DOI: 10.1002/bbpc.19690730105. Molecular motion in aqueous mixtures with organic liquids by nmr relaxation measurements

Molecular motion in aqueous mixtures with organic liquids by nmr relaxation measurements

10.1002/bbpc.19690730105

Crossref journal-article

Wiley

Berichte der Bunsengesellschaft für physikalische Chemie (311)

Abstract

AbstractMeasurements of the nmr spin‐lattice relaxation time T1 and of the self‐diffusion coefficient were performed for the organic component, and in some cases for the aqueous component, in binary mixtures of water with an organic liquid over the whole composition range at 25 °C. By isotopic substitution of one component and measurement of either the proton or deuteron resonance, the intramolecular and intermolecular contributions to the relaxation rates including that of water could be separated. From these data the reorientation time which is characteristic of the molecular motion is calculated and the behaviour of the intermolecular contribution is discussed. Comparison of the reorientation times for both components in the mixture leads to informations concerning intermolecular forces in the liquid.

Bibliography

Goldammer, E. V., & Zeidler, M. D. (1969). Molecular motion in aqueous mixtures with organic liquids by nmr relaxation measurements. Berichte Der Bunsengesellschaft FÃ¼r Physikalische Chemie, 73(1), 4â15. Portico.

Authors 2

E. V. Goldammer (first)
M. D. Zeidler (additional)

References 25 Referenced 141

10.1002/bbpc.19670710908
10.1002/bbpc.19650690803
10.1002/bbpc.196800020
10.1080/00268976600101341
10.1063/1.1716004
H.Pfeifer in Hochfrequenzspektroskopie ed. A. Lösche and W. Schütz Berlin1961.
10.1007/BF01407192
{'key': 'e_1_2_1_9_2', 'series-title': 'Special Publication No. 11', 'volume-title': 'Tables of Interatomic Distances and Configuration in Molecules and Ions', 'author': 'The Chemical Society', 'year': '1958'} / Tables of Interatomic Distances and Configuration in Molecules and Ions / Special Publication No. 11 by The Chemical Society (1958)
10.1080/00268976600100201
10.1080/00268976800100291
10.1063/1.1712431
10.1088/0370-1328/83/6/311
10.1063/1.1732274
10.1063/1.1701390
10.1063/1.1725202
10.1063/1.1669645
10.1016/0079-6565(67)80015-3
10.1021/j100824a520
M.Grüner private communication.
10.1016/0031-9163(65)90321-5
{'key': 'e_1_2_1_21_2', 'volume-title': 'Molecular Spectra and Molecular Structure', 'author': 'Herzberg G.', 'year': '1960'} / Molecular Spectra and Molecular Structure by Herzberg G. (1960)
10.1002/bbpc.19550590106
10.1039/tf9686400529
10.1002/bbpc.19640681003
10.1051/jcp/1967641319

Dates

Type	When
Created	1 year, 9 months ago (Nov. 13, 2023, 8:33 p.m.)
Deposited	1 year, 9 months ago (Nov. 13, 2023, 8:33 p.m.)
Indexed	11 months, 1 week ago (Sept. 14, 2024, 12:33 a.m.)
Issued	56 years, 7 months ago (Jan. 1, 1969)
Published	56 years, 7 months ago (Jan. 1, 1969)
Published Online	15 years, 2 months ago (June 21, 2010)
Published Print	56 years, 7 months ago (Jan. 1, 1969)

Funders 0

None

BibTeX

@article{Goldammer_1969, title={Molecular motion in aqueous mixtures with organic liquids by nmr relaxation measurements}, volume={73}, ISSN={0005-9021}, url={http://dx.doi.org/10.1002/bbpc.19690730105}, DOI={10.1002/bbpc.19690730105}, number={1}, journal={Berichte der Bunsengesellschaft für physikalische Chemie}, publisher={Wiley}, author={Goldammer, E. V. and Zeidler, M. D.}, year={1969}, month=jan, pages={4–15} }

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