DOI: 10.1002/app.1995.070560403. Thermal stability studies of transparent conducting polyaniline composite films on their conductivity and optical spectra

Thermal stability studies of transparent conducting polyaniline composite films on their conductivity and optical spectra

10.1002/app.1995.070560403

Crossref journal-article

Wiley

Journal of Applied Polymer Science (311)

Abstract

AbstractThe thermal stability of highly transparent and conducting polyaniline–Nylon 6 (PAn‐N) composites films doped with various protonic acids such as hydrochloric acid (HCI), benzenesulfonic acid (BSA), sulfosalicylic acid (SSA), and p‐toluenesulfonic acid (TSA) was investigated at different elevated temperatures under air atmosphere. Two different degradation kinetic processes of electrical conductivity were found depending on the species of protonic acids. The conductivity degradation of PAn‐N composite films doped with SSA and TSA were found to obey first‐order reaction kinetics, while that of the other dopants was found to follow multiorder kinetics. Spectroscopic studies revealed that the thermal de‐doping process of doped composite films, which reversed the doping process, took place without major structural modifications of the polyaniline in the composite system but was not completely reversible. From the differential scanning calorimetry (DSC) study, the crystal structure of the composite films was found to be affected by the formation of polyaniline in matrix polymer and depended on the types of dopant species. © 1995 John Wiley & Sons, Inc.

Bibliography

Byun, S. W., & Im, S. S. (1995). Thermal stability studies of transparent conducting polyaniline composite films on their conductivity and optical spectra. Journal of Applied Polymer Science, 56(4), 425â431. Portico.

Authors 2

Sung Weon Byun (first)
Sung Soon Im (additional)

References 21 Referenced 15

10.1080/00268948508074861
10.1016/0379-6779(87)90893-9
10.1038/357477a0
10.1002/pi.4990250110
10.1080/00268948508074857
10.1016/0379-6779(88)90233-0
{'key': 'e_1_2_1_8_2', 'first-page': '151', 'volume': '30', 'author': 'Reynolds J. R.', 'year': '1989', 'journal-title': 'Polym. Prepr.'} / Polym. Prepr. by Reynolds J. R. (1989)
10.1002/app.1990.070400536
10.1021/ma00006a004
10.1016/0379-6779(90)90123-3
10.1016/0379-6779(88)90249-4
10.1016/0379-6779(89)90654-1
10.1002/pola.1989.080271312
10.1016/0379-6779(93)90466-A
10.1002/app.1994.070510709
10.1021/ma00157a057
10.1080/00268948208072175
10.1016/0379-6779(90)90180-S
10.1016/0379-6779(86)90127-X
10.1016/0379-6779(92)90366-Q
10.1016/0379-6779(89)90626-7

Dates

Type	When
Created	22 years, 4 months ago (April 15, 2003, 6:34 p.m.)
Deposited	1 year, 9 months ago (Nov. 20, 2023, 6:54 p.m.)
Indexed	11 months, 1 week ago (Sept. 16, 2024, 3:13 p.m.)
Issued	30 years, 3 months ago (April 25, 1995)
Published	30 years, 3 months ago (April 25, 1995)
Published Online	22 years, 5 months ago (March 10, 2003)
Published Print	30 years, 3 months ago (April 25, 1995)

Funders 0

None

BibTeX

@article{Byun_1995, title={Thermal stability studies of transparent conducting polyaniline composite films on their conductivity and optical spectra}, volume={56}, ISSN={1097-4628}, url={http://dx.doi.org/10.1002/app.1995.070560403}, DOI={10.1002/app.1995.070560403}, number={4}, journal={Journal of Applied Polymer Science}, publisher={Wiley}, author={Byun, Sung Weon and Im, Sung Soon}, year={1995}, month=apr, pages={425–431} }

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