DOI: 10.1002/anie.201711598. Building Organic/Inorganic Hybrid Interphases for Fast Interfacial Transport in Rechargeable Metal Batteries

Building Organic/Inorganic Hybrid Interphases for Fast Interfacial Transport in Rechargeable Metal Batteries

10.1002/anie.201711598

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Abstract

AbstractWe report a facile in situ synthesis that utilizes readily accessible SiCl4 cross‐linking chemistry to create durable hybrid solid–electrolyte interphases (SEIs) on metal anodes. Such hybrid SEIs composed of Si‐interlinked OOCOR molecules that host LiCl salt exhibit fast charge‐transfer kinetics and as much as five‐times higher exchange current densities, in comparison to their spontaneously formed analogues. Electrochemical analysis and direct optical visualization of Li and Na deposition in symmetric Li/Li and Na/Na cells show that the hybrid SEI provides excellent morphological control at high current densities (3–5 mA cm−2) for Li and even for notoriously unstable Na metal anodes. The fast interfacial transport attributes of the SEI are also found to be beneficial for Li‐S cells and stable electrochemical cycling was achieved in galvanostatic studies at rates as high as 2 C. Our work therefore provides a promising approach towards rational design of multifunctional, elastic SEIs that overcome the most serious limitations of spontaneously formed interphases on high‐capacity metal anodes.

Bibliography

Zhao, Q., Tu, Z., Wei, S., Zhang, K., Choudhury, S., Liu, X., & Archer, L. A. (2017). Building Organic/Inorganic Hybrid Interphases for Fast Interfacial Transport in Rechargeable Metal Batteries. Angewandte Chemie International Edition, 57(4), 992â996. Portico.

Authors 7

Qing Zhao (first)
Zhengyuan Tu (additional)
Shuya Wei (additional)
Kaihang Zhang (additional)
Snehashis Choudhury (additional)
Xiaotun Liu (additional)
Lynden A. Archer (additional)

References 49 Referenced 226

Dates

Type	When
Created	7 years, 8 months ago (Dec. 11, 2017, 10:22 a.m.)
Deposited	1 year, 10 months ago (Sept. 26, 2023, 6 p.m.)
Indexed	1 day, 19 hours ago (Aug. 19, 2025, 6:18 a.m.)
Issued	7 years, 8 months ago (Dec. 21, 2017)
Published	7 years, 8 months ago (Dec. 21, 2017)
Published Online	7 years, 8 months ago (Dec. 21, 2017)
Published Print	7 years, 6 months ago (Jan. 22, 2018)

Funders 2

Basic Energy Sciences 10.13039/100006151
Region: Americas
gov (National government)
Labels6
1. Office of Basic Energy Sciences
2. DOE Office of Basic Energy Sciences
3. US Department of Energy's Basic Energy Sciences
4. DOE Basic Energy Sciences
5. Department of Energy Basic Energy Sciences Program
6. BES
Awards1
1. DE-SC0016082
Advanced Research Projects Agency - Energy 10.13039/100006133
Region: Americas
gov (National government)
Labels2
1. Advanced Research Projects Agency - Energy - U.S. Department of Energy
2. ARPA-E
Awards1
1. DE-AR-0000750

BibTeX

@article{Zhao_2017, title={Building Organic/Inorganic Hybrid Interphases for Fast Interfacial Transport in Rechargeable Metal Batteries}, volume={57}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.201711598}, DOI={10.1002/anie.201711598}, number={4}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Zhao, Qing and Tu, Zhengyuan and Wei, Shuya and Zhang, Kaihang and Choudhury, Snehashis and Liu, Xiaotun and Archer, Lynden A.}, year={2017}, month=dec, pages={992–996} }

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