DOI: 10.1002/anie.200703710. Mercury Is a Transition Metal: The First Experimental Evidence for HgF<sub>4</sub>

Mercury Is a Transition Metal: The First Experimental Evidence for HgF4

10.1002/anie.200703710

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Bibliography

Wang, X., Andrews, L., Riedel, S., & Kaupp, M. (2007). Mercury Is a Transition Metal: The First Experimental Evidence for HgF4. Angewandte Chemie International Edition, 46(44), 8371â8375. Portico.

Authors 4

Xuefang Wang (first)
Lester Andrews (additional)
Sebastian Riedel (additional)
Martin Kaupp (additional)

References 54 Referenced 123

{'key': 'e_1_2_3_1_2', 'volume-title': 'Chemistry of the Elements', 'author': 'Greenwood N. N.', 'year': '1984'} / Chemistry of the Elements by Greenwood N. N. (1984)
{'key': 'e_1_2_3_2_2', 'volume-title': 'Advanced Inorganic Chemsitry', 'author': 'Cotton F. A.', 'year': '1999'} / Advanced Inorganic Chemsitry by Cotton F. A. (1999)
10.1021/ja00430a020
10.1051/jcp/1979760630
10.1002/zaac.19865400912
10.1002/ange.19931050639
10.1002/anie.199308611
10.1021/ic00088a012
10.1039/b315019d
Computed reaction energies at 0 K for the reaction HgF4→HgF2+F2at CCSD(T)/aug‐cc‐pVQZ (B3LYP/aug‐cc‐pVTZ) level are +27.4 kJ mol−1(+45.9 kJ mol−1). Thermochemical data at higher temperature at the B3 LYP/aug‐cc‐pVTZ level are:
10 K ΔH=−5.5 kJ mol−1 ΔS=0.08 kJ mol−1 K−1 ΔG=−6.3 kJ mol−1.
298.15 K ΔH°=−2.8 kJ mol−1 ΔS°=0.14 kJ mol−1 K−1 ΔG°=−44.5 kJ mol−1.
10.1016/S0009-2614(99)00147-5
10.1039/B203585E
10.1002/chem.200401130
10.1063/1.473437
For example see: K. Millington PhD Thesis University of Southampton (United Kingdom) 1987and
I. R. Beattie personal communication to M.K. 1993.
10.1063/1.459165
10.1021/ja01096a006
10.1063/1.448747
10.1021/ja00255a004
10.1063/1.439596
10.1021/ja00451a024
10.1016/0022-2852(80)90240-4
10.1021/jp046414m
{'key': 'e_1_2_3_25_2', 'first-page': '76', 'volume': '1', 'author': 'Hastie J. W.', 'year': '1969', 'journal-title': 'High Temp. Sci.'} / High Temp. Sci. by Hastie J. W. (1969)
10.1016/0301-0104(94)00143-X
10.1016/0022-2852(87)90100-7
10.1021/j100882a031
10.1007/BF00746871
10.1007/978-1-4757-0961-2
10.1021/ic00090a014
10.1021/om020789h
10.1002/ange.200600274
10.1002/anie.200600274
10.1021/ic051944y
10.1021/ic700431s
10.1021/ic048673w
10.1039/b210547k
10.1039/b412373e
Gaussian03 Revision B.04 M. J. Frisch G. W. Trucks H. B. Schlegel G. E. Scuseria M. A. Robb J. R. Cheeseman J. A. Montgomery J. T. Vreven K. N. Kudin J. C. Burant J. M. Millam S. S. Iyengar J. Tomasi V. Barone B. Mennucci M. Cossi G. Scalmani N. Rega G. A. Petersson H. Nakatsuji M. Hada M. Ehara K. Toyota R. Fukuda J. Hasegawa M. Ishida T. Nakajima Y. Honda O. Kitao H. Nakai M. Klene X. Li J. E. Knox H. P. Hratchian J. B. Cross C. Adamo J. Jaramillo R. Gomperts R. E. Stratmann O. Yazyev A. J. Austin R. Cammi C. Pomelli J. W. Ochterski P. Y. Ayala K. Morokuma G. A. Voth P. Salvador J. J. Dannenberg V. G. Zakrzewski S. Dapprich A. D. Daniels M. C. Strain O. Farkas D. K. Malick A. D. Rabuck K. Raghavachari J. B. Foresman J. V. Ortiz Q. Cui A. G. Baboul S. Clifford J. Cioslowski B. B. Stefanov G. Liu A. Liashenko P. Piskorz I. Komaromi R. L. Martin D. J. Fox T. Keith M. A. Al‐Laham C. Y. Peng A. Nanayakkara M. Challacombe P. M. W. Gill B. Johnson W. Chen M. W. Wong C. Gonzalez J. A. Pople Gaussian Inc. Pittsburgh PA 2003.
10.1063/1.464913
10.1103/PhysRevB.37.785
10.1016/0009-2614(89)87234-3
MOLPRO 2006.1 ed. H.‐J. Werner P. J. Knowles R. Lindh F. R. Manby M. Schütz P. Celani T. Korona G. Rauhut R. D. Amos A. Bernhardsson A. Berning D. L. Cooper M. J. O. Deegan A. J. Dobbyn F. Eckert C. Hampel G. Hetzer A. W. Lloyd S. J. McNicholas W. Meyer M. E. Mura A. Nicklaß P. Palmieri R. Pitzer U. Schumann H. Stoll A. J. Stone R. Tarroni T. Thorsteinsson Birmingham UK 2006.
10.1080/00268979300100801
10.1063/1.1337864
10.1063/1.456153
10.1002/jcc.540141112
10.1063/1.458517
10.1002/ange.19911030410
10.1002/anie.199104091
10.2533/chimia.2000.766

