DOI: 10.1002/anie.201107033. Modifying Chemical Landscapes by Coupling to Vacuum Fields

Modifying Chemical Landscapes by Coupling to Vacuum Fields

10.1002/anie.201107033

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Bibliography

Hutchison, J. A., Schwartz, T., Genet, C., Devaux, E., & Ebbesen, T. W. (2012). Modifying Chemical Landscapes by Coupling to Vacuum Fields. Angewandte Chemie International Edition, 51(7), 1592â1596. Portico.

Authors 5

James A. Hutchison (first)
Tal Schwartz (additional)
Cyriaque Genet (additional)
Eloïse Devaux (additional)
Thomas W. Ebbesen (additional)

References 32 Referenced 762

10.1063/1.3480075
10.1103/RevModPhys.73.565
10.1088/0268-1242/13/7/003
10.1103/PhysRevLett.69.3314
10.1016/0038-1098(94)00865-5
10.1103/PhysRevB.67.085311
10.1016/j.jlumin.2004.08.033
10.1038/nature02969
10.1038/nature03119
10.1103/PhysRevLett.101.180404
10.1103/PhysRevB.72.115303
10.1103/PhysRevB.79.201303
10.1063/1.881201
10.1103/PhysRevLett.68.1132
10.1038/25692
10.1063/1.1517714
10.1103/PhysRevLett.93.036404
10.1103/PhysRevLett.93.186404
10.1109/JQE.2002.1017612
10.1103/PhysRevLett.95.036401
10.1103/PhysRevB.71.035424
10.1002/ange.200903191
10.1002/anie.200903191
10.1103/PhysRevLett.103.053602
10.1103/PhysRevLett.106.196405
10.1021/j100273a015
10.1021/jp962569l
10.1021/jp012564a
10.1021/jp053782x
10.1081/MC-120025978
10.1021/ja00018a020
Perhaps the more surprising is why the lifetime of |P−〉 is not roughly that of the lifetime of the photon in the cavity that is very short on the order of tens of fs. From the width of the Fabry–Perot resonance the damping time in the cavity is ca. 25 fs. The lifetime of the MC* is much longer on the order of tens of ps so one would expect that the lifetime of the polaritonic state would be dominated by the shorter of the two since it is formed by a coherent photon exchange between the molecule and the cavity. One explanation for the observed longer lifetime of polaritonic states involving molecules has been explained by energy transfer from incoherent uncoupled molecules to the coherent polaritonic states.[6 7]If this was the case here then the transient absorption spectrum would be that of the uncoupled molecules which it is clearly not (Figure 4). Another explanation must therefore be sought to explain such results.

Dates

Type	When
Created	13 years, 7 months ago (Jan. 10, 2012, 11:22 a.m.)
Deposited	9 months ago (Nov. 28, 2024, 6:03 a.m.)
Indexed	3 days, 23 hours ago (Aug. 29, 2025, 5:58 a.m.)
Issued	13 years, 7 months ago (Jan. 10, 2012)
Published	13 years, 7 months ago (Jan. 10, 2012)
Published Online	13 years, 7 months ago (Jan. 10, 2012)
Published Print	13 years, 6 months ago (Feb. 13, 2012)

