DOI: 10.1002/anie.201400711. Superior Rechargeability and Efficiency of Lithium–Oxygen Batteries: Hierarchical Air Electrode Architecture Combined with a Soluble Catalyst

Superior Rechargeability and Efficiency of Lithium–Oxygen Batteries: Hierarchical Air Electrode Architecture Combined with a Soluble Catalyst

10.1002/anie.201400711

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Abstract

AbstractThe lithium–oxygen battery has the potential to deliver extremely high energy densities; however, the practical use of Li‐O2 batteries has been restricted because of their poor cyclability and low energy efficiency. In this work, we report a novel Li‐O2 battery with high reversibility and good energy efficiency using a soluble catalyst combined with a hierarchical nanoporous air electrode. Through the porous three‐dimensional network of the air electrode, not only lithium ions and oxygen but also soluble catalysts can be rapidly transported, enabling ultra‐efficient electrode reactions and significantly enhanced catalytic activity. The novel Li‐O2 battery, combining an ideal air electrode and a soluble catalyst, can deliver a high reversible capacity (1000 mAh g−1) up to 900 cycles with reduced polarization (about 0.25 V).

Bibliography

Lim, H., Song, H., Kim, J., Gwon, H., Bae, Y., Park, K., Hong, J., Kim, H., Kim, T., Kim, Y. H., LeprÃ³, X., OvalleâRobles, R., Baughman, R. H., & Kang, K. (2014). Superior Rechargeability and Efficiency of LithiumâOxygen Batteries: Hierarchical Air Electrode Architecture Combined with a Soluble Catalyst. Angewandte Chemie International Edition, 53(15), 3926â3931. Portico.

Authors 14

Hee‐Dae Lim (first)
Hyelynn Song (additional)
Jinsoo Kim (additional)
Hyeokjo Gwon (additional)
Youngjoon Bae (additional)
Kyu‐Young Park (additional)
Jihyun Hong (additional)
Haegyeom Kim (additional)
Taewoo Kim (additional)
Yong Hyup Kim (additional)
Xavier Lepró (additional)
Raquel Ovalle‐Robles (additional)
Ray H. Baughman (additional)
Kisuk Kang (additional)

References 39 Referenced 424

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Dates

Type	When
Created	11 years, 5 months ago (March 5, 2014, 3:26 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 11:47 a.m.)
Indexed	3 days, 23 hours ago (Aug. 23, 2025, 1:10 a.m.)
Issued	11 years, 5 months ago (March 5, 2014)
Published	11 years, 5 months ago (March 5, 2014)
Published Online	11 years, 5 months ago (March 5, 2014)
Published Print	11 years, 4 months ago (April 7, 2014)

Funders 0

None

BibTeX

@article{Lim_2014, title={Superior Rechargeability and Efficiency of Lithium–Oxygen Batteries: Hierarchical Air Electrode Architecture Combined with a Soluble Catalyst}, volume={53}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.201400711}, DOI={10.1002/anie.201400711}, number={15}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Lim, Hee‐Dae and Song, Hyelynn and Kim, Jinsoo and Gwon, Hyeokjo and Bae, Youngjoon and Park, Kyu‐Young and Hong, Jihyun and Kim, Haegyeom and Kim, Taewoo and Kim, Yong Hyup and Lepró, Xavier and Ovalle‐Robles, Raquel and Baughman, Ray H. and Kang, Kisuk}, year={2014}, month=mar, pages={3926–3931} }

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