DOI: 10.1002/anie.200901241. Heterogeneous Catalytic Oxidation by MFU‐1: A Cobalt(II)‐Containing Metal

Heterogeneous Catalytic Oxidation by MFU‐1: A Cobalt(II)‐Containing Metal–Organic Framework

10.1002/anie.200901241

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Bibliography

Tonigold, M., Lu, Y., BredenkÃ¶tter, B., Rieger, B., BahnmÃ¼ller, S., Hitzbleck, J., Langstein, G., & Volkmer, D. (2009). Heterogeneous Catalytic Oxidation by MFUâ1: A Cobalt(II)âContaining MetalâOrganic Framework. Angewandte Chemie International Edition, 48(41), 7546â7550. Portico.

Authors 8

Markus Tonigold (first)
Ying Lu (additional)
Björn Bredenkötter (additional)
Bernhard Rieger (additional)
Stefan Bahnmüller (additional)
Julia Hitzbleck (additional)
Gerhard Langstein (additional)
Dirk Volkmer (additional)

References 60 Referenced 197

For recent reviews on different aspects of MOF applications see:
10.1021/ar000034b
10.1021/ar040163i
10.1039/B511962F
10.1038/46248
10.1126/science.1067208
10.1021/ja063506b
10.1021/ja069972i
10.1021/jp063600e
10.1002/cssc.200800203
10.1002/ange.200462515
10.1002/anie.200462515
10.1039/B600408C
10.1002/ange.200602099
10.1002/anie.200602099
10.1039/B609733B
10.1107/S010827019301337X
10.1021/jo01286a058
German Patent and Trademark Office S.Bahnmüller G.Langstein J.Hitzbleck D.Volkmer Y.Lu M.Tonigold DE102008027218A1 2009.
MFU is the acronym for Metal–Organic Framework Ulm University.
10.1246/bcsj.27.112
10.1021/ic025821e
10.1021/ja0635231
Crystal data for MFU‐1: [Co4O(C16H16N4)3]n∞ C48H48N12OCo4 Mr=1044.70 cubic space groupP$\bar 4$3m a=15.963(2) Å V=4067.9(8) Å3 Z=1 ρcalcd=0.426 g cm−3. In the chosen achiral space group the phenylene moiety of the bridging bdpb ligand occupies two alternative positions each with 50 % probability. Crystals suitable for single crystal X‐ray structure analysis of this compound are notoriously hard to obtain because the crystal specimens are small (<50 μm) and show a marked tendency of (inversion) twinning. To remove the occluded DMF solvent molecules we refluxed a suspension of crystals several times with chloroform and kept the crystals for at least 12 h under high vacuum (p<10−4 mbar). The crystallographic data from six independent measurements all showed a large residual electron density in the void regions of the crystal lattice which we could not refine any further. This electron density could be due to residual disordered solvent molecules or it might result from crystal twinning.
10.1021/ic702085x
10.1021/jp074723h
10.1021/ja071174k
The reported surface areas for MOF‐5 substantially vary; see for example:
10.1002/adma.200400946
10.1021/ja056831s
10.1021/ja061681m
10.1002/adfm.200500561
10.1016/S1387-1811(02)00609-1
10.1021/ja0675447
10.1021/ja0752336
{'key': 'e_1_2_2_36_2', 'first-page': '323', 'volume-title': 'Inorganic Electronic Spectroscopy', 'author': 'Lever A. B. P.', 'year': '1968'} / Inorganic Electronic Spectroscopy by Lever A. B. P. (1968)
10.1021/cm991179j
10.1021/ja9814873
10.1021/ic980970b
10.1021/ja00298a022
10.1021/jo00229a022
10.1021/jo01083a022
10.1016/j.catcom.2006.04.005
{'key': 'e_1_2_2_46_2', 'volume-title': 'Elements of Chemical Reaction Engineering', 'author': 'Fogler H. S.', 'year': '1986'} / Elements of Chemical Reaction Engineering by Fogler H. S. (1986)
10.1021/ie050683x
10.1016/j.apcata.2004.03.042
10.1016/S0166-9834(00)82317-9
10.1080/01614948408064725
10.1016/S0166-9834(00)81453-0
10.1021/ie970797b
10.1002/aic.690290505
10.1016/j.jcat.2008.02.011
10.1073/pnas.0602439103
10.1021/j100785a001

