DOI: 10.1002/bbpc.19690730504. Permittivity and dielectric relaxation of aqueous solutions of hydrocarbons

Permittivity and dielectric relaxation of aqueous solutions of hydrocarbons

10.1002/bbpc.19690730504

Crossref journal-article

Wiley

Berichte der Bunsengesellschaft für physikalische Chemie (311)

Abstract

AbstractThe solutes are hydrogen bond forming, mostly non‐polar non‐electrolytes (heterocyclic hydrocarbons). ‐ From the permittivities measured in dependence of frequency between 1.5 and 38 GHz at 25 °C are derived values of the static permittivity, of the dielectric principal relaxation time, and of the relaxation time distribution parameter of the solutions. For evaluating these data simple models of the solutions are introduced.An analysis of the static permittivities of the solutions shows that the orientational polarizability of the hydration water does not markedly differ from that of pure water.From the changes of the relaxation times and of the relaxation time distribution parameters with the solute concentrations are estimated the increased reorientation times and the numbers of the dynamically disturbed water molecules around the solute particles. The reorientation times are discussed with respect to the hydration of the second kind and are compared with viscosity data.In all considerations are also included solutions of tetra‐alkyl ammonium ions. The hydrogen bond forming in the series of the neutral solute molecules and the electric field in the series of the large ionic solute particles appear as distinguishable effects counteracting the tendency to the hydration of the second kind.

Bibliography

Pottel, R., & Kaatze, U. (1969). Permittivity and dielectric relaxation of aqueous solutions of hydrocarbons. Berichte Der Bunsengesellschaft FÃ¼r Physikalische Chemie, 73(5), 437â446. Portico.

Authors 2

R. Pottel (first)
U. Kaatze (additional)

References 14 Referenced 64

10.1002/ange.19660780102
10.1002/bbpc.19640681003
10.1002/bbpc.19670710204
10.1002/bbpc.19680720713
10.1063/1.1750906
10.1063/1.1747496
{'key': 'e_1_2_1_8_2', 'first-page': '105', 'volume': '17', 'author': 'Brown W. F.', 'year': '1956', 'journal-title': 'Hdb. Physik'} / Hdb. Physik by Brown W. F. (1956)
10.1021/ja01104a506
10.1002/bbpc.19640680834
10.1039/tf9514700577
10.1021/j100879a041
10.1002/andp.19063240204
10.1002/andp.19113390313
{'key': 'e_1_2_1_14_2', 'first-page': '14', 'volume': '4', 'author': 'Timmermans J.', 'year': '1960', 'journal-title': 'The Phys.‐chem. Const.'} / The Phys.‐chem. Const. by Timmermans J. (1960)

Dates

Type	When
Created	1 year, 10 months ago (Oct. 18, 2023, 11:12 p.m.)
Deposited	1 year, 10 months ago (Oct. 18, 2023, 11:12 p.m.)
Indexed	11 months, 2 weeks ago (Sept. 15, 2024, 8:59 a.m.)
Issued	56 years, 2 months ago (July 1, 1969)
Published	56 years, 2 months ago (July 1, 1969)
Published Online	15 years, 2 months ago (June 21, 2010)
Published Print	56 years, 2 months ago (July 1, 1969)

Funders 0

None

BibTeX

@article{Pottel_1969, title={Permittivity and dielectric relaxation of aqueous solutions of hydrocarbons}, volume={73}, ISSN={0005-9021}, url={http://dx.doi.org/10.1002/bbpc.19690730504}, DOI={10.1002/bbpc.19690730504}, number={5}, journal={Berichte der Bunsengesellschaft für physikalische Chemie}, publisher={Wiley}, author={Pottel, R. and Kaatze, U.}, year={1969}, month=jul, pages={437–446} }

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