DOI: 10.1002/anie.201508303. Iron‐ and Cobalt‐Catalyzed Synthesis of Carbene Phosphinidenes

Iron‐ and Cobalt‐Catalyzed Synthesis of Carbene Phosphinidenes

10.1002/anie.201508303

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Abstract

AbstractIn the presence of stoichiometric or catalytic amounts of [M{N(SiMe3)2}2] (M=Fe, Co), N‐heterocyclic carbenes (NHCs) react with primary phosphines to give a series of carbene phosphinidenes of the type (NHC)⋅PAr. The formation of (IMe4)⋅PMes (Mes=mesityl) is also catalyzed by the phosphinidene‐bridged complex [(IMe4)2Fe(μ‐PMes)]2, which provides evidence for metal‐catalyzed phosphinidene transfer.

Bibliography

Pal, K., Hemming, O. B., Day, B. M., Pugh, T., Evans, D. J., & Layfield, R. A. (2015). Ironâ and CobaltâCatalyzed Synthesis of Carbene Phosphinidenes. Angewandte Chemie International Edition, 55(5), 1690â1693. Portico.

Authors 6

Kuntal Pal (first)
Oliver B. Hemming (additional)
Benjamin M. Day (additional)
Thomas Pugh (additional)
David J. Evans (additional)
Richard A. Layfield (additional)

References 57 Referenced 62

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Dates

Type	When
Created	9 years, 8 months ago (Dec. 9, 2015, 2:55 a.m.)
Deposited	1 year, 11 months ago (Sept. 9, 2023, 9:23 a.m.)
Indexed	3 months, 3 weeks ago (May 6, 2025, 11:54 a.m.)
Issued	9 years, 8 months ago (Dec. 8, 2015)
Published	9 years, 8 months ago (Dec. 8, 2015)
Published Online	9 years, 8 months ago (Dec. 8, 2015)
Published Print	9 years, 7 months ago (Jan. 26, 2016)

Funders 3

EU
UK EPSRC
Awards2
1. EP/K008722/1
2. EP/K039547/1
Leverhulme Trust 10.13039/501100000275
Awards1
1. RPG-2012-460

BibTeX

@article{Pal_2015, title={Iron‐ and Cobalt‐Catalyzed Synthesis of Carbene Phosphinidenes}, volume={55}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.201508303}, DOI={10.1002/anie.201508303}, number={5}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Pal, Kuntal and Hemming, Oliver B. and Day, Benjamin M. and Pugh, Thomas and Evans, David J. and Layfield, Richard A.}, year={2015}, month=dec, pages={1690–1693} }

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