Funders 0

None

BibTeX

@article{Hutchison_2012, title={Modifying Chemical Landscapes by Coupling to Vacuum Fields}, volume={51}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.201107033}, DOI={10.1002/anie.201107033}, number={7}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Hutchison, James A. and Schwartz, Tal and Genet, Cyriaque and Devaux, Eloïse and Ebbesen, Thomas W.}, year={2012}, month=jan, pages={1592–1596} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        29
      ]
    ],
    "date-time": "2025-08-29T09:58:55Z",
    "timestamp": 1756461535000,
    "version": "3.29.0"
  },
  "reference-count": 32,
  "publisher": "Wiley",
  "issue": "7",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2012,
            1,
            10
          ]
        ],
        "date-time": "2012-01-10T00:00:00Z",
        "timestamp": 1326153600000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2012,
        2,
        13
      ]
    ]
  },
  "DOI": "10.1002/anie.201107033",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2012,
        1,
        10
      ]
    ],
    "date-time": "2012-01-10T16:22:37Z",
    "timestamp": 1326212557000
  },
  "page": "1592-1596",
  "source": "Crossref",
  "is-referenced-by-count": 762,
  "title": "Modifying Chemical Landscapes by Coupling to Vacuum Fields",
  "prefix": "10.1002",
  "volume": "51",
  "author": [
    {
      "given": "James A.",
      "family": "Hutchison",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Tal",
      "family": "Schwartz",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Cyriaque",
      "family": "Genet",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Elo\u00efse",
      "family": "Devaux",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Thomas W.",
      "family": "Ebbesen",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2012,
        1,
        10
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_2_1_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.3480075"
    },
    {
      "key": "e_1_2_2_2_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/RevModPhys.73.565"
    },
    {
      "key": "e_1_2_2_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1088/0268-1242/13/7/003"
    },
    {
      "key": "e_1_2_2_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.69.3314"
    },
    {
      "key": "e_1_2_2_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0038-1098(94)00865-5"
    },
    {
      "key": "e_1_2_2_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.67.085311"
    },
    {
      "key": "e_1_2_2_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jlumin.2004.08.033"
    },
    {
      "key": "e_1_2_2_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/nature02969"
    },
    {
      "key": "e_1_2_2_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/nature03119"
    },
    {
      "key": "e_1_2_2_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.101.180404"
    },
    {
      "key": "e_1_2_2_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.72.115303"
    },
    {
      "key": "e_1_2_2_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.79.201303"
    },
    {
      "key": "e_1_2_2_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.881201"
    },
    {
      "key": "e_1_2_2_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.68.1132"
    },
    {
      "key": "e_1_2_2_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/25692"
    },
    {
      "key": "e_1_2_2_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1517714"
    },
    {
      "key": "e_1_2_2_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.93.036404"
    },
    {
      "key": "e_1_2_2_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.93.186404"
    },
    {
      "key": "e_1_2_2_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1109/JQE.2002.1017612"
    },
    {
      "key": "e_1_2_2_20_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.95.036401"
    },
    {
      "key": "e_1_2_2_21_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.71.035424"
    },
    {
      "key": "e_1_2_2_22_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.200903191"
    },
    {
      "key": "e_1_2_2_22_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200903191"
    },
    {
      "key": "e_1_2_2_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.103.053602"
    },
    {
      "key": "e_1_2_2_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevLett.106.196405"
    },
    {
      "key": "e_1_2_2_25_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100273a015"
    },
    {
      "key": "e_1_2_2_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp962569l"
    },
    {
      "key": "e_1_2_2_27_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp012564a"
    },
    {
      "key": "e_1_2_2_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp053782x"
    },
    {
      "key": "e_1_2_2_29_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1081/MC-120025978"
    },
    {
      "key": "e_1_2_2_30_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00018a020"
    },
    {
      "key": "e_1_2_2_31_2",
      "unstructured": "Perhaps the more surprising is why the lifetime of |P\u2212\u3009 is not roughly that of the lifetime of the photon in the cavity that is very short on the order of tens of fs. From the width of the Fabry\u2013Perot resonance the damping time in the cavity is ca. 25\u2005fs. The lifetime of the MC* is much longer on the order of tens of ps so one would expect that the lifetime of the polaritonic state would be dominated by the shorter of the two since it is formed by a coherent photon exchange between the molecule and the cavity. One explanation for the observed longer lifetime of polaritonic states involving molecules has been explained by energy transfer from incoherent uncoupled molecules to the coherent polaritonic states.[6 \u20097]If this was the case here then the transient absorption spectrum would be that of the uncoupled molecules which it is clearly not (Figure\u20054). Another explanation must therefore be sought to explain such results."
    }
  ],
  "container-title": "Angewandte Chemie International Edition",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.201107033",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201107033",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2024,
        11,
        28
      ]
    ],
    "date-time": "2024-11-28T11:03:33Z",
    "timestamp": 1732791813000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/anie.201107033"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2012,
        1,
        10
      ]
    ]
  },
  "references-count": 32,
  "journal-issue": {
    "issue": "7",
    "published-print": {
      "date-parts": [
        [
          2012,
          2,
          13
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/anie.201107033"
  ],
  "URL": "http://dx.doi.org/10.1002/anie.201107033",
  "relation": {},
  "ISSN": [
    "1433-7851",
    "1521-3773"
  ],
  "subject": [],
  "container-title-short": "Angew Chem Int Ed",
  "published": {
    "date-parts": [
      [
        2012,
        1,
        10
      ]
    ]
  }
}