DOI: 10.1002/anie.201500993. Synthesis of Ultrathin Face‐Centered‐Cubic Au@Pt and Au@Pd Core–Shell Nanoplates from Hexagonal‐Close‐Packed Au Square Sheets

Synthesis of Ultrathin Face‐Centered‐Cubic Au@Pt and Au@Pd Core–Shell Nanoplates from Hexagonal‐Close‐Packed Au Square Sheets

10.1002/anie.201500993

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Abstract

AbstractThe synthesis of ultrathin face‐centered‐cubic (fcc) Au@Pt rhombic nanoplates is reported through the epitaxial growth of Pt on hexagonal‐close‐packed (hcp) Au square sheets (AuSSs). The Pt‐layer growth results in a hcp‐to‐fcc phase transformation of the AuSSs under ambient conditions. Interestingly, the obtained fcc Au@Pt rhombic nanoplates demonstrate a unique (101)f orientation with the same atomic arrangement extending from the Au core to the Pt shell. Importantly, this method can be extended to the epitaxial growth of Pd on hcp AuSSs, resulting in the unprecedented formation of fcc Au@Pd rhombic nanoplates with (101)f orientation. Additionally, a small amount of fcc (100)f‐oriented Au@Pt and Au@Pd square nanoplates are obtained with the Au@Pt and Au@Pd rhombic nanoplates, respectively. We believe that these findings will shed new light on the synthesis of novel noble bimetallic nanostructures.

Bibliography

Fan, Z., Zhu, Y., Huang, X., Han, Y., Wang, Q., Liu, Q., Huang, Y., Gan, C. L., & Zhang, H. (2015). Synthesis of Ultrathin FaceâCenteredâCubic Au@Pt and Au@Pd CoreâShell Nanoplates from HexagonalâCloseâPacked Au Square Sheets. Angewandte Chemie International Edition, 54(19), 5672â5676. Portico.

Authors 9

Zhanxi Fan (first)
Yihan Zhu (additional)
Xiao Huang (additional)
Yu Han (additional)
Qingxiao Wang (additional)
Qing Liu (additional)
Ying Huang (additional)
Chee Lip Gan (additional)
Hua Zhang (additional)

References 52 Referenced 115

Dates

Type	When
Created	10 years, 5 months ago (March 17, 2015, 7:10 p.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 8:29 p.m.)
Indexed	3 weeks, 2 days ago (July 30, 2025, 8:32 p.m.)
Issued	10 years, 5 months ago (March 17, 2015)
Published	10 years, 5 months ago (March 17, 2015)
Published Online	10 years, 5 months ago (March 17, 2015)
Published Print	10 years, 3 months ago (May 4, 2015)

Funders 1

MOE
Awards5
1. MOE2013-T2-1-034
2. RG 61/12
3. RG5/13
4. M4080865.070.706022
5. RGT18/13

BibTeX

@article{Fan_2015, title={Synthesis of Ultrathin Face‐Centered‐Cubic Au@Pt and Au@Pd Core–Shell Nanoplates from Hexagonal‐Close‐Packed Au Square Sheets}, volume={54}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.201500993}, DOI={10.1002/anie.201500993}, number={19}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Fan, Zhanxi and Zhu, Yihan and Huang, Xiao and Han, Yu and Wang, Qingxiao and Liu, Qing and Huang, Ying and Gan, Chee Lip and Zhang, Hua}, year={2015}, month=mar, pages={5672–5676} }

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