DOI: 10.1002/anie.201408876. Cobalt Sulfide Nanosheet/Graphene/Carbon Nanotube Nanocomposites as Flexible Electrodes for Hydrogen Evolution

Cobalt Sulfide Nanosheet/Graphene/Carbon Nanotube Nanocomposites as Flexible Electrodes for Hydrogen Evolution

10.1002/anie.201408876

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Abstract

AbstractFlexible three‐dimensional (3D) nanoarchitectures have received tremendous interest recently because of their potential applications in wearable electronics, roll‐up displays, and other devices. The design and fabrication of a flexible and robust electrode based on cobalt sulfide/reduced graphene oxide/carbon nanotube (CoS2/RGO‐CNT) nanocomposites are reported. An efficient hydrothermal process combined with vacuum filtration was used to synthesize such composite architecture, which was then embedded in a porous CNT network. This conductive and robust film is evaluated as electrocatalyst for the hydrogen evolution reaction. The synergistic effect of CoS2, graphene, and CNTs leads to unique CoS2/RGO‐CNT nanoarchitectures, the HER activity of which is among the highest for non‐noble metal electrocatalysts, showing 10 mA cm−2 current density at about 142 mV overpotentials and a high electrochemical stability.

Bibliography

Peng, S., Li, L., Han, X., Sun, W., Srinivasan, M., Mhaisalkar, S. G., Cheng, F., Yan, Q., Chen, J., & Ramakrishna, S. (2014). Cobalt Sulfide Nanosheet/Graphene/Carbon Nanotube Nanocomposites as Flexible Electrodes for Hydrogen Evolution. Angewandte Chemie International Edition, 53(46), 12594â12599. Portico.

Authors 10

Shengjie Peng (first)
Linlin Li (additional)
Xiaopeng Han (additional)
Wenping Sun (additional)
Madhavi Srinivasan (additional)
Subodh G. Mhaisalkar (additional)
Fangyi Cheng (additional)
Qingyu Yan (additional)
Jun Chen (additional)
Seeram Ramakrishna (additional)

References 78 Referenced 368

Dates

Type	When
Created	10 years, 10 months ago (Oct. 8, 2014, 4:42 p.m.)
Deposited	1 year, 11 months ago (Sept. 12, 2023, 8:50 p.m.)
Indexed	1 day ago (Sept. 3, 2025, 6:54 a.m.)
Issued	10 years, 10 months ago (Oct. 8, 2014)
Published	10 years, 10 months ago (Oct. 8, 2014)
Published Online	10 years, 10 months ago (Oct. 8, 2014)
Published Print	10 years, 9 months ago (Nov. 10, 2014)

