DOI: 10.1002/anie.201404608. An Extra‐Large‐Pore Zeolite with Intersecting 18‐, 12‐, and 10‐Membered Ring Channels

An Extra‐Large‐Pore Zeolite with Intersecting 18‐, 12‐, and 10‐Membered Ring Channels

10.1002/anie.201404608

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Abstract

AbstractZeolites with extra‐large pores have attracted great attention because of their important applications such as in hydrocracking, catalysis, and separation of large molecules. Despite much progress has been made during the past decades, the synthesis of these materials remains a big challenge. A new extra‐large‐pore zeolite NUD‐1 (Nanjing University Du’s group zeolite no. 1) is synthesized by using an approach based on supramolecular self‐assemblies of small aromatic organic cations as structure‐directing agents. NUD‐1 possesses interconnecting 18‐, 12‐, and 10‐membered ring channels, built from the same building units as those of ITQ‐33 and ITQ‐44. There coexist single 3‐membered ring, double‐3‐membered ring and double‐4‐membered ring secondary building units in NUD‐1, which have not been seen in any other zeolites.

Bibliography

Chen, F., Xu, Y., & Du, H. (2014). An ExtraâLargeâPore Zeolite with Intersecting 18â, 12â, and 10âMembered Ring Channels. Angewandte Chemie International Edition, 53(36), 9592â9596. Portico.

Authors 3

Fei‐Jian Chen (first)
Yan Xu (additional)
Hong‐Bin Du (additional)

References 42 Referenced 68

10.1038/306356a0
10.1016/j.apcata.2011.11.015
10.1021/cr050989d
10.1038/331698a0
10.1002/ange.200904016
10.1002/anie.200904016
10.1038/nature07957
10.1126/science.1208652
10.1039/c2dt32231e
10.1002/(SICI)1521-3765(19991001)5:10<2796::AID-CHEM2796>3.0.CO;2-6
10.1038/337146a0
10.1021/jp906984z
M. D. Foster M. M. J. Treacy http://www.hypotheticalzeolites.net/.
10.1038/nature05238
10.1002/ange.201001506
10.1002/anie.201001506
Crystal data for NUD‐1: H10F6Ge47.81O198Si50.19 M=8172.44 hexagonal a=19.2571(9) Å b=19.2571(9) Å c=25.9826(14) Å γ=120° V=8344.4(10) Å3 T=100(2) K space group P6/mmm Z=1 47091 reflections measured 3324 independent reflections (Rint=0.0880). The finalR1andwR(F2) values were 0.0665 and 0.1637 forI>2 σ(I) and 0.0834 and 0.1735 for all data respectively. The goodness of the fit onF2was 1.109. Further details on the crystal structure investigations may be obtained free of charge from The Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk/data_request/cif by quoting the depository number CCDC 998761 which contains the supplementary crystallographic data for this paper.
10.1039/b007054h
10.1002/ange.200290027
10.1002/anie.200290028
10.1021/ja9840549
10.1038/nature02909
10.1021/ja0603599
10.1002/ange.200603027
10.1002/anie.200603027
10.1021/ja904458y
10.1002/ange.201306527
10.1002/anie.201306527
10.1002/ange.201306744
10.1002/anie.201306744
10.1252/jcej.16.470
10.1021/jp411124d
10.1021/ja8023725
10.1021/ja906105x
SMART and SADABS Bruker AXS Inc. Madison Wisconsin USA 1997.
10.1107/S0108767307043930
10.1107/S0021889802022112

Dates

Type	When
Created	11 years, 1 month ago (July 11, 2014, 4:59 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 3:43 p.m.)
Indexed	5 days, 14 hours ago (Aug. 30, 2025, 12:35 p.m.)
Issued	11 years, 1 month ago (July 11, 2014)
Published	11 years, 1 month ago (July 11, 2014)
Published Online	11 years, 1 month ago (July 11, 2014)
Published Print	11 years ago (Sept. 1, 2014)

