DOI: 10.1002/anie.201307422. Homometallic Rare‐Earth Metal Phosphinidene Clusters: Synthesis and Reactivity

Homometallic Rare‐Earth Metal Phosphinidene Clusters: Synthesis and Reactivity

10.1002/anie.201307422

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Abstract

AbstractTwo new trinuclear μ3‐bridged rare‐earth metal phosphinidene complexes, [{L(Ln)(μ‐Me)}3(μ3‐Me)(μ3‐PPh)] (L=[PhC(NC6H4iPr2‐2,6)2]−, Ln=Y (2 a), Lu (2 b)), were synthesized through methane elimination of the corresponding carbene precursors with phenylphosphine. Heating a toluene solution of 2 at 120 °C leads to an unprecedented ortho CH bond activation of the PhP ligand to form the bridged phosphinidene/phenyl complexes. Reactions of 2 with ketones, thione, or isothiocyanate show clear phospha‐Wittig chemistry, giving the corresponding organic phosphinidenation products and oxide (sulfide) complexes. Reaction of 2 with CS2 leads to the formation of novel trinuclear rare‐earth metal thione dianion clusters, for which a possible pathway was determined by DFT calculation.

Bibliography

Wang, K., Luo, G., Hong, J., Zhou, X., Weng, L., Luo, Y., & Zhang, L. (2013). Homometallic RareâEarth Metal Phosphinidene Clusters: Synthesis and Reactivity. Angewandte Chemie International Edition, 53(4), 1053â1056. Portico.

Authors 7

Kai Wang (first)
Gen Luo (additional)
Jianquan Hong (additional)
Xigeng Zhou (additional)
Linhong Weng (additional)
Yi Luo (additional)
Lixin Zhang (additional)

References 70 Referenced 59

10.1021/ja00380a029
10.1039/c39820000667
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For recent reviews see:
10.1002/(SICI)1521-3757(20000117)112:2<322::AID-ANGE322>3.0.CO;2-6
10.1002/(SICI)1521-3773(20000117)39:2<314::AID-ANIE314>3.0.CO;2-D
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For recent work on binuclear phosphinidene complexes see:
10.1039/B604150G
10.1002/chem.200800804
10.1039/b822732b
10.1002/ange.200904827
10.1002/anie.200904827
For μ3‐bridged transition metal phosphinidene complexes see:
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10.1002/ange.19840960227
10.1002/anie.198401601
10.1002/ange.19840960922
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CCDC 926452 (2 a) 926450 (2 b) 926453 (3 a) 926455 (3 b) 973095 (4 a) 779072 (4 b) 973096 (5 a) 845818 (5 b) 926454 (6 a) and 926451 (6 b) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk/data_request/cif.

Dates

Type	When
Created	11 years, 8 months ago (Dec. 5, 2013, 12:37 p.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 1:30 a.m.)
Indexed	3 weeks, 6 days ago (Aug. 5, 2025, 8:38 a.m.)
Issued	11 years, 8 months ago (Dec. 5, 2013)
Published	11 years, 8 months ago (Dec. 5, 2013)
Published Online	11 years, 8 months ago (Dec. 5, 2013)
Published Print	11 years, 7 months ago (Jan. 20, 2014)

Funders 2

NSFC 10.13039/501100001809 National Natural Science Foundation of China
Region: Asia
gov (National government)
Labels11
1. Chinese National Science Foundation
2. Natural Science Foundation of China
3. National Science Foundation of China
4. NNSF of China
5. NSF of China
6. 国家自然科学基金委员会
7. National Nature Science Foundation of China
8. Guójiā Zìrán Kēxué Jījīn Wěiyuánhuì
9. NSFC
10. NNSF
11. NNSFC
Awards1
1. 2012CB821604
Ministry of Education of China 10.13039/501100002338 Ministry of Education of the People's Republic of China
Region: Asia
gov (National government)
Labels9
1. 中华人民共和国教育部
2. Министерство образования Китайской Народной Республики
3. 中華人民共和国教育部
4. Bildungsministerium der Volksrepublik China
5. Ministry of Education of China
6. Ministry of Education, The People's Republic of China
7. Ministry of Education of the Central People's Government
8. State Education Commission
9. MOE

BibTeX

@article{Wang_2013, title={Homometallic Rare‐Earth Metal Phosphinidene Clusters: Synthesis and Reactivity}, volume={53}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.201307422}, DOI={10.1002/anie.201307422}, number={4}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Wang, Kai and Luo, Gen and Hong, Jianquan and Zhou, Xigeng and Weng, Linhong and Luo, Yi and Zhang, Lixin}, year={2013}, month=dec, pages={1053–1056} }

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