DOI: 10.1002/bbpc.19710751108. Molecular Motion and Structure around the Hydrated Ions Li<sup>+</sup>and Al<sup>3+</sup>

Molecular Motion and Structure around the Hydrated Ions Li+and Al3+

10.1002/bbpc.19710751108

Crossref journal-article

Wiley

Berichte der Bunsengesellschaft für physikalische Chemie (311)

Abstract

AbstractExperimental results for the nuclear magnetic relaxation rate of Li7in H2O and D2O solutions of LiCl, LiBr, and LiI are reported. The relaxation contribution due to magnetic dipole‐dipole interaction is separated, the rotational correlation time of the vector connecting the cation with the 1st hydration water is determined and the latter time is compared with the correlation time of the H – H vector in H2O of the 1st hydration sphere. Both times are not equal which indicates that the water molecules rotates about the Li – O axis. The quadrupolar contribution to the relaxation rate of Li7is interpreted in terms of a break‐down of cubic symmetry in the hydration sphere as the salt concentration increases. Self‐diffusion data of Li+in LiCl, LiBr, and LiI solutions are as well reported and a structural interpretation of the concentration dependence is given.Proton relaxation rates of AlCl3solutions containing 100% H2O and of those which contain only a very small amount of HDO in D2O are given. The evaluation yields the result that the correlation times of the two vectors in the hydration sphere as described above are equal for Al3+. Some structural consequences are described, proton relaxation rates in Ga3+solutions, Al27relaxation rates in AlCl3solutions, and water self‐diffusion coefficients in AlCl3solutions are reported.

Bibliography

Hertz, H. G., Tutsch, R., & Versmold, H. (1971). Molecular Motion and Structure around the Hydrated Ions Li+and Al3+. Berichte Der Bunsengesellschaft FÃ¼r Physikalische Chemie, 75(11), 1177â1191. Portico.

Authors 3

H. G. Hertz (first)
R. Tutsch (additional)
H. Versmold (additional)

References 40 Referenced 81

10.1063/1.1734442
10.1063/1.1712118
10.1063/1.1669674
10.1063/1.1725738
T. L.Hill Statistical Mechanics New York Toronto London1956.
10.1002/bbpc.19710750615
10.1080/00268976700101161
10.1080/00268976800100341
10.1039/tf9635901972
10.1063/1.1669832
10.1139/p67-202
H. G.Hertz G.Stalidis andH.Versmold J. Chim. physique numéro spécial Octobre 177 (1969). (10.1051/jcp/196966s20177)
10.1063/1.1671882
{'key': 'e_1_2_1_14_2', 'first-page': '1223', 'volume': '36', 'author': 'Bakulin E. A.', 'year': '1962', 'journal-title': 'Russ. J. physic. Chem.'} / Russ. J. physic. Chem. by Bakulin E. A. (1962)
10.1063/1.1726873
10.1021/j100842a058
10.1002/bbpc.19670710907
10.1002/bbpc.19630670807
10.1063/1.1670960
10.1002/bbpc.19670710908
10.1002/bbpc.19690730609
10.1002/bbpc.19710750303
10.1063/1.1744159
10.1002/bbpc.19670710906
10.1063/1.1671819
10.1515/zna-1967-0925 / Z. Naturforsch. by Berthold I. (1967)
10.1002/bbpc.19690730105 / Ber. Bunsenges. physik. Chem. by v. Goldammer E. (1969)
10.1016/0079-6565(67)80015-3
10.1021/j100890a034
B.Brun Thesis Montpellier1967.
See e.g.E. A. C.Lucken Nuclear Quadrupole Coupling Constants London New York1969.
10.1016/S0081-1947(08)60105-8
10.1002/bbpc.19610650104
H. G.Hertz R.Klute G.Stalidis andH.Versmold Ber. Bunsenges. physik. Chem. to be published.
H. G.HertzandH.Versmold Ber. Bunsenges. physik. Chem. to be published.
10.1103/PhysRev.101.511
{'key': 'e_1_2_1_37_2', 'first-page': '38', 'volume-title': 'Crystal Structure', 'author': 'Wyckhoff R. W. G.', 'year': '1960'} / Crystal Structure by Wyckhoff R. W. G. (1960)
10.1007/BF01387090
10.1063/1.1732274
10.1021/ja01005a009

