol

Nuclear Magnetic Relaxation Study of Glycerol

10.1002/bbpc.19730770209

Crossref journal-article

Wiley

Berichte der Bunsengesellschaft für physikalische Chemie (311)

Abstract

AbstractUsing isotopic dilution experiments the intramolecular and intermolecular contributions to the proton nuclear magnetic relaxation rate in glycerol were determined separately at frequencies between 6 MHz and 180 MHz and at temperatures between ‐ 20°C and + 72 ° C. Also some deuteron relaxation rates in glycerol‐d3were measured at 6 MHz and comparable temperatures.The intramolecular and intermolecular proton relaxation rates are of similar magnitude but show different frequency dependence. The former contribution can be rationalized on the basis of a Cole‐Davidson distribution of rotational correlation times, as is customary in dielectric relaxation studies, and close agreement with dielectric results is found. The intermolecular proton relaxation rate on the other hand could not be explained satisfactorily on the basis of Torrey's theory, using independently measured translational self‐diffusion constants.

Bibliography

Kintzinger, J. P., & Zeidler, M. D. (1973). Nuclear Magnetic Relaxation Study of Glycerol. Berichte Der Bunsengesellschaft FÃ¼r Physikalische Chemie, 77(2), 98â103. Portico.

Authors 2

J. P. Kintzinger (first)
M. D. Zeidler (additional)

References 26 Referenced 54

10.1103/PhysRev.73.679
10.1515/zna-1969-0117 / Z. Naturforsch. by Noack F. (1969)
10.1063/1.1675291
10.1063/1.1677909
10.1007/BF01402653
10.1063/1.1678389
10.1007/BF02033317
{'key': 'e_1_2_1_9_2', 'first-page': '363', 'volume': '6', 'author': 'Eisner M.', 'year': '1961', 'journal-title': 'Bull. Amer. physic. Soc.'} / Bull. Amer. physic. Soc. by Eisner M. (1961)
10.1063/1.1695665
10.1002/bbpc.19650690803
10.1080/00268976600100201
C. S.MinerandN. N.Dalton Glycerol New York1953.
10.1002/bbpc.19710750308
10.1063/1.1748105
10.1145/362705.362714
10.1063/1.1733360
10.3891/acta.chem.scand.03-0415
10.1063/1.1726072
E. A. C.Lucken Nuclear Quadrupole Coupling Constants New York1969.
10.1002/bbpc.19690730105 / Ber. Bunsenges. physik. Chem. by v. Goldammer E. (1970)
10.1103/PhysRev.92.962
10.1103/PhysRev.131.275
10.1139/p61-093
10.1103/PhysRev.182.400
10.1002/bbpc.19710750812
D. J.Tomlinson Molecular Physics (to be published).

Dates

Type	When
Created	1 year, 9 months ago (Nov. 13, 2023, 5:37 p.m.)
Deposited	1 year, 7 months ago (Dec. 25, 2023, 2:22 p.m.)
Indexed	11 months, 1 week ago (Sept. 14, 2024, 12:30 a.m.)
Issued	52 years, 6 months ago (Feb. 1, 1973)
Published	52 years, 6 months ago (Feb. 1, 1973)
Published Online	15 years, 3 months ago (May 5, 2010)
Published Print	52 years, 6 months ago (Feb. 1, 1973)

Funders 0

None

BibTeX

@article{Kintzinger_1973, title={Nuclear Magnetic Relaxation Study of Glycerol}, volume={77}, ISSN={0005-9021}, url={http://dx.doi.org/10.1002/bbpc.19730770209}, DOI={10.1002/bbpc.19730770209}, number={2}, journal={Berichte der Bunsengesellschaft für physikalische Chemie}, publisher={Wiley}, author={Kintzinger, J. P. and Zeidler, M. D.}, year={1973}, month=feb, pages={98–103} }

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