DOI: 10.1002/anie.201709552. Phase‐Contact Engineering in Mono‐ and Bimetallic Cu‐Ni Co‐catalysts for Hydrogen Photocatalytic Materials

Phase‐Contact Engineering in Mono‐ and Bimetallic Cu‐Ni Co‐catalysts for Hydrogen Photocatalytic Materials

10.1002/anie.201709552

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Abstract

AbstractUnderstanding how a photocatalyst modulates its oxidation state, size, and structure during a photocatalytic reaction under operando conditions is strongly limited by the mismatch between (catalyst) volume sampled by light and, to date, the physicochemical techniques and probes employed to study them. A synchrotron micro‐beam X‐ray absorption spectroscopy study together with the computational simulation and analysis (at the X‐ray cell) of the light‐matter interaction occurring in powdered TiO2‐based monometallic Cu, Ni and bimetallic CuNi catalysts for hydrogen production from renewables was carried out. The combined information unveils an unexpected key catalytic role involving the phase contact between the reduced and oxidized non‐noble metal phases in all catalysts and, additionally, reveals the source of the synergistic Cu‐Ni interaction in the bimetallic material. The experimental method is applicable to operando studies of a wide variety of photocatalytic materials.

Bibliography

MuÃ±ozâBatista, M. J., MottaâMeira, D., ColÃ³n, G., Kubacka, A., & FernÃ¡ndezâGarcÃa, M. (2018). PhaseâContact Engineering in Monoâ and Bimetallic CuâNi Coâcatalysts for Hydrogen Photocatalytic Materials. Angewandte Chemie International Edition, 57(5), 1199â1203. Portico.

Authors 5

Mario J. Muñoz‐Batista (first)
Debora Motta Meira (additional)
Gerardo Colón (additional)
Anna Kubacka (additional)
Marcos Fernández‐García (additional)

References 14 Referenced 68

10.1021/cr1001645
10.1021/cr100454n
10.1039/C4CY01128G
10.1016/j.solmat.2014.12.016
10.1002/cctc.201600697
10.1021/cs3004006
{'key': 'e_1_2_2_7_1', 'volume-title': 'X-ray Absorption and X-Ray Emission Spectroscopy', 'year': '2016'} / X-ray Absorption and X-Ray Emission Spectroscopy (2016)
10.1081/CR-120001459
10.1016/j.apcatb.2014.11.019
10.1039/b925206a
10.1016/S0926-860X(98)00056-8
10.1016/j.apcata.2015.11.013
10.1002/cctc.201601361
10.1016/j.jcat.2015.03.008

Dates

Type	When
Created	7 years, 8 months ago (Dec. 19, 2017, 8:43 a.m.)
Deposited	1 year, 11 months ago (Sept. 10, 2023, 5:55 a.m.)
Indexed	2 days, 19 hours ago (Aug. 19, 2025, 6:28 a.m.)
Issued	7 years, 7 months ago (Jan. 11, 2018)
Published	7 years, 7 months ago (Jan. 11, 2018)
Published Online	7 years, 7 months ago (Jan. 11, 2018)
Published Print	7 years, 6 months ago (Jan. 26, 2018)

Funders 1

Ministerio de Economía y Competitividad 10.13039/501100003329
Region: Europe
gov (National government)
Labels3
1. Ministry of Economy and Competitiveness
2. MINECO
3. MEC
Awards2
1. CTQ2014-60524-R
2. ENER2016-77798-C4-1-R

BibTeX

@article{Mu_oz_Batista_2018, title={Phase‐Contact Engineering in Mono‐ and Bimetallic Cu‐Ni Co‐catalysts for Hydrogen Photocatalytic Materials}, volume={57}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.201709552}, DOI={10.1002/anie.201709552}, number={5}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Muñoz‐Batista, Mario J. and Motta Meira, Debora and Colón, Gerardo and Kubacka, Anna and Fernández‐García, Marcos}, year={2018}, month=jan, pages={1199–1203} }

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