DOI: 10.1002/anie.200802659. Molecular Catalysts that Oxidize Water to Dioxygen

Molecular Catalysts that Oxidize Water to Dioxygen

10.1002/anie.200802659

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Abstract

AbstractWater into oxygen: A good catalyst for converting water into oxygen is seen as an essential part of any sustainable solar‐energy conversion scheme. Some success has been achieved using molecular complexes as catalysts and the key factors influencing their performance are discussed. The necessity of generating a solid‐state catalytic system is presented and the first attempts to generate supported molecular water‐oxidation catalysts are analyzed.magnified imageDuring the past four years we have witnessed a revolution in the field of water‐oxidation catalysis, in which well‐defined molecules are opening up entirely new possibilities for the design of more rugged and efficient catalysts. This revolution has been stimulated by two factors: the urgent need for clean and renewable fuel and the intrinsic human desire to mimic nature's reactions, in this case the oxygen‐evolving complex (OEC) of the photosystem II (PSII). Herein we give a short general overview of the established basis for the oxidation of water to dioxygen as well as presenting the new developments in the field. Furthermore, we describe the new avenues these developments are opening up with regard to catalyst design and performance, together with the new questions they pose, especially from a mechanistic perspective. Finally the challenges the field is facing are also discussed.

Bibliography

Sala, X., Romero, I., RodrÃguez, M., Escriche, L., & Llobet, A. (2009). Molecular Catalysts that Oxidize Water to Dioxygen. Angewandte Chemie International Edition, 48(16), 2842â2852. Portico.

Authors 5

Xavier Sala (first)
Isabel Romero (additional)
Montserrat Rodríguez (additional)
Lluís Escriche (additional)
Antoni Llobet (additional)

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Dates

Type	When
Created	16 years, 7 months ago (Jan. 22, 2009, 8:23 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 1:55 a.m.)
Indexed	1 month ago (Aug. 2, 2025, 1:19 a.m.)
Issued	16 years, 5 months ago (March 30, 2009)
Published	16 years, 5 months ago (March 30, 2009)
Published Online	16 years, 5 months ago (March 30, 2009)
Published Print	16 years, 5 months ago (April 6, 2009)

Funders 0

None

BibTeX

@article{Sala_2009, title={Molecular Catalysts that Oxidize Water to Dioxygen}, volume={48}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.200802659}, DOI={10.1002/anie.200802659}, number={16}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Sala, Xavier and Romero, Isabel and Rodríguez, Montserrat and Escriche, Lluís and Llobet, Antoni}, year={2009}, month=mar, pages={2842–2852} }

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