DOI: 10.1002/anie.200804836. Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core–Shell Single Crystals with an In‐Plane Rotational Epitaxial Relationship

Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core–Shell Single Crystals with an In‐Plane Rotational Epitaxial Relationship

10.1002/anie.200804836

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Abstract

AbstractMOF on MOF: Core–shell porous coordination polymer (PCP) crystals are fabricated at the single‐crystal level by epitaxial growth in solution. Synchrotron X‐ray diffraction measurements unveiled the structural relationship between the shell crystal and the core crystal, where in‐plane rotational epitaxial growth compensates the difference in lattice constant.magnified image

Bibliography

Furukawa, S., Hirai, K., Nakagawa, K., Takashima, Y., Matsuda, R., Tsuruoka, T., Kondo, M., Haruki, R., Tanaka, D., Sakamoto, H., Shimomura, S., Sakata, O., & Kitagawa, S. (2009). Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic CoreâShell Single Crystals with an InâPlane Rotational Epitaxial Relationship. Angewandte Chemie International Edition, 48(10), 1766â1770. Portico.

Authors 13

Shuhei Furukawa (first)
Kenji Hirai (additional)
Keiji Nakagawa (additional)
Yohei Takashima (additional)
Ryotaro Matsuda (additional)
Takaaki Tsuruoka (additional)
Mio Kondo (additional)
Rie Haruki (additional)
Daisuke Tanaka (additional)
Hirotoshi Sakamoto (additional)
Satoru Shimomura (additional)
Osami Sakata (additional)
Susumu Kitagawa (additional)

References 60 Referenced 301

10.1038/nature01362
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The yield of the hybridization was estimated as following: one hundred core crystals were used for the reaction in the same manner as described in the Experimental Section. A total of 93 light greenish (hybridized) crystals were counted out of one hundred core crystals. The yield was thus calculated as 93 %.
10.1016/S0020-1693(00)90852-1
10.1039/dt9860001283
10.1366/000370273774333966
These unit cell parameters for both1and2are estimated by X‐ray crystal structure analyses for guest‐free porous frameworks. See the Supporting Information for details of the structural analysis for2.
Since frameworks measured herein (1and1/2) most likely contained DMF molecules as guests in the pores giving different unit cell parameters from those of the guest‐free frameworks comparison of the absolute values of each angle in Table S1 in the Supporting Information should be avoided. The difference of the lattice constant between the core crystal and the shell crystal along thea axis is significantly larger than that between the guest‐free framework and the guest‐captured framework as estimated in framework1 for which the crystal structures of both states have been determined.[6d]Therefore we concluded that the effect of guest accommodation on the lattice shrinkage is negligible. See the Supporting Information for details of the comparison of the structural parameters of1and2.
The 2θangles are refined by the peaks in thek o hscans as summarized in Table S1 in the Supporting Information. The same explanation as in footnote [12] is applicable.
The formation of such Miller domains on the well‐defined surface is often observed in two‐dimensional crystals constructed from assembled organic molecules at solid–liquid interfaces see:
10.1039/B201099M
10.1039/b206566p

Dates

Type	When
Created	16 years, 8 months ago (Dec. 12, 2008, 12:21 p.m.)
Deposited	1 year, 10 months ago (Sept. 28, 2023, 6:07 p.m.)
Indexed	3 weeks, 3 days ago (July 28, 2025, 2:38 a.m.)
Issued	16 years, 6 months ago (Feb. 17, 2009)
Published	16 years, 6 months ago (Feb. 17, 2009)
Published Online	16 years, 6 months ago (Feb. 17, 2009)
Published Print	16 years, 5 months ago (Feb. 23, 2009)

Funders 0

None

BibTeX

@article{Furukawa_2009, title={Heterogeneously Hybridized Porous Coordination Polymer Crystals: Fabrication of Heterometallic Core–Shell Single Crystals with an In‐Plane Rotational Epitaxial Relationship}, volume={48}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.200804836}, DOI={10.1002/anie.200804836}, number={10}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Furukawa, Shuhei and Hirai, Kenji and Nakagawa, Keiji and Takashima, Yohei and Matsuda, Ryotaro and Tsuruoka, Takaaki and Kondo, Mio and Haruki, Rie and Tanaka, Daisuke and Sakamoto, Hirotoshi and Shimomura, Satoru and Sakata, Osami and Kitagawa, Susumu}, year={2009}, month=feb, pages={1766–1770} }

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