DOI: 10.1002/anie.200705624. Iron‐Catalyzed Enantioselective Hydrosilylation of Ketones

Iron‐Catalyzed Enantioselective Hydrosilylation of Ketones

10.1002/anie.200705624

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Bibliography

Shaikh, N. S., Enthaler, S., Junge, K., & Beller, M. (2008). IronâCatalyzed Enantioselective Hydrosilylation of Ketones. Angewandte Chemie International Edition, 47(13), 2497â2501. Portico.

Authors 4

Nadim S. Shaikh (first)
Stephan Enthaler (additional)
Kathrin Junge (additional)
Matthias Beller (additional)

References 69 Referenced 256

{'key': 'e_1_2_4_2_2', 'volume-title': 'Comprehensive Asymmetric Catalysis', 'year': '1999'} / Comprehensive Asymmetric Catalysis (1999)
{'key': 'e_1_2_4_3_2', 'volume-title': 'Asymmetric Catalysis in Organic Synthesis', 'author': 'Noyori R.', 'year': '1994'} / Asymmetric Catalysis in Organic Synthesis by Noyori R. (1994)
10.1002/1521-3757(20010105)113:1<40::AID-ANGE40>3.0.CO;2-K
10.1002/1521-3773(20010105)40:1<40::AID-ANIE40>3.0.CO;2-5
10.1021/op049838n
10.1002/0471721506.ch1
{'key': 'e_1_2_4_8_2', 'volume-title': 'Transition Metals for Organic Synthesis', 'year': '2004'} / Transition Metals for Organic Synthesis (2004)
{'key': 'e_1_2_4_10_2', 'volume-title': 'Comprehensive Asymmetric Catalysis', 'author': 'Nishiyama H.', 'year': '1999'} / Comprehensive Asymmetric Catalysis by Nishiyama H. (1999)
{'key': 'e_1_2_4_11_2', 'volume-title': 'Catalytic Asymmetric Synthesis', 'author': 'Brunner H.', 'year': '1993'} / Catalytic Asymmetric Synthesis by Brunner H. (1993)
10.1021/ja00806a015
10.1039/c3972000938a
10.1246/bcsj.45.3506
Leading references for hydrosilylation employing rhodium catalysts:
10.1021/om00105a047
10.1002/ange.19941060114
10.1002/anie.199401111
10.1002/1521-3757(20021018)114:20<4048::AID-ANGE4048>3.0.CO;2-5
10.1002/1521-3773(20021018)41:20<3892::AID-ANIE3892>3.0.CO;2-A
10.1002/ange.200353133
10.1002/anie.200353133
Leading references for hydrosilylation by using ruthenium catalysts:
10.1016/S0022-328X(97)00201-5
10.1021/om980399o
10.1021/om050323
Hydrosilylation by using titanium catalysts:
10.1021/ja990450v
10.1021/ja990522i
10.1016/S0040-4039(00)00652-3
10.1016/0022-328X(84)85066-4
10.1021/ja021391f
10.1002/adsc.200606152
10.1016/j.tetlet.2004.05.048
10.1021/ol0169170
10.1021/ol026755n
10.1002/ange.200703053
10.1002/anie.200703053
Selected reports on iron catalysis from our group. Transfer hydrogenation of ketones:
10.1016/j.tetlet.2006.09.058
10.1002/asia.200600105
10.1039/B612048B
10.1002/ange.200701235
10.1002/anie.200701235
10.1002/ange.200703418
10.1002/anie.200703418
10.1021/ol0523143
10.1002/ange.200462522
10.1002/anie.200462522
10.1023/A:1020259021641
An excellent review on iron catalysis:
10.1021/cr040664h
Iron Catalysis(Ed.: B. Plietker) Wiley‐VCH Weinheim 2008in press.
10.1039/B617388H
10.1021/ol7021802
Duphos was formerly used in asymmetric hydrogenation:
10.1021/ja953872n
10.1021/ja974278b
10.1021/jo049723h
10.1039/b505271h
PMHS was discovered as a stoichiometric reductant with reduced toxicity and reagent cost:
10.1021/jo00094a056
10.1039/a903662h
10.1021/ja011529e
10.1073/pnas.0409043102
According to GC‐MS analysis of the crude reaction mixture 1 4‐reduction is observed.

Dates

Type	When
Created	17 years, 6 months ago (Feb. 22, 2008, 10:47 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 10:42 a.m.)
Indexed	1 month, 4 weeks ago (July 9, 2025, 6:51 p.m.)
Issued	17 years, 5 months ago (March 10, 2008)
Published	17 years, 5 months ago (March 10, 2008)
Published Online	17 years, 5 months ago (March 10, 2008)
Published Print	17 years, 5 months ago (March 14, 2008)

Funders 0

None

BibTeX

@article{Shaikh_2008, title={Iron‐Catalyzed Enantioselective Hydrosilylation of Ketones}, volume={47}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.200705624}, DOI={10.1002/anie.200705624}, number={13}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Shaikh, Nadim S. and Enthaler, Stephan and Junge, Kathrin and Beller, Matthias}, year={2008}, month=mar, pages={2497–2501} }

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