DOI: 10.1002/app.1964.070080228. The relative inhibitory effect of various compounds on the rate of polymerization of vinyl acetate. II. Effect of conjugated and unconjugated acetylenes and olefins

The relative inhibitory effect of various compounds on the rate of polymerization of vinyl acetate. II. Effect of conjugated and unconjugated acetylenes and olefins

10.1002/app.1964.070080228

Crossref journal-article

Wiley

Journal of Applied Polymer Science (311)

Abstract

AbstractThe relative inhibitory effects of hexene‐1, hexyne‐1, trans‐hexene‐2, cis‐hexene‐2, hexyne‐2, 1,5‐hexadiene, 1,5‐hexadiyne, 1,7‐octadiyne, 1,8‐octadiyne, 1‐hexen‐5‐yne, 4‐chloro‐1,2‐butadiene, chloroprene, 2,5‐dimethyl‐2,4‐hexadiene, 2,4‐hexadiyne, 2‐methyl‐1‐buten‐3‐yne, styrene, ethynylbenzene, hydroquinone, and p‐methoxyphenol on the bulk polymerization of vinyl acetate were measured. Polymerization was carried out at 70°C. in a test tube in the presence of benzoyl peroxide. A comparison was made of the magnitude of the inhibitory effect due to isolated and conjugated, double and triple bonds as well as cumulative double bonds. A brief comparison between aliphatic and aromatic compounds was also made.

Bibliography

Georgieff, K. K., Blaikie, K. G., & White, R. C. (1964). The relative inhibitory effect of various compounds on the rate of polymerization of vinyl acetate. II. Effect of conjugated and unconjugated acetylenes and olefins. Journal of Applied Polymer Science, 8(2), 889â896. Portico.

Authors 3

K. K. Georgieff (first)
K. G. Blaikie (additional)
R. C. White (additional)

References 10 Referenced 6

10.1002/app.1961.070051414
10.15227/orgsyn.030.0015
10.1021/jo01377a003
{'key': 'e_1_2_1_5_2', 'first-page': '121', 'volume': '3', 'author': 'Turk A.', 'year': '1955', 'journal-title': 'Org. Syntheses Coll. Vol.'} / Org. Syntheses Coll. Vol. by Turk A. (1955)
10.6028/jres.052.009
10.1021/ja01349a034
10.1063/1.1747630
Unpublished results Shawinigan Chemicals Ltd.
{'key': 'e_1_2_1_10_2', 'first-page': '102', 'volume': '38', 'author': 'Capitani C.', 'year': '1956', 'journal-title': 'Chim. Ind. (Milan)'} / Chim. Ind. (Milan) by Capitani C. (1956)
10.1002/pol.1954.120147809

Dates

Type	When
Created	22 years, 4 months ago (April 15, 2003, 6:46 p.m.)
Deposited	1 year, 9 months ago (Nov. 20, 2023, 3:46 p.m.)
Indexed	1 year, 7 months ago (Jan. 11, 2024, 12:19 p.m.)
Issued	61 years, 6 months ago (March 1, 1964)
Published	61 years, 6 months ago (March 1, 1964)
Published Online	22 years, 5 months ago (March 9, 2003)
Published Print	61 years, 6 months ago (March 1, 1964)

Funders 0

None

BibTeX

@article{Georgieff_1964, title={The relative inhibitory effect of various compounds on the rate of polymerization of vinyl acetate. II. Effect of conjugated and unconjugated acetylenes and olefins}, volume={8}, ISSN={1097-4628}, url={http://dx.doi.org/10.1002/app.1964.070080228}, DOI={10.1002/app.1964.070080228}, number={2}, journal={Journal of Applied Polymer Science}, publisher={Wiley}, author={Georgieff, K. K. and Blaikie, K. G. and White, R. C.}, year={1964}, month=mar, pages={889–896} }

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