Abstract
AbstractThe quantum yields for methanol photodecomposition have been found to be pressure dependent. Apart from methanol itself, other gases (alkane, N2, SF6, CO2, Ar, Kr, Xe) are effective in promoting the transition to dissociative states. A collision induced predissociation is postulated and the relative efficiencies of the different gases analyzed using a model based on simple degenerate perturbation theory.
References
14
Referenced
11
10.1021/ja01519a007
10.1051/jcp/1965620736
10.1063/1.1749715
{'key': 'e_1_2_1_5_2', 'first-page': '153', 'volume': '4', 'author': 'Price W. C.', 'year': '1936', 'journal-title': 'J. chem. Physics'}
/ J. chem. Physics by Price W. C. (1936)10.1007/BF01341527
{'key': 'e_1_2_1_7_2', 'first-page': '1684', 'volume': '37', 'author': 'Turner L. A.', 'year': '1931', 'journal-title': 'Physic. Rev.'}
/ Physic. Rev. by Turner L. A. (1931)10.1063/1.1749858
10.1063/1.1725680
10.1063/1.1695750
10.1063/1.1727121
- D.Bohn Quantum Mechanics ch. 19.8 19.9 and 19.13.
{'key': 'e_1_2_1_13_2', 'first-page': '351', 'volume-title': 'Quantum Chemistry', 'author': 'Eyring H.', 'year': '1944'}
/ Quantum Chemistry by Eyring H. (1944){'key': 'e_1_2_1_14_2', 'volume-title': 'Molecular Theory of Gases and Liquids', 'author': 'Hirschfelder J. O.', 'year': '1954'}
/ Molecular Theory of Gases and Liquids by Hirschfelder J. O. (1954){'issue': '1', 'key': 'e_1_2_1_15_2', 'first-page': '105', 'author': 'Collin J.', 'year': '1967', 'journal-title': 'Mémoires Soc. Roy. Sci. Liège'}
/ Mémoires Soc. Roy. Sci. Liège by Collin J. (1967)
Dates
Type | When |
---|---|
Created | 1 year, 10 months ago (Oct. 19, 2023, 2:48 p.m.) |
Deposited | 1 year, 10 months ago (Oct. 19, 2023, 2:51 p.m.) |
Indexed | 1 year, 3 months ago (May 23, 2024, 5:51 a.m.) |
Issued | 57 years, 5 months ago (March 1, 1968) |
Published | 57 years, 5 months ago (March 1, 1968) |
Published Online | 15 years, 3 months ago (May 4, 2010) |
Published Print | 57 years, 5 months ago (March 1, 1968) |
@article{Hag_ge_1968, title={Methanol Photochemistry: Collision‐Induced Predissociation}, volume={72}, ISSN={0005-9021}, url={http://dx.doi.org/10.1002/bbpc.19680720207}, DOI={10.1002/bbpc.19680720207}, number={2}, journal={Berichte der Bunsengesellschaft für physikalische Chemie}, publisher={Wiley}, author={Hagège, J. and Roberge, P. C. and Vermeil, C.}, year={1968}, month=mar, pages={138–141} }