Dates

Type	When
Created	15 years, 11 months ago (Sept. 10, 2009, 3:10 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 8:40 a.m.)
Indexed	1 month, 2 weeks ago (July 16, 2025, 7:59 a.m.)
Issued	15 years, 11 months ago (Sept. 23, 2009)
Published	15 years, 11 months ago (Sept. 23, 2009)
Published Online	15 years, 11 months ago (Sept. 23, 2009)
Published Print	15 years, 11 months ago (Sept. 28, 2009)

Funders 0

None

BibTeX

@article{Tonigold_2009, title={Heterogeneous Catalytic Oxidation by MFU‐1: A Cobalt(II)‐Containing Metal–Organic Framework}, volume={48}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.200901241}, DOI={10.1002/anie.200901241}, number={41}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Tonigold, Markus and Lu, Ying and Bredenkötter, Björn and Rieger, Bernhard and Bahnmüller, Stefan and Hitzbleck, Julia and Langstein, Gerhard and Volkmer, Dirk}, year={2009}, month=sep, pages={7546–7550} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        7,
        16
      ]
    ],
    "date-time": "2025-07-16T11:59:17Z",
    "timestamp": 1752667157931
  },
  "reference-count": 60,
  "publisher": "Wiley",
  "issue": "41",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2009,
            9,
            10
          ]
        ],
        "date-time": "2009-09-10T00:00:00Z",
        "timestamp": 1252540800000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2009,
        9,
        28
      ]
    ]
  },
  "DOI": "10.1002/anie.200901241",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2009,
        9,
        10
      ]
    ],
    "date-time": "2009-09-10T07:10:21Z",
    "timestamp": 1252566621000
  },
  "page": "7546-7550",
  "source": "Crossref",
  "is-referenced-by-count": 197,
  "title": "Heterogeneous Catalytic Oxidation by MFU\u20101: A Cobalt(II)\u2010Containing Metal\u2013Organic Framework",
  "prefix": "10.1002",
  "volume": "48",
  "author": [
    {
      "given": "Markus",
      "family": "Tonigold",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Ying",
      "family": "Lu",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Bj\u00f6rn",
      "family": "Bredenk\u00f6tter",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Bernhard",
      "family": "Rieger",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Stefan",
      "family": "Bahnm\u00fcller",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Julia",
      "family": "Hitzbleck",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Gerhard",
      "family": "Langstein",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Dirk",
      "family": "Volkmer",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2009,
        9,
        23
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_2_1_2",
      "unstructured": "For recent reviews on different aspects of MOF applications see:"
    },
    {
      "key": "e_1_2_2_2_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ar000034b"
    },
    {
      "key": "e_1_2_2_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ar040163i"
    },
    {
      "key": "e_1_2_2_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/B511962F"
    },
    {
      "key": "e_1_2_2_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/46248"
    },
    {
      "key": "e_1_2_2_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.1067208"
    },
    {
      "key": "e_1_2_2_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja063506b"
    },
    {
      "key": "e_1_2_2_7_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja069972i"
    },
    {
      "key": "e_1_2_2_8_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp063600e"
    },
    {
      "key": "e_1_2_2_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/cssc.200800203"
    },
    {
      "key": "e_1_2_2_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.200462515"
    },
    {
      "key": "e_1_2_2_11_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200462515"
    },
    {
      "key": "e_1_2_2_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/B600408C"
    },
    {
      "key": "e_1_2_2_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.200602099"
    },
    {
      "key": "e_1_2_2_13_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200602099"
    },
    {
      "key": "e_1_2_2_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/B609733B"
    },
    {
      "key": "e_1_2_2_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1107/S010827019301337X"
    },
    {
      "key": "e_1_2_2_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jo01286a058"
    },
    {
      "key": "e_1_2_2_17_2",
      "unstructured": "German Patent and Trademark Office S.Bahnm\u00fcller G.Langstein J.Hitzbleck D.Volkmer Y.Lu M.Tonigold DE102008027218A1 2009."
    },
    {
      "key": "e_1_2_2_18_2",
      "unstructured": "MFU is the acronym for Metal\u2013Organic Framework Ulm University."
    },
    {
      "key": "e_1_2_2_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1246/bcsj.27.112"
    },
    {
      "key": "e_1_2_2_20_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic025821e"
    },
    {
      "key": "e_1_2_2_21_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja0635231"
    },
    {
      "key": "e_1_2_2_22_2",