Dates

Type	When
Created	17 years, 11 months ago (Sept. 26, 2007, 2:47 p.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 5:30 p.m.)
Indexed	6 days, 13 hours ago (Aug. 26, 2025, 3:11 a.m.)
Issued	17 years, 9 months ago (Nov. 2, 2007)
Published	17 years, 9 months ago (Nov. 2, 2007)
Published Online	17 years, 9 months ago (Nov. 2, 2007)
Published Print	17 years, 9 months ago (Nov. 12, 2007)

Funders 0

None

BibTeX

@article{Wang_2007, title={Mercury Is a Transition Metal: The First Experimental Evidence for HgF4}, volume={46}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.200703710}, DOI={10.1002/anie.200703710}, number={44}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Wang, Xuefang and Andrews, Lester and Riedel, Sebastian and Kaupp, Martin}, year={2007}, month=nov, pages={8371–8375} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        26
      ]
    ],
    "date-time": "2025-08-26T07:11:52Z",
    "timestamp": 1756192312625
  },
  "reference-count": 54,
  "publisher": "Wiley",
  "issue": "44",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2007,
            9,
            26
          ]
        ],
        "date-time": "2007-09-26T00:00:00Z",
        "timestamp": 1190764800000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2007,
        11,
        12
      ]
    ]
  },
  "DOI": "10.1002/anie.200703710",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2007,
        9,
        26
      ]
    ],
    "date-time": "2007-09-26T18:47:50Z",
    "timestamp": 1190832470000
  },
  "page": "8371-8375",
  "source": "Crossref",
  "is-referenced-by-count": 123,
  "title": "Mercury Is a Transition Metal: The First Experimental Evidence for HgF<sub>4</sub>",
  "prefix": "10.1002",
  "volume": "46",
  "author": [
    {
      "given": "Xuefang",
      "family": "Wang",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Lester",
      "family": "Andrews",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Sebastian",
      "family": "Riedel",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Martin",
      "family": "Kaupp",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2007,
        11,
        2
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_3_1_2",
      "volume-title": "Chemistry of the Elements",
      "author": "Greenwood N. N.",
      "year": "1984"
    },
    {
      "key": "e_1_2_3_2_2",
      "volume-title": "Advanced Inorganic Chemsitry",
      "author": "Cotton F. A.",
      "year": "1999"
    },
    {
      "key": "e_1_2_3_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00430a020"
    },
    {
      "key": "e_1_2_3_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1051/jcp/1979760630"
    },
    {
      "key": "e_1_2_3_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/zaac.19865400912"
    },
    {
      "key": "e_1_2_3_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.19931050639"
    },
    {
      "key": "e_1_2_3_6_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.199308611"
    },
    {
      "key": "e_1_2_3_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic00088a012"
    },
    {
      "key": "e_1_2_3_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/b315019d"
    },
    {
      "key": "e_1_2_3_9_2",
      "unstructured": "Computed reaction energies at 0\u2005K for the reaction HgF4\u2192HgF2+F2at CCSD(T)/aug\u2010cc\u2010pVQZ (B3LYP/aug\u2010cc\u2010pVTZ) level are +27.4\u2005kJ\u2009mol\u22121(+45.9\u2005kJ\u2009mol\u22121). Thermochemical data at higher temperature at the B3\u2009LYP/aug\u2010cc\u2010pVTZ level are:"
    },
    {
      "key": "e_1_2_3_10_2",
      "unstructured": "10\u2005K \u0394H=\u22125.5\u2005kJ\u2009mol\u22121 \u0394S=0.08\u2005kJ\u2009mol\u22121\u2009K\u22121 \u0394G=\u22126.3\u2005kJ\u2009mol\u22121."
