DOI: 10.1002/app.1981.070260313. Rubber‐modified epoxies. I. Transitions and morphology

Rubber‐modified epoxies. I. Transitions and morphology

10.1002/app.1981.070260313

Crossref journal-article

Wiley

Journal of Applied Polymer Science (311)

Abstract

AbstractA variety of different morphologies, and therefore mechanical properties, can be obtained from a single rubber‐modified epoxy formulation. The volume fraction, domain size, and the number of particles of phase‐separated rubber are determined by the competing effects of incompatibility, rate of nucleation and domain growth, and the quenching of morphological development by gelation. These factors can be varied by the butadience/acrylonitrile ratio of the reactive rubber, the temperature of cure, and the gelation time. These ideas have been exploited to control the development of morphology of these amorphous systems. Phase separation was investigated by electron microscopy, viscometry, and dynamic mechanical analysis.

Bibliography

Manzione, L. T., Gillham, J. K., & McPherson, C. A. (1981). Rubberâmodified epoxies. I. Transitions and morphology. Journal of Applied Polymer Science, 26(3), 889â905. Portico.

Authors 3

L. T. Manzione (first)
J. K. Gillham (additional)
C. A. McPherson (additional)

References 21 Referenced 250

{'key': 'e_1_2_1_2_2', 'first-page': '110', 'volume': '47', 'author': 'Rowe E. H.', 'year': '1970', 'journal-title': 'Mod. Plast.'} / Mod. Plast. by Rowe E. H. (1970)
10.1002/pen.760130105
{'key': 'e_1_2_1_4_2', 'volume-title': 'Principles of Polymer Chemistry', 'author': 'Flory P. J.', 'year': '1953'} / Principles of Polymer Chemistry by Flory P. J. (1953)
{'key': 'e_1_2_1_5_2', 'volume-title': 'Adv. in Chem. Series, No. 154, 326', 'author': 'Riew C. K.', 'year': '1976'} / Adv. in Chem. Series, No. 154, 326 by Riew C. K. (1976)
{'issue': '1', 'key': 'e_1_2_1_6_2', 'first-page': '195', 'volume': '37', 'author': 'Gillham J. K.', 'year': '1977', 'journal-title': 'Am. Chem. Soc. Div. Org. Coat. Plast. Chem.'} / Am. Chem. Soc. Div. Org. Coat. Plast. Chem. by Gillham J. K. (1977)
10.1016/B978-0-12-432250-9.50033-2
10.1007/978-94-017-5349-4
10.1002/pen.760191005
10.1002/aic.690200603
10.1002/pol.1971.150090927
{'key': 'e_1_2_1_10_2', 'first-page': '364', 'volume': '41', 'author': 'Manzione L. T.', 'year': '1979', 'journal-title': 'Am. Chem. Soc., Prepr. Div. Org. Coat. Plast. Chem.'} / Am. Chem. Soc., Prepr. Div. Org. Coat. Plast. Chem. by Manzione L. T. (1979)
{'key': 'e_1_2_1_11_2', 'first-page': '371', 'volume': '41', 'author': 'Manzione L. T.', 'year': '1979', 'journal-title': 'Am. Chem. Soc., Prepr. Div. Org. Coat. Plast. Chem.'} / Am. Chem. Soc., Prepr. Div. Org. Coat. Plast. Chem. by Manzione L. T. (1979)
10.1002/app.1981.070260314
{'key': 'e_1_2_1_12_2', 'volume-title': 'Quantitative Microscopy', 'author': 'DeHoff R. T.', 'year': '1968'} / Quantitative Microscopy by DeHoff R. T. (1968)
10.1002/app.1971.070150209
L. T.Manzione Ph.D. thesis Princeton University (1979).
10.1002/pol.1955.120158006
10.1002/pol.1968.110061005
{'key': 'e_1_2_1_17_2', 'volume-title': 'Transport Phenomena', 'author': 'Bird R. B.', 'year': '1969'} / Transport Phenomena by Bird R. B. (1969)
C. A.Glandt Ph.D. thesis Princeton University (1976).
10.1002/pen.760191014

Dates

Type	When
Created	22 years, 4 months ago (April 15, 2003, 10:40 a.m.)
Deposited	1 year, 9 months ago (Nov. 20, 2023, 12:56 p.m.)
Indexed	1 month, 2 weeks ago (July 13, 2025, 10:41 p.m.)
Issued	44 years, 6 months ago (March 1, 1981)
Published	44 years, 6 months ago (March 1, 1981)
Published Online	22 years, 5 months ago (March 9, 2003)
Published Print	44 years, 6 months ago (March 1, 1981)

Funders 0

None

BibTeX

@article{Manzione_1981, title={Rubber‐modified epoxies. I. Transitions and morphology}, volume={26}, ISSN={1097-4628}, url={http://dx.doi.org/10.1002/app.1981.070260313}, DOI={10.1002/app.1981.070260313}, number={3}, journal={Journal of Applied Polymer Science}, publisher={Wiley}, author={Manzione, L. T. and Gillham, J. K. and McPherson, C. A.}, year={1981}, month=mar, pages={889–905} }

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