DOI: 10.1002/app.26162. Application of polypyrrole to flexible substrates

Application of polypyrrole to flexible substrates

10.1002/app.26162

Crossref journal-article

Wiley

Journal of Applied Polymer Science (311)

Abstract

AbstractConducting polymers such as polypyrrole may be useful in smart packaging products, provided application methods can be developed that circumvent the insolubility and infusibility of these materials. Experiments were conducted in five research areas relevant to the application of polypyrrole to nonrigid substrates. The studies reveal that application of polypyrrole from the liquid phase, either by deposition from depleted bulk solution or inkjet printing dispersions, is unlikely to give films as regular as those produced by vapor phase polymerization. Using the latter approach, two potential methods of applying patterned polypyrrole films to nonrigid substrates were developed. The first used hypochlorite to pattern a continuous film of polypyrrole, previously applied by vapor phase polymerization. The second used inkjet printing to apply an oxidant solution, whose pH had been raised with a volatile base, to nonrigid substrates. The higher pH reduced corrosion of the print head, increasing the lifetime of printers exposed to oxidative compounds. The base was subsequently evaporated by heating, and the dried oxidant used as a template for vapor phase polymerization of polypyrrole. This method gave smooth, shiny and adherent polypyrrole films on papers and polyester transparency, with high resolution. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 3938–3947, 2007

Bibliography

WintherâJensen, B., Clark, N., Subramanian, P., Helmer, R., Ashraf, S., Wallace, G., Spiccia, L., & MacFarlane, D. (2007). Application of polypyrrole to flexible substrates. Journal of Applied Polymer Science, 104(6), 3938â3947. Portico.

Authors 8

Bjørn Winther‐Jensen (first)
Noel Clark (additional)
Priya Subramanian (additional)
Richard Helmer (additional)
Syed Ashraf (additional)
Gordon Wallace (additional)
Leone Spiccia (additional)
Douglas MacFarlane (additional)

References 21 Referenced 33

Subramanian P.;Clark N. B.;Helmer R. J. N.;Barisci J. N.;Kim B. C.;Wallace G. G.;Spiccia L.;MacFarlane D.;Appita J.2006 59 465.
10.1039/b415339a
10.1039/c39920000018
10.1002/adma.19950071011
10.1016/S0379-6779(98)00017-4
10.1016/j.snb.2005.10.019
Li S.;Newsome C.;Kugler T.;Russel D.Eur. Pat. 1 594 178 (2005).
10.1126/science.290.5499.2123
10.1002/marc.200400485
Ferraris J. P.;Dam T. H.;Meeker D.U.S. Pat. 6 501 587‐B1 (2003).
10.1016/0379-6779(86)90183-9
Kunimura S.;Nakayama S.Jpn. Pat. 63 010 409 (1986).
Kunimura S.;Nakayama S.Jpn. Pat. 63 021 713 (1986).
Warren L. F. Jr.;Maus L.;Hall W. F.U.S. Pat. 4 710 401 (1987).
{'key': 'e_1_2_6_16_2', 'author': 'Winther‐Jensen B.', 'journal-title': 'Macromol'} / Macromol by Winther‐Jensen B.
10.1021/ma049864l
10.1002/marc.200400527
10.1016/j.synthmet.2005.05.014
10.1021/cm970466p
10.1007/BF02759550
10.1080/15421400490506531

Dates

Type	When
Created	18 years, 5 months ago (March 27, 2007, 12:54 p.m.)
Deposited	1 year, 10 months ago (Oct. 10, 2023, 9:27 a.m.)
Indexed	1 month, 1 week ago (July 26, 2025, 5:27 a.m.)
Issued	18 years, 5 months ago (March 27, 2007)
Published	18 years, 5 months ago (March 27, 2007)
Published Online	18 years, 5 months ago (March 27, 2007)
Published Print	18 years, 2 months ago (June 15, 2007)

Funders 0

None

BibTeX

@article{Winther_Jensen_2007, title={Application of polypyrrole to flexible substrates}, volume={104}, ISSN={1097-4628}, url={http://dx.doi.org/10.1002/app.26162}, DOI={10.1002/app.26162}, number={6}, journal={Journal of Applied Polymer Science}, publisher={Wiley}, author={Winther‐Jensen, Bjørn and Clark, Noel and Subramanian, Priya and Helmer, Richard and Ashraf, Syed and Wallace, Gordon and Spiccia, Leone and MacFarlane, Douglas}, year={2007}, month=mar, pages={3938–3947} }

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