    },
    {
      "key": "e_1_2_3_11_2",
      "unstructured": "298.15\u2005K \u0394H\u00b0=\u22122.8\u2005kJ\u2009mol\u22121 \u0394S\u00b0=0.14\u2005kJ\u2009mol\u22121\u2009K\u22121 \u0394G\u00b0=\u221244.5\u2005kJ\u2009mol\u22121."
    },
    {
      "key": "e_1_2_3_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0009-2614(99)00147-5"
    },
    {
      "key": "e_1_2_3_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/B203585E"
    },
    {
      "key": "e_1_2_3_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/chem.200401130"
    },
    {
      "key": "e_1_2_3_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.473437"
    },
    {
      "key": "e_1_2_3_16_2",
      "unstructured": "For example see: K. Millington PhD Thesis University of Southampton (United Kingdom) 1987and"
    },
    {
      "key": "e_1_2_3_16_3",
      "unstructured": "I.\u2005R. Beattie personal communication to M.K. 1993."
    },
    {
      "key": "e_1_2_3_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.459165"
    },
    {
      "key": "e_1_2_3_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja01096a006"
    },
    {
      "key": "e_1_2_3_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.448747"
    },
    {
      "key": "e_1_2_3_20_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00255a004"
    },
    {
      "key": "e_1_2_3_21_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.439596"
    },
    {
      "key": "e_1_2_3_22_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja00451a024"
    },
    {
      "key": "e_1_2_3_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-2852(80)90240-4"
    },
    {
      "key": "e_1_2_3_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp046414m"
    },
    {
      "key": "e_1_2_3_25_2",
      "first-page": "76",
      "volume": "1",
      "author": "Hastie J. W.",
      "year": "1969",
      "journal-title": "High Temp. Sci."
    },
    {
      "key": "e_1_2_3_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0301-0104(94)00143-X"
    },
    {
      "key": "e_1_2_3_27_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0022-2852(87)90100-7"
    },
    {
      "key": "e_1_2_3_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100882a031"
    },
    {
      "key": "e_1_2_3_29_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/BF00746871"
    },
    {
      "key": "e_1_2_3_30_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/978-1-4757-0961-2"
    },
    {
      "key": "e_1_2_3_31_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic00090a014"
    },
    {
      "key": "e_1_2_3_32_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/om020789h"
    },
    {
      "key": "e_1_2_3_33_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.200600274"
    },
    {
      "key": "e_1_2_3_33_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200600274"
    },
    {
      "key": "e_1_2_3_34_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic051944y"
    },
    {
      "key": "e_1_2_3_35_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic700431s"
    },
    {
      "key": "e_1_2_3_36_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic048673w"
    },
    {
      "key": "e_1_2_3_37_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/b210547k"
    },
    {
      "key": "e_1_2_3_38_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/b412373e"
    },
    {
      "key": "e_1_2_3_39_2",
