DOI: 10.1002/app.1983.070281222. Rheology of solvent‐cast polymer films

10.1002/app.1983.070281222

Crossref journal-article

Wiley

Journal of Applied Polymer Science (311)

Abstract

AbstractThis paper describes and analyzes the results of an experiment where various thin polymeric films are continuously sheared between smooth glass substrates. The shear force per unit area has been measured as a function of mean uniaxial stress and temperature using representative “good” and “poor” casting solvents followed by a range of heat treatments. The polymers studied include high density polyethylene, polybisphenol‐A–carbonate, poly(ethylene terephthalate), atactic polystyrene, isotactic polystyrene, atactic poly(methyl methacrylate), isotactic poly(methyl methacrylate), poly(vinyl acetate), poly(vinyl alcohol), poly(vinyl pyrrolidone), poly(vinyl chloride), and polytetrafluoroethylene. The results indicate that the casting solvent has a very pronounced influence upon the rheology of the film. The casting solvents may apparently confer either ductile or brittle failure in the film and also influence the nature of the temperature and pressure dependence of the shear stress. The data have been analyzed using Eyring theory and also by reference to relevant published literature on the influence of solvent and thermal treatments on the morphology and deformation behavior of polymers. “Good” solvents generally tend to promote a brittle mode of failure with little temperature dependence. The same type of solvents also produced films which have higher shear strengths and show greater increases in shear strength with pressure. These data are adequately rationalized using free volume and entanglement notions.

Bibliography

Briscoe, B., & Smith, A. C. (1983). Rheology of solventâcast polymer films. Journal of Applied Polymer Science, 28(12), 3827â3848. Portico.

Authors 2

B. Briscoe (first)
A. C. Smith (additional)

References 43 Referenced 24

10.1098/rspa.1973.0050
10.1080/00218467808075110
{'key': 'e_1_2_1_4_2', 'volume-title': 'Adhesion 5', 'author': 'Briscoe B. J.', 'year': '1981'} / Adhesion 5 by Briscoe B. J. (1981)
{'key': 'e_1_2_1_5_2', 'first-page': '151', 'volume': '3', 'author': 'Briscoe B. J.', 'year': '1980', 'journal-title': 'Rev. Deformation Behaviour Mater.'} / Rev. Deformation Behaviour Mater. by Briscoe B. J. (1980)
{'key': 'e_1_2_1_6_2', 'volume-title': 'Theory of Elasticity', 'author': 'Timoshenko S. P.', 'year': '1970'} / Theory of Elasticity by Timoshenko S. P. (1970)
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{'key': 'e_1_2_1_23_2', 'volume-title': 'The Theory of Rate Processes', 'author': 'Glasstone S.', 'year': '1941'} / The Theory of Rate Processes by Glasstone S. (1941)
10.1007/BF00549685
{'key': 'e_1_2_1_25_2', 'first-page': '152', 'volume': '20', 'author': 'Amuzu J. K. A.', 'year': '1977', 'journal-title': 'Trans. Amer. Soc. Lubrication Engineers'} / Trans. Amer. Soc. Lubrication Engineers by Amuzu J. K. A. (1977)
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R. A.Duckett S. H.Joseph H.Sumner andZ.Stachurski Paper 37 at 4th International Conference: Deformation Yield and Fracture of Polymers Churchill College Cambridge 1979.
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{'key': 'e_1_2_1_44_2', 'volume-title': 'Microscopic Aspects of Adhesion', 'author': 'Tabor D.', 'year': '1982'} / Microscopic Aspects of Adhesion by Tabor D. (1982)

Dates

Type	When
Created	22 years, 4 months ago (April 15, 2003, 10:50 a.m.)
Deposited	1 year, 9 months ago (Nov. 20, 2023, 2:45 p.m.)
Indexed	1 year, 9 months ago (Nov. 20, 2023, 3:10 p.m.)
Issued	41 years, 9 months ago (Dec. 1, 1983)
Published	41 years, 9 months ago (Dec. 1, 1983)
Published Online	22 years, 5 months ago (March 9, 2003)
Published Print	41 years, 9 months ago (Dec. 1, 1983)

Funders 0

None

BibTeX

@article{Briscoe_1983, title={Rheology of solvent‐cast polymer films}, volume={28}, ISSN={1097-4628}, url={http://dx.doi.org/10.1002/app.1983.070281222}, DOI={10.1002/app.1983.070281222}, number={12}, journal={Journal of Applied Polymer Science}, publisher={Wiley}, author={Briscoe, B. and Smith, A. C.}, year={1983}, month=dec, pages={3827–3848} }

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