Abstract
AbstractIonic polymers in action: Conjugated polyelectrolytes are an emerging class of multifunctional polymers that feature π‐conjugated backbones festooned with ionic solubilizing groups. These materials have been exploited in a number of applications, including fluorescent biosensors, polymer light‐emitting diodes, and polymer solar cells. MV2+=methylviologenmagnified imageOrganic optoelectronic polymers have evolved to the point where fine structural control of the conjugated main chain, coupled with solubilizing and property‐modifying pendant substituents, provides an entirely new class of materials. Conjugated polyelectrolytes (CPEs) provide a unique set of properties, including water solubility and processability, main‐chain‐controlled exciton and charge transport, variable band gap light absorption and fluorescence, ionic interactions, and aggregation phenomena. These characteristics allow these materials to be considered for use in applications ranging from light‐emitting diodes and electrochromic color‐changing displays, to photovoltaic devices and photodetectors, along with chemical and biological sensors. This Review describes the evolution of CPE structures from simple polymers to complex materials, describes numerous photophysical aspects, including amplified quenching in macromolecules and aggregates, and illustrates how the physical and electronic properties lead to useful applications in devices.
References
94
Referenced
688
{'key': 'e_1_2_9_1_2', 'volume-title': 'Handbook of Conducting Polymers, Vol.\u20051', 'year': '2007'}
/ Handbook of Conducting Polymers, Vol. 1 (2007){'key': 'e_1_2_9_2_2', 'volume-title': 'Handbook of Conducting Polymers, Vol.\u20052', 'year': '2007'}
/ Handbook of Conducting Polymers, Vol. 2 (2007)10.1055/s-2002-32541
10.1021/ar700115t
10.1021/ja0469737
{'key': 'e_1_2_9_6_2', 'first-page': '14.01', 'volume-title': 'Handbook of Conducting Polymers, Vol.\u20051', 'author': 'Schanze K. S.', 'year': '2007'}
/ Handbook of Conducting Polymers, Vol. 1 by Schanze K. S. (2007){'key': 'e_1_2_9_7_2', 'first-page': '13.01', 'volume-title': 'Handbook of Conducting Polymers, Vol.\u20052', 'author': 'Nilsson P.', 'year': '2007'}
/ Handbook of Conducting Polymers, Vol. 2 by Nilsson P. (2007)10.1021/cr0501339
10.1021/cm049587x
10.1039/b501314c
10.1002/adma.200800533
10.1021/ja00240a044
10.1039/c39870000621
10.1016/0022-0728(88)85176-3
10.1016/S0379-6779(98)00546-3
10.1021/ma047396
10.1021/ja00019a042
10.1021/cr00078a005
10.1016/0032-3861(93)90136-X
10.1021/ma00062a032
10.1002/marc.1995.030160703
10.1002/marc.1994.030150902
10.1021/ma00085a050
10.1021/ma970781x
10.1021/ma960256i
10.1039/a708709h
10.1021/ja000819c
10.1021/ja00131a031
10.1021/ma048360k
10.1021/ma00210a004
10.1073/pnas.96.22.12287
10.1021/ma052741w
10.1039/a904822g
10.1021/ar010092c
10.1021/j100014a003
10.1039/a703723f
{'key': 'e_1_2_9_37_2', 'first-page': '971', 'volume': '36', 'author': 'IV W. T. Slaven', 'year': '1999', 'journal-title': 'J. Mater. Sci. Pure Appl. Chem.'}
/ J. Mater. Sci. Pure Appl. Chem. by IV W. T. Slaven (1999)10.1021/ar9600502
10.1039/b109630c
10.1021/ja046856b
10.1021/la034324n
10.1021/cm062198d
10.1021/la060031t
10.1021/ac701672g
10.1073/pnas.0402280101
10.1021/ac801508y
10.1021/ac801908f
10.1021/ma0611523
10.1021/ja046160i
10.1021/ma010974r
10.1021/ja027152
10.1021/ja0476765
10.1021/ma048780
10.1021/jp0560563
10.1021/ma070070r
10.1021/jo00099a049
10.1021/ol047674p
10.1021/ma062246f
10.1021/ja073216a
10.1021/la060429p
10.1021/jp071307o
10.1021/la701192t
10.1002/adma.200306711
10.1126/science.277.5333.1793
10.1021/ja983995i
10.1021/ja002129e
10.1021/ja00155a023
10.1007/978-1-4757-3061-6
10.1021/ja055630l
10.1073/pnas.012581399
10.1073/pnas.162375999
10.1021/ja0737927
10.1002/asia.200800096
10.1002/adma.200700165
10.1002/ange.200701724
10.1002/anie.200701724
10.1002/adfm.200500602
10.1002/adma.200701637
10.1039/b703856a
10.1039/b706629e
10.1021/la0264926
10.1002/ange.200462431
10.1002/anie.200462431
10.1063/1.363369
10.1002/(SICI)1521-4095(199812)10:17<1452::AID-ADMA1452>3.0.CO;2-V
10.1002/adma.200400963
10.1021/ja072612q
10.1021/ja711068d
10.1016/j.solmat.2004.02.030
10.1126/science.258.5087.1474
{'key': 'e_1_2_9_89_2', 'volume-title': 'Organic Photovoltaics: Concepts and Realization', 'year': '2003'}
/ Organic Photovoltaics: Concepts and Realization (2003)10.1016/S0379-6779(00)01231-5
10.1021/la050599m
10.1021/am800089n
Dates
Type | When |
---|---|
Created | 16 years, 3 months ago (May 14, 2009, 8:17 a.m.) |
Deposited | 1 year, 11 months ago (Sept. 28, 2023, 7:50 p.m.) |
Indexed | 3 days, 19 hours ago (Aug. 27, 2025, 12:13 p.m.) |
Issued | 16 years, 3 months ago (May 26, 2009) |
Published | 16 years, 3 months ago (May 26, 2009) |
Published Online | 16 years, 3 months ago (May 26, 2009) |
Published Print | 16 years, 2 months ago (June 2, 2009) |
@article{Jiang_2009, title={Conjugated Polyelectrolytes: Synthesis, Photophysics, and Applications}, volume={48}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.200805456}, DOI={10.1002/anie.200805456}, number={24}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Jiang, Hui and Taranekar, Prasad and Reynolds, John R. and Schanze, Kirk S.}, year={2009}, month=may, pages={4300–4316} }