Dates

Type	When
Created	9 years, 8 months ago (Dec. 16, 2015, 9:29 p.m.)
Deposited	1 year, 2 months ago (June 13, 2024, 12:10 a.m.)
Indexed	1 week, 1 day ago (Aug. 29, 2025, 6:08 a.m.)
Issued	53 years, 10 months ago (Nov. 1, 1971)
Published	53 years, 10 months ago (Nov. 1, 1971)
Published Online	15 years, 4 months ago (May 4, 2010)
Published Print	53 years, 10 months ago (Nov. 1, 1971)

Funders 0

None

BibTeX

@article{Hertz_1971, title={Molecular Motion and Structure around the Hydrated Ions Li+and Al3+}, volume={75}, ISSN={0005-9021}, url={http://dx.doi.org/10.1002/bbpc.19710751108}, DOI={10.1002/bbpc.19710751108}, number={11}, journal={Berichte der Bunsengesellschaft für physikalische Chemie}, publisher={Wiley}, author={Hertz, H. G. and Tutsch, R. and Versmold, H.}, year={1971}, month=nov, pages={1177–1191} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        29
      ]
    ],
    "date-time": "2025-08-29T10:08:55Z",
    "timestamp": 1756462135032
  },
  "reference-count": 40,
  "publisher": "Wiley",
  "issue": "11",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2010,
            5,
            4
          ]
        ],
        "date-time": "2010-05-04T00:00:00Z",
        "timestamp": 1272931200000
      },
      "content-version": "vor",
      "delay-in-days": 14064,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        1971,
        11
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>Experimental results for the nuclear magnetic relaxation rate of Li<jats:sup>7</jats:sup>in H<jats:sub>2</jats:sub>O and D<jats:sub>2</jats:sub>O solutions of LiCl, LiBr, and LiI are reported. The relaxation contribution due to magnetic dipole\u2010dipole interaction is separated, the rotational correlation time of the vector connecting the cation with the 1st hydration water is determined and the latter time is compared with the correlation time of the H \u2013 H vector in H<jats:sub>2</jats:sub>O of the 1st hydration sphere. Both times are not equal which indicates that the water molecules rotates about the Li \u2013 O axis. The quadrupolar contribution to the relaxation rate of Li<jats:sup>7</jats:sup>is interpreted in terms of a break\u2010down of cubic symmetry in the hydration sphere as the salt concentration increases. Self\u2010diffusion data of Li<jats:sup>+</jats:sup>in LiCl, LiBr, and LiI solutions are as well reported and a structural interpretation of the concentration dependence is given.</jats:p><jats:p>Proton relaxation rates of AlCl<jats:sub>3</jats:sub>solutions containing 100% H<jats:sub>2</jats:sub>O and of those which contain only a very small amount of HDO in D<jats:sub>2</jats:sub>O are given. The evaluation yields the result that the correlation times of the two vectors in the hydration sphere as described above are equal for Al<jats:sup>3+</jats:sup>. Some structural consequences are described, proton relaxation rates in Ga<jats:sup>3+</jats:sup>solutions, Al<jats:sup>27</jats:sup>relaxation rates in AlCl<jats:sub>3</jats:sub>solutions, and water self\u2010diffusion coefficients in AlCl<jats:sub>3</jats:sub>solutions are reported.</jats:p>",
  "DOI": "10.1002/bbpc.19710751108",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2015,
        12,
        17
      ]
    ],
    "date-time": "2015-12-17T02:29:15Z",
    "timestamp": 1450319355000
  },
  "page": "1177-1191",
  "source": "Crossref",
  "is-referenced-by-count": 81,
  "title": "Molecular Motion and Structure around the Hydrated Ions Li<sup>+</sup>and Al<sup>3+</sup>",
  "prefix": "10.1002",
  "volume": "75",
  "author": [
    {
      "given": "H. G.",
      "family": "Hertz",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "R.",
      "family": "Tutsch",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "H.",
      "family": "Versmold",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2010,
        5,
        4
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_1_2_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1734442"
    },
    {
      "key": "e_1_2_1_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1712118"
    },
    {
      "key": "e_1_2_1_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1669674"
    },
    {
      "key": "e_1_2_1_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1725738"
    },
    {
      "key": "e_1_2_1_6_2",
      "unstructured": "T. L.Hill Statistical Mechanics New York Toronto London1956."
    },
    {
      "key": "e_1_2_1_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/bbpc.19710750615"
    },
    {
      "key": "e_1_2_1_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1080/00268976700101161"
    },
    {
      "key": "e_1_2_1_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1080/00268976800100341"
    },
    {
      "key": "e_1_2_1_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/tf9635901972"
    },
    {
      "key": "e_1_2_1_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1669832"
    },
    {
      "key": "e_1_2_1_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1139/p67-202"