      "unstructured": "Gaussian03 Revision\u2009B.04 M.\u2005J. Frisch G.\u2005W. Trucks H.\u2005B. Schlegel G.\u2005E. Scuseria M.\u2005A. Robb J.\u2005R. Cheeseman J.\u2005A. Montgomery J.\u2005T. Vreven K.\u2005N. Kudin J.\u2005C. Burant J.\u2005M. Millam S.\u2005S. Iyengar J. Tomasi V. Barone B. Mennucci M. Cossi G. Scalmani N. Rega G.\u2005A. Petersson H. Nakatsuji M. Hada M. Ehara K. Toyota R. Fukuda J. Hasegawa M. Ishida T. Nakajima Y. Honda O. Kitao H. Nakai M. Klene X. Li J.\u2005E. Knox H.\u2005P. Hratchian J.\u2005B. Cross C. Adamo J. Jaramillo R. Gomperts R.\u2005E. Stratmann O. Yazyev A.\u2005J. Austin R. Cammi C. Pomelli J.\u2005W. Ochterski P.\u2005Y. Ayala K. Morokuma G.\u2005A. Voth P. Salvador J.\u2005J. Dannenberg V.\u2005G. Zakrzewski S. Dapprich A.\u2005D. Daniels M.\u2005C. Strain O. Farkas D.\u2005K. Malick A.\u2005D. Rabuck K. Raghavachari J.\u2005B. Foresman J.\u2005V. Ortiz Q. Cui A.\u2005G. Baboul S. Clifford J. Cioslowski B.\u2005B. Stefanov G. Liu A. Liashenko P. Piskorz I. Komaromi R.\u2005L. Martin D.\u2005J. Fox T. Keith M.\u2005A. Al\u2010Laham C.\u2005Y. Peng A. Nanayakkara M. Challacombe P.\u2005M.\u2005W. Gill B. Johnson W. Chen M.\u2005W. Wong C. Gonzalez J.\u2005A. Pople Gaussian Inc. Pittsburgh PA 2003."
    },
    {
      "key": "e_1_2_3_40_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.464913"
    },
    {
      "key": "e_1_2_3_41_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.37.785"
    },
    {
      "key": "e_1_2_3_42_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0009-2614(89)87234-3"
    },
    {
      "key": "e_1_2_3_43_2",
      "unstructured": "MOLPRO 2006.1 ed. H.\u2010J. Werner P.\u2005J. Knowles R. Lindh F.\u2005R. Manby M. Sch\u00fctz P. Celani T. Korona G. Rauhut R.\u2005D. Amos A. Bernhardsson A. Berning D.\u2005L. Cooper M.\u2005J.\u2005O. Deegan A.\u2005J. Dobbyn F. Eckert C. Hampel G. Hetzer A.\u2005W. Lloyd S.\u2005J. McNicholas W. Meyer M.\u2005E. Mura A. Nickla\u00df P. Palmieri R. Pitzer U. Schumann H. Stoll A.\u2005J. Stone R. Tarroni T. Thorsteinsson Birmingham UK 2006."
    },
    {
      "key": "e_1_2_3_44_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1080/00268979300100801"
    },
    {
      "key": "e_1_2_3_45_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1337864"
    },
    {
      "key": "e_1_2_3_46_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.456153"
    },
    {
      "key": "e_1_2_3_47_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/jcc.540141112"
    },
    {
      "key": "e_1_2_3_48_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.458517"
    },
    {
      "key": "e_1_2_3_49_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.19911030410"
    },
    {
      "key": "e_1_2_3_49_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.199104091"
    },
    {
      "key": "e_1_2_3_50_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.2533/chimia.2000.766"
    }
  ],
  "container-title": "Angewandte Chemie International Edition",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.200703710",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.200703710",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        16
      ]
    ],
    "date-time": "2023-10-16T21:30:48Z",
    "timestamp": 1697491848000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/anie.200703710"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2007,
        11,
        2
      ]
    ]
  },
  "references-count": 54,
  "journal-issue": {
    "issue": "44",
    "published-print": {
      "date-parts": [
        [
          2007,
          11,
          12
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/anie.200703710"
  ],
  "URL": "http://dx.doi.org/10.1002/anie.200703710",
  "relation": {},
  "ISSN": [
    "1433-7851",
    "1521-3773"
  ],
  "subject": [],
  "container-title-short": "Angew Chem Int Ed",
  "published": {
    "date-parts": [
      [
        2007,
        11,
        2
      ]
    ]
  }
}