      "unstructured": "Crystal data for MFU\u20101: [Co4O(C16H16N4)3]n\u221e C48H48N12OCo4 Mr=1044.70 cubic space groupP$\\bar 4$3m a=15.963(2)\u2005\u00c5 V=4067.9(8)\u2005\u00c53 Z=1 \u03c1calcd=0.426\u2005g\u2009cm\u22123. In the chosen achiral space group the phenylene moiety of the bridging bdpb ligand occupies two alternative positions each with 50\u2009% probability. Crystals suitable for single crystal X\u2010ray structure analysis of this compound are notoriously hard to obtain because the crystal specimens are small (<50\u2005\u03bcm) and show a marked tendency of (inversion) twinning. To remove the occluded DMF solvent molecules we refluxed a suspension of crystals several times with chloroform and kept the crystals for at least 12\u2005h under high vacuum (p<10\u22124\u2005mbar). The crystallographic data from six independent measurements all showed a large residual electron density in the void regions of the crystal lattice which we could not refine any further. This electron density could be due to residual disordered solvent molecules or it might result from crystal twinning."
    },
    {
      "key": "e_1_2_2_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic702085x"
    },
    {
      "key": "e_1_2_2_24_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_25_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp074723h"
    },
    {
      "key": "e_1_2_2_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja071174k"
    },
    {
      "key": "e_1_2_2_27_2",
      "unstructured": "The reported surface areas for MOF\u20105 substantially vary; see for example:"
    },
    {
      "key": "e_1_2_2_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.200400946"
    },
    {
      "key": "e_1_2_2_29_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja056831s"
    },
    {
      "key": "e_1_2_2_30_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja061681m"
    },
    {
      "key": "e_1_2_2_31_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adfm.200500561"
    },
    {
      "key": "e_1_2_2_32_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S1387-1811(02)00609-1"
    },
    {
      "key": "e_1_2_2_33_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja0675447"
    },
    {
      "key": "e_1_2_2_34_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja0752336"
    },
    {
      "key": "e_1_2_2_35_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_36_2",
      "first-page": "323",
      "volume-title": "Inorganic Electronic Spectroscopy",
      "author": "Lever A. B. P.",
      "year": "1968"
    },
    {
      "key": "e_1_2_2_37_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cm991179j"
    },
    {
      "key": "e_1_2_2_38_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_39_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja9814873"
    },
    {
      "key": "e_1_2_2_40_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic980970b"
    },
    {
      "key": "e_1_2_2_41_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00298a022"
    },
    {
      "key": "e_1_2_2_42_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_43_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jo00229a022"
    },
    {
      "key": "e_1_2_2_44_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jo01083a022"
    },
    {
      "key": "e_1_2_2_45_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.catcom.2006.04.005"
    },
    {
      "key": "e_1_2_2_46_2",
      "volume-title": "Elements of Chemical Reaction Engineering",
      "author": "Fogler H. S.",
      "year": "1986"
    },
    {
      "key": "e_1_2_2_47_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_48_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ie050683x"
    },
    {
      "key": "e_1_2_2_49_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.apcata.2004.03.042"
    },
    {
      "key": "e_1_2_2_50_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0166-9834(00)82317-9"
    },
    {
      "key": "e_1_2_2_51_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1080/01614948408064725"
    },
    {
      "key": "e_1_2_2_52_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0166-9834(00)81453-0"
    },
    {
      "key": "e_1_2_2_53_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ie970797b"
    },
    {
      "key": "e_1_2_2_54_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/aic.690290505"
    },
    {
      "key": "e_1_2_2_55_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jcat.2008.02.011"
    },
    {
      "key": "e_1_2_2_56_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1073/pnas.0602439103"
    },
    {
      "key": "e_1_2_2_57_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100785a001"
    }
  ],
  "container-title": "Angewandte Chemie International Edition",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.200901241",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.200901241",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        16
      ]
    ],
    "date-time": "2023-10-16T12:40:30Z",
    "timestamp": 1697460030000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/anie.200901241"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2009,
        9,
        23
      ]
    ]
  },
  "references-count": 60,
  "journal-issue": {
    "issue": "41",
    "published-print": {
      "date-parts": [
        [
          2009,
          9,
          28
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/anie.200901241"
  ],
  "URL": "http://dx.doi.org/10.1002/anie.200901241",
  "relation": {},
  "ISSN": [
    "1433-7851",
    "1521-3773"
  ],
  "subject": [],
  "container-title-short": "Angew Chem Int Ed",
  "published": {
    "date-parts": [
      [
        2009,
        9,
        23
      ]
    ]
  }
}