Crossref
journal-article
Wiley
Angewandte Chemie International Edition (311)
References
61
Referenced
144
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- Compound1is composed of dinuclear Zn2units (with a paddle‐wheel structure) which are bridged by 1 4‐bdc to form 2D square‐grid {[Zn2(1 4‐bdc)2]n}. The axial sites of the Zn2paddle wheels are occupied by dabco molecules which act as pillars to extend the 2D layers into a 3D structure. Three kinds of crystal structures namely 1⊃4 DMF⋅1/2 H2O 1 and1⊃2 C6H6(depending on the guest molecules) have been reported.
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- The reflections of1′were indexed with an orthorhombic cell; orthorhombic a=10.91(2) Å b=10.73(2) Å c=9.57(5) Å V=1122 Å3.
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- d(lnP)/d(T−1)=ΔHad/Rfor the adsorption process whereRand ΔHaddenote the gas constant and the adsorption enthalpy of the guest respectively.
- The corresponding desorption enthalpy is estimated as 89.3 kJ mol−1.
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Dates
Type | When |
---|---|
Created | 18 years ago (July 30, 2007, 11:49 a.m.) |
Deposited | 1 year, 10 months ago (Oct. 16, 2023, 7:51 a.m.) |
Indexed | 1 month, 2 weeks ago (July 6, 2025, 10:05 a.m.) |
Issued | 17 years, 11 months ago (Aug. 28, 2007) |
Published | 17 years, 11 months ago (Aug. 28, 2007) |
Published Online | 17 years, 11 months ago (Aug. 28, 2007) |
Published Print | 17 years, 11 months ago (Sept. 3, 2007) |
@article{Uemura_2007, title={Two‐Step Adsorption/Desorption on a Jungle‐Gym‐Type Porous Coordination Polymer}, volume={46}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.200702390}, DOI={10.1002/anie.200702390}, number={35}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Uemura, Kazuhiro and Yamasaki, Yukari and Komagawa, Yuki and Tanaka, Kazuhiro and Kita, Hidetoshi}, year={2007}, month=aug, pages={6662–6665} }