DOI: 10.1002/anie.200702278. Highly Diastereoselective Formation of Ruthenium Complexes for Efficient Catalytic Asymmetric Transfer Hydrogenation

Highly Diastereoselective Formation of Ruthenium Complexes for Efficient Catalytic Asymmetric Transfer Hydrogenation

10.1002/anie.200702278

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Bibliography

Baratta, W., Chelucci, G., Herdtweck, E., Magnolia, S., Siega, K., & Rigo, P. (2007). Highly Diastereoselective Formation of Ruthenium Complexes for Efficient Catalytic Asymmetric Transfer Hydrogenation. Angewandte Chemie International Edition, 46(40), 7651â7654. Portico.

Authors 6

Walter Baratta (first)
Giorgio Chelucci (additional)
Eberhardt Herdtweck (additional)
Santo Magnolia (additional)
Katia Siega (additional)
Pierluigi Rigo (additional)

References 49 Referenced 114

{'key': 'e_1_2_3_2_2', 'volume-title': 'The Handbook of Homogeneous Hydrogenation, Vol.\u20051–3', 'year': '2007'} / The Handbook of Homogeneous Hydrogenation, Vol. 1–3 (2007)
{'key': 'e_1_2_3_3_2', 'volume-title': 'Asymmetric Catalysis on Industrial Scale', 'year': '2004'} / Asymmetric Catalysis on Industrial Scale (2004)
{'key': 'e_1_2_3_4_2', 'volume-title': 'Comprehensive Asymmetric Catalysis', 'year': '2004'} / Comprehensive Asymmetric Catalysis (2004)
10.1002/0471721506
10.1002/(SICI)1521-3757(19980619)110:12<1792::AID-ANGE1792>3.0.CO;2-9
10.1002/(SICI)1521-3773(19980703)37:12<1703::AID-ANIE1703>3.0.CO;2-I
10.1002/1521-3757(20010105)113:1<40::AID-ANGE40>3.0.CO;2-K
10.1002/1521-3773(20010105)40:1<40::AID-ANIE40>3.0.CO;2-5
10.1021/cr0200318
10.1021/cr0000630
10.1002/1521-3765(20000703)6:13<2309::AID-CHEM2309>3.0.CO;2-N
10.1021/ar9900818
10.1021/ja972897e
10.1021/ja952115m
10.1021/ja00184a087
10.1021/cr000260z
10.1021/om0491701
10.1021/ja052071
10.1002/ange.200454199
10.1002/anie.200454199
10.1021/om049408l
10.1016/j.jorganchem.2005.07.001
10.1039/b515269k
10.1039/B513396C
10.1016/j.ccr.2004.04.007
10.1039/a808170k
10.1021/om960955j
10.1002/(SICI)1521-3757(20000218)112:4<759::AID-ANGE759>3.0.CO;2-K
10.1002/(SICI)1521-3773(20000218)39:4<743::AID-ANIE743>3.0.CO;2-I
For a review on the stereoselective synthesis of optically active 1‐substituted‐1‐(pyridin‐2‐yl)methanamines see:
10.1016/j.tetasy.2005.05.026
10.1016/S0957-4166(97)00330-3
10.1021/ja00784a030
[Ru]/Josiphos/Pyme=1:1.5:1; acetophenone/Ru/NaOiPr=2000:1:40; TOF at 50 % conversion.
NMR spectroscopic data for1–5and the X‐ray crystal analysis of1and2are provided asSupporting Information.
31P{1H} NMR spectrum in toluene with CD2Cl2(10 % in volume) as internal lock:δ=61.6 (d 2J(P P)=40.9 Hz) and 41.1 ppm (d 2J(P P)=40.9 Hz) compound1 major product;δ=59.2 (d 2J(P P)=38.6 Hz) and 39.2 ppm (d 2J(P P)=38.6 Hz);δ=58.8 (d 2J(P P)=39.3 Hz) and 47.4 ppm (d 2J(P P)=39.3 Hz) minor product.
31P NMR spectrum in CD2Cl2:δ=49.2 (d 2J(P P)=38.5 Hz) and 46.8 ppm (d 2J(P P)=38.5 Hz).
10.1002/1521-3765(20011203)7:23<5052::AID-CHEM5052>3.0.CO;2-Z
10.1039/a809236b
10.1002/ange.200502118
10.1002/anie.200502118

Dates

Type	When
Created	18 years ago (Aug. 27, 2007, 7:51 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 10:16 a.m.)
Indexed	1 month ago (July 30, 2025, 11:23 a.m.)
Issued	17 years, 11 months ago (Sept. 28, 2007)
Published	17 years, 11 months ago (Sept. 28, 2007)
Published Online	17 years, 11 months ago (Sept. 28, 2007)
Published Print	17 years, 10 months ago (Oct. 8, 2007)

Funders 0

None

BibTeX

@article{Baratta_2007, title={Highly Diastereoselective Formation of Ruthenium Complexes for Efficient Catalytic Asymmetric Transfer Hydrogenation}, volume={46}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.200702278}, DOI={10.1002/anie.200702278}, number={40}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Baratta, Walter and Chelucci, Giorgio and Herdtweck, Eberhardt and Magnolia, Santo and Siega, Katia and Rigo, Pierluigi}, year={2007}, month=sep, pages={7651–7654} }

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