DOI: 10.1002/anie.200806203. Improving the Hydrogen‐Adsorption Properties of a Hydroxy‐Modified MIL‐53(Al) Structural Analogue by Lithium Doping

Improving the Hydrogen‐Adsorption Properties of a Hydroxy‐Modified MIL‐53(Al) Structural Analogue by Lithium Doping

10.1002/anie.200806203

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Abstract

AbstractLithium makes the difference: A simple strategy for the synthesis of lithium‐doped porous metal–organic frameworks (MOFs) is developed (see structure; C black, O red, AlO6 blue octahedra), thus paving the way for the facile preparation of lithium‐doped MOFs. Moreover, the significant increase in hydrogen adsorption predicted by theoretical calculations is observed.magnified image

Bibliography

Himsl, D., Wallacher, D., & Hartmann, M. (2009). Improving the HydrogenâAdsorption Properties of a HydroxyâModified MILâ53(Al) Structural Analogue by Lithium Doping. Angewandte Chemie International Edition, 48(25), 4639â4642. Portico.

Authors 3

Dieter Himsl (first)
Dirk Wallacher (additional)
Martin Hartmann (additional)

References 58 Referenced 209

10.1016/j.jpowsour.2006.12.073
10.1039/b701563c
10.1039/b808322n
10.1039/b702858j
10.1021/nl072941g
10.1073/pnas.0708603104
10.1021/ja072599
10.1021/jp8021369
10.1021/jp801008d
10.1021/jp7102098
10.1063/1.2971201
10.1063/1.2912525
10.1016/j.cplett.2008.10.081
10.1021/ic800700h
10.1021/ja0740364
10.1021/la803014k
10.1016/S0167-2991(07)81096-2
10.1021/ja052431t
10.1002/ange.200602099
10.1002/anie.200602099
10.1021/ja805222x
10.1021/cg050126d
10.1002/zaac.200600309
10.1021/ic060871v
10.1021/ic060550j
10.1002/ejic.200701284
10.1021/ic801404p
10.1016/j.poly.2007.10.011
10.1039/B516365J
10.1016/j.jssc.2008.07.027
10.1021/ic050999x
One of the compounds exhibits a rather complicated homochiral structure[5a b]which we regarded to be not suitable for introducing lithium alkoxide groups into a MOF under facile experimental conditions. The other[5c]was published after our work was completed (December 2008).
10.1039/b515434k
10.1021/ja045123o
10.1021/ic800623v
10.1039/b711273d
10.1002/chem.200305413
10.1021/ja0276974
10.1021/ja054900x
10.1126/science.1116275
10.1021/ic800538r
10.1021/la8008656
10.1107/S0365110X53000752
10.1107/S0365110X65002517
10.1524/zkri.1973.138.138.19
10.1002/(SICI)1097-458X(199806)36:13<S61::AID-OMR319>3.0.CO;2-D
A. Pepels PhD thesis University of Siegen (Germany) 2001.
10.1039/B308903G
10.1021/ja803669w
10.1002/cphc.200800463

Dates

Type	When
Created	16 years, 3 months ago (May 19, 2009, 9:55 a.m.)
Deposited	1 year, 10 months ago (Sept. 28, 2023, 6 p.m.)
Indexed	4 days, 1 hour ago (Aug. 20, 2025, 8:21 a.m.)
Issued	16 years, 2 months ago (June 3, 2009)
Published	16 years, 2 months ago (June 3, 2009)
Published Online	16 years, 2 months ago (June 3, 2009)
Published Print	16 years, 2 months ago (June 8, 2009)

Funders 0

None

BibTeX

@article{Himsl_2009, title={Improving the Hydrogen‐Adsorption Properties of a Hydroxy‐Modified MIL‐53(Al) Structural Analogue by Lithium Doping}, volume={48}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.200806203}, DOI={10.1002/anie.200806203}, number={25}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Himsl, Dieter and Wallacher, Dirk and Hartmann, Martin}, year={2009}, month=jun, pages={4639–4642} }

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