Funders 0

None

BibTeX

@article{Peng_2014, title={Cobalt Sulfide Nanosheet/Graphene/Carbon Nanotube Nanocomposites as Flexible Electrodes for Hydrogen Evolution}, volume={53}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.201408876}, DOI={10.1002/anie.201408876}, number={46}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Peng, Shengjie and Li, Linlin and Han, Xiaopeng and Sun, Wenping and Srinivasan, Madhavi and Mhaisalkar, Subodh G. and Cheng, Fangyi and Yan, Qingyu and Chen, Jun and Ramakrishna, Seeram}, year={2014}, month=oct, pages={12594–12599} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        9,
        3
      ]
    ],
    "date-time": "2025-09-03T10:54:24Z",
    "timestamp": 1756896864101
  },
  "reference-count": 78,
  "publisher": "Wiley",
  "issue": "46",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2014,
            10,
            8
          ]
        ],
        "date-time": "2014-10-08T00:00:00Z",
        "timestamp": 1412726400000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2014,
        11,
        10
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>Flexible three\u2010dimensional (3D) nanoarchitectures have received tremendous interest recently because of their potential applications in wearable electronics, roll\u2010up displays, and other devices. The design and fabrication of a flexible and robust electrode based on cobalt sulfide/reduced graphene oxide/carbon nanotube (CoS<jats:sub>2</jats:sub>/RGO\u2010CNT) nanocomposites are reported. An efficient hydrothermal process combined with vacuum filtration was used to synthesize such composite architecture, which was then embedded in a porous CNT network. This conductive and robust film is evaluated as electrocatalyst for the hydrogen evolution reaction. The synergistic effect of CoS<jats:sub>2</jats:sub>, graphene, and CNTs leads to unique CoS<jats:sub>2</jats:sub>/RGO\u2010CNT nanoarchitectures, the HER activity of which is among the highest for non\u2010noble metal electrocatalysts, showing 10\u2005mA\u2009cm<jats:sup>\u22122</jats:sup> current density at about 142\u2005mV overpotentials and a high electrochemical stability.</jats:p>",
  "DOI": "10.1002/anie.201408876",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2014,
        10,
        8
      ]
    ],
    "date-time": "2014-10-08T20:42:12Z",
    "timestamp": 1412800932000
  },
  "page": "12594-12599",
  "source": "Crossref",
  "is-referenced-by-count": 368,
  "title": "Cobalt Sulfide Nanosheet/Graphene/Carbon Nanotube Nanocomposites as Flexible Electrodes for Hydrogen Evolution",
  "prefix": "10.1002",
  "volume": "53",
  "author": [
    {
      "given": "Shengjie",
      "family": "Peng",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Linlin",
      "family": "Li",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Xiaopeng",
      "family": "Han",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Wenping",
      "family": "Sun",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Madhavi",
      "family": "Srinivasan",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Subodh G.",
      "family": "Mhaisalkar",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Fangyi",
      "family": "Cheng",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Qingyu",
      "family": "Yan",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Jun",
      "family": "Chen",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Seeram",
      "family": "Ramakrishna",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2014,
        10,
        8
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_2_1_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_2_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/nmat1752"
    },
    {
      "key": "e_1_2_2_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cr1002326"
    },
    {
      "key": "e_1_2_2_4_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/nmat3439"
    },
    {
      "key": "e_1_2_2_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.201204453"
    },
    {
      "key": "e_1_2_2_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c2cs35019j"
    },
    {
      "key": "e_1_2_2_8_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.elecom.2008.01.022"
    },
    {
      "key": "e_1_2_2_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/nl0517619"
    },
    {
      "key": "e_1_2_2_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jpowsour.2007.11.072"
    },
    {
      "key": "e_1_2_2_12_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201402646"
    },
    {
      "key": "e_1_2_2_13_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.201402646"
    },
    {
      "key": "e_1_2_2_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201303495"
    },
    {
      "key": "e_1_2_2_14_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.201303495"
    },
    {
      "key": "e_1_2_2_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201210294"
    },
    {
      "key": "e_1_2_2_15_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.201210294"
    },
    {
      "key": "e_1_2_2_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201404161"
    },
    {
      "key": "e_1_2_2_16_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.201404161"
    },
    {
      "key": "e_1_2_2_17_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/ncomms4783"
    },
    {
      "key": "e_1_2_2_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c3cc44076a"
    },
    {
      "key": "e_1_2_2_20_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201200699"
    },
    {
      "key": "e_1_2_2_20_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.201200699"
    },
    {
      "key": "e_1_2_2_21_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_22_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c3ee42413h"
    },
    {
      "key": "e_1_2_2_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c3ee40600h"
    },
    {
      "key": "e_1_2_2_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja504099w"
    },
    {
      "key": "e_1_2_2_25_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.201302685"
    },
    {
      "key": "e_1_2_2_27_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201307475"
    },
    {
      "key": "e_1_2_2_27_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.201307475"
    },
    {
      "key": "e_1_2_2_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja404523s"
    },
    {
      "key": "e_1_2_2_29_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c2ee02618j"
    },
    {
      "key": "e_1_2_2_30_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/nl400258t"
    },
    {
      "key": "e_1_2_2_31_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/nl403661s"
    },
    {
      "key": "e_1_2_2_32_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201306918"
    },
    {
      "key": "e_1_2_2_32_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.201306918"
    },
    {
      "key": "e_1_2_2_33_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_34_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adfm.201203777"
    },
    {
      "key": "e_1_2_2_35_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adfm.201300318"
    },
    {
      "key": "e_1_2_2_36_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.201301051"
    },
    {
      "key": "e_1_2_2_37_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_38_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja201269b"
    },
    {
      "key": "e_1_2_2_39_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c3sc51290h"
    },
    {
      "key": "e_1_2_2_40_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja501497n"
    },
    {
      "key": "e_1_2_2_41_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c2cc33397j"
    },
    {
      "key": "e_1_2_2_42_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_43_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/smll.201302407"
    },
    {
      "key": "e_1_2_2_44_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.201202920"
    },
    {
      "key": "e_1_2_2_45_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_46_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adfm.201303273"
    },
    {
      "key": "e_1_2_2_47_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201103163"
    },
    {
      "key": "e_1_2_2_47_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.201103163"
    },
    {
      "key": "e_1_2_2_48_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cm7024763"
    },
    {
      "key": "e_1_2_2_49_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp111626a"
    },
    {
      "key": "e_1_2_2_50_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201402315"
    },
    {
      "key": "e_1_2_2_50_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.201402315"
    },
    {
      "key": "e_1_2_2_51_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_52_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adfm.201001054"
    },
    {
      "key": "e_1_2_2_53_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.201304683"
    },
    {
      "key": "e_1_2_2_54_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp2002113"
    },
    {
      "key": "e_1_2_2_55_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jpowsour.2013.05.062"
    },
    {
      "key": "e_1_2_2_56_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_57_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.201104720"
    },
    {
      "key": "e_1_2_2_58_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/nl301804c"
    },
    {
      "key": "e_1_2_2_59_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/nn303478e"
    },
    {
      "key": "e_1_2_2_60_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_61_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jcat.2008.06.016"
    },
    {
      "key": "e_1_2_2_62_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/cssc.201402161"
    },
    {
      "key": "e_1_2_2_63_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c1ee01970h"
    },
    {
      "key": "e_1_2_2_64_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/nn500959v"
    },
    {
      "key": "e_1_2_2_65_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja503372r"
    },
    {
      "key": "e_1_2_2_66_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/nn503027k"
    },
    {
      "key": "e_1_2_2_67_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_68_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c3nr02994h"
    },
    {
      "key": "e_1_2_2_69_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c2sc20539d"
    }
  ],
  "container-title": "Angewandte Chemie International Edition",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201408876",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201408876",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        9,
        13
      ]
    ],
    "date-time": "2023-09-13T00:50:35Z",
    "timestamp": 1694566235000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/anie.201408876"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2014,
        10,
        8
      ]
    ]
  },
  "references-count": 78,
  "journal-issue": {
    "issue": "46",
    "published-print": {
      "date-parts": [
        [
          2014,
          11,
          10
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/anie.201408876"
  ],
  "URL": "http://dx.doi.org/10.1002/anie.201408876",
  "relation": {},
  "ISSN": [
    "1433-7851",
    "1521-3773"
  ],
  "subject": [],
  "container-title-short": "Angew Chem Int Ed",
  "published": {
    "date-parts": [
      [
        2014,
        10,
        8
      ]
    ]
  }
}