Funders 0

None

BibTeX

@article{Chen_2014, title={An Extra‐Large‐Pore Zeolite with Intersecting 18‐, 12‐, and 10‐Membered Ring Channels}, volume={53}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.201404608}, DOI={10.1002/anie.201404608}, number={36}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Chen, Fei‐Jian and Xu, Yan and Du, Hong‐Bin}, year={2014}, month=jul, pages={9592–9596} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        30
      ]
    ],
    "date-time": "2025-08-30T16:35:09Z",
    "timestamp": 1756571709630
  },
  "reference-count": 42,
  "publisher": "Wiley",
  "issue": "36",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2014,
            7,
            11
          ]
        ],
        "date-time": "2014-07-11T00:00:00Z",
        "timestamp": 1405036800000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2014,
        9
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>Zeolites with extra\u2010large pores have attracted great attention because of their important applications such as in hydrocracking, catalysis, and separation of large molecules. Despite much progress has been made during the past decades, the synthesis of these materials remains a big challenge. A new extra\u2010large\u2010pore zeolite NUD\u20101 (Nanjing University Du\u2019s group zeolite no. 1) is synthesized by using an approach based on supramolecular self\u2010assemblies of small aromatic organic cations as structure\u2010directing agents. NUD\u20101 possesses interconnecting 18\u2010, 12\u2010, and 10\u2010membered ring channels, built from the same building units as those of ITQ\u201033 and ITQ\u201044. There coexist single 3\u2010membered ring, double\u20103\u2010membered ring and double\u20104\u2010membered ring secondary building units in NUD\u20101, which have not been seen in any other zeolites.</jats:p>",
  "DOI": "10.1002/anie.201404608",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2014,
        7,
        11
      ]
    ],
    "date-time": "2014-07-11T08:59:57Z",
    "timestamp": 1405069197000
  },
  "page": "9592-9596",
  "source": "Crossref",
  "is-referenced-by-count": 68,
  "title": "An Extra\u2010Large\u2010Pore Zeolite with Intersecting 18\u2010, 12\u2010, and 10\u2010Membered Ring Channels",
  "prefix": "10.1002",
  "volume": "53",
  "author": [
    {
      "given": "Fei\u2010Jian",
      "family": "Chen",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Yan",
      "family": "Xu",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Hong\u2010Bin",
      "family": "Du",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2014,
        7,
        11
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_4_1_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/306356a0"
    },
    {
      "key": "e_1_2_4_2_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_4_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.apcata.2011.11.015"
    },
    {
      "key": "e_1_2_4_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cr050989d"
    },
    {
      "key": "e_1_2_4_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/331698a0"
    },
    {
      "key": "e_1_2_4_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.200904016"
    },
    {
      "key": "e_1_2_4_6_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200904016"
    },
    {
      "key": "e_1_2_4_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/nature07957"
    },
    {
      "key": "e_1_2_4_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.1208652"
    },
    {
      "key": "e_1_2_4_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c2dt32231e"
    },
    {
      "key": "e_1_2_4_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/(SICI)1521-3765(19991001)5:10<2796::AID-CHEM2796>3.0.CO;2-6"
    },
    {
      "key": "e_1_2_4_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/337146a0"
    },
    {
      "key": "e_1_2_4_12_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_4_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp906984z"
    },
    {
      "key": "e_1_2_4_14_2",
      "unstructured": "M.\u2005D. Foster M.\u2005M.\u2005J. Treacy http://www.hypotheticalzeolites.net/."
    },
    {
      "key": "e_1_2_4_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/nature05238"
    },
    {
      "key": "e_1_2_4_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.201001506"
    },
    {
      "key": "e_1_2_4_16_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201001506"
    },
    {
      "key": "e_1_2_4_17_2",
      "unstructured": "Crystal data for NUD\u20101: H10F6Ge47.81O198Si50.19 M=8172.44 hexagonal a=19.2571(9)\u2005\u00c5 b=19.2571(9)\u2005\u00c5 c=25.9826(14)\u2005\u00c5 \u03b3=120\u00b0 V=8344.4(10)\u2005\u00c53 T=100(2)\u2005K space group P6/mmm Z=1 47091 reflections measured 3324 independent reflections (Rint=0.0880). The finalR1andwR(F2) values were 0.0665 and 0.1637 forI>2\u2009\u03c3(I) and 0.0834 and 0.1735 for all data respectively. The goodness of the fit onF2was 1.109. Further details on the crystal structure investigations may be obtained free of charge from The Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk/data_request/cif by quoting the depository number CCDC\u2005998761 which contains the supplementary crystallographic data for this paper."
    },
    {
      "key": "e_1_2_4_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/b007054h"
    },
    {
      "key": "e_1_2_4_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.200290027"
    },
    {
      "key": "e_1_2_4_19_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200290028"
    },
    {
      "key": "e_1_2_4_20_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja9840549"
    },
    {
      "key": "e_1_2_4_21_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_4_22_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/nature02909"
    },
    {
      "key": "e_1_2_4_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja0603599"
    },
    {
      "key": "e_1_2_4_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.200603027"
    },
    {
      "key": "e_1_2_4_24_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200603027"
    },
    {
      "key": "e_1_2_4_25_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_4_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja904458y"
    },
    {
      "key": "e_1_2_4_27_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.201306527"
    },
    {
      "key": "e_1_2_4_27_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201306527"
    },
    {
      "key": "e_1_2_4_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.201306744"
    },
    {
      "key": "e_1_2_4_28_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201306744"
    },
    {
      "key": "e_1_2_4_29_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1252/jcej.16.470"
    },
    {
      "key": "e_1_2_4_30_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_4_31_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp411124d"
    },
    {
      "key": "e_1_2_4_32_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja8023725"
    },
    {
      "key": "e_1_2_4_33_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja906105x"
    },
    {
      "key": "e_1_2_4_34_2",
      "unstructured": "SMART and SADABS Bruker AXS Inc. Madison Wisconsin USA 1997."
    },
    {
      "key": "e_1_2_4_35_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1107/S0108767307043930"
    },
    {
      "key": "e_1_2_4_36_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1107/S0021889802022112"
    }
  ],
  "container-title": "Angewandte Chemie International Edition",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201404608",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201404608",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        16
      ]
    ],
    "date-time": "2023-10-16T19:43:18Z",
    "timestamp": 1697485398000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/anie.201404608"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2014,
        7,
        11
      ]
    ]
  },
  "references-count": 42,
  "journal-issue": {
    "issue": "36",
    "published-print": {
      "date-parts": [
        [
          2014,
          9
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/anie.201404608"
  ],
  "URL": "http://dx.doi.org/10.1002/anie.201404608",
  "relation": {},
  "ISSN": [
    "1433-7851",
    "1521-3773"
  ],
  "subject": [],
  "container-title-short": "Angew Chem Int Ed",
  "published": {
    "date-parts": [
      [
        2014,
        7,
        11
      ]
    ]
  }
}