    },
    {
      "key": "e_1_2_1_13_2",
      "doi-asserted-by": "crossref",
      "unstructured": "H. G.Hertz G.Stalidis andH.Versmold J. Chim. physique num\u00e9ro sp\u00e9cial Octobre 177 (1969).",
      "DOI": "10.1051/jcp/196966s20177"
    },
    {
      "key": "e_1_2_1_13_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1671882"
    },
    {
      "key": "e_1_2_1_14_2",
      "first-page": "1223",
      "volume": "36",
      "author": "Bakulin E. A.",
      "year": "1962",
      "journal-title": "Russ. J. physic. Chem."
    },
    {
      "key": "e_1_2_1_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1726873"
    },
    {
      "key": "e_1_2_1_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100842a058"
    },
    {
      "key": "e_1_2_1_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/bbpc.19670710907"
    },
    {
      "key": "e_1_2_1_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/bbpc.19630670807"
    },
    {
      "key": "e_1_2_1_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1670960"
    },
    {
      "key": "e_1_2_1_20_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/bbpc.19670710908"
    },
    {
      "key": "e_1_2_1_21_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/bbpc.19690730609"
    },
    {
      "key": "e_1_2_1_22_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/bbpc.19710750303"
    },
    {
      "key": "e_1_2_1_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1744159"
    },
    {
      "key": "e_1_2_1_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/bbpc.19670710906"
    },
    {
      "key": "e_1_2_1_25_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1671819"
    },
    {
      "key": "e_1_2_1_26_2",
      "doi-asserted-by": "crossref",
      "first-page": "1433",
      "DOI": "10.1515/zna-1967-0925",
      "volume": "22",
      "author": "Berthold I.",
      "year": "1967",
      "journal-title": "Z. Naturforsch."
    },
    {
      "key": "e_1_2_1_27_2",
      "doi-asserted-by": "crossref",
      "first-page": "4",
      "DOI": "10.1002/bbpc.19690730105",
      "volume": "73",
      "author": "v. Goldammer E.",
      "year": "1969",
      "journal-title": "Ber. Bunsenges. physik. Chem."
    },
    {
      "key": "e_1_2_1_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0079-6565(67)80015-3"
    },
    {
      "key": "e_1_2_1_29_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100890a034"
    },
    {
      "key": "e_1_2_1_30_2",
      "unstructured": "B.Brun Thesis Montpellier1967."
    },
    {
      "key": "e_1_2_1_31_2",
      "unstructured": "See e.g.E. A. C.Lucken Nuclear Quadrupole Coupling Constants London New York1969."
    },
    {
      "key": "e_1_2_1_32_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0081-1947(08)60105-8"
    },
    {
      "key": "e_1_2_1_33_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/bbpc.19610650104"
    },
    {
      "key": "e_1_2_1_34_2",
      "unstructured": "H. G.Hertz R.Klute G.Stalidis andH.Versmold Ber. Bunsenges. physik. Chem. to be published."
    },
    {
      "key": "e_1_2_1_35_2",
      "unstructured": "H. G.HertzandH.Versmold Ber. Bunsenges. physik. Chem. to be published."
    },
    {
      "key": "e_1_2_1_36_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRev.101.511"
    },
    {
      "key": "e_1_2_1_37_2",
      "first-page": "38",
      "volume-title": "Crystal Structure",
      "author": "Wyckhoff R. W. G.",
      "year": "1960"
    },
    {
      "key": "e_1_2_1_38_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/BF01387090"
    },
    {
      "key": "e_1_2_1_39_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1732274"
    },
    {
      "key": "e_1_2_1_40_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja01005a009"
    }
  ],
  "container-title": "Berichte der Bunsengesellschaft f\u00fcr physikalische Chemie",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "http://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fbbpc.19710751108",
      "content-type": "application/pdf",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fbbpc.19710751108",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/bbpc.19710751108",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        6,
        13
      ]
    ],
    "date-time": "2024-06-13T04:10:14Z",
    "timestamp": 1718251814000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/bbpc.19710751108"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        1971,
        11
      ]
    ]
  },
  "references-count": 40,
  "journal-issue": {
    "issue": "11",
    "published-print": {
      "date-parts": [
        [
          1971,
          11
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/bbpc.19710751108"
  ],
  "URL": "http://dx.doi.org/10.1002/bbpc.19710751108",
  "relation": {},
  "ISSN": [
    "0005-9021",
    "0005-9021"
  ],
  "subject": [],
  "container-title-short": "Ber Bunsenges Phys Chem",
  "published": {
    "date-parts": [
      [
        1971,
        11
      ]
    ]
  }
}