DOI: 10.1002/anie.200604306. Assembly of Metal–Organic Frameworks (MOFs) Based on Indium‐Trimer Building Blocks: A Porous MOF with soc Topology and High Hydrogen Storage

Assembly of Metal–Organic Frameworks (MOFs) Based on Indium‐Trimer Building Blocks: A Porous MOF with soc Topology and High Hydrogen Storage

10.1002/anie.200604306

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Bibliography

Liu, Y., Eubank, J. F., Cairns, A. J., Eckert, J., Kravtsov, V. Ch., Luebke, R., & Eddaoudi, M. (2007). Assembly of MetalâOrganic Frameworks (MOFs) Based on IndiumâTrimer Building Blocks: A Porous MOF with soc Topology and High Hydrogen Storage. Angewandte Chemie International Edition, 46(18), 3278â3283. Portico.

Authors 7

Yunling Liu (first)
Jarrod F. Eubank (additional)
Amy J. Cairns (additional)
Juergen Eckert (additional)
Victor Ch. Kravtsov (additional)
Ryan Luebke (additional)
Mohamed Eddaoudi (additional)

References 72 Referenced 648

10.1021/ar040153h
10.1002/anie.200300636
10.1038/38985
10.1002/(SICI)1521-3757(19991115)111:22<3466::AID-ANGE3466>3.0.CO;2-M
10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO;2-U
10.1021/cr9900432
10.1021/ar010142d
10.1021/ar040163i
10.1021/ja052431t
10.1002/ange.200300610
10.1002/anie.200300610
10.1021/ar9703138
10.1021/ar0001012
10.1002/ange.200461408
10.1002/anie.200461408
10.1126/science.1083440
10.1021/ja051168t
10.1039/B308903G
10.1002/ange.200460712
10.1002/anie.200460712
10.1126/science.1101982
10.1126/science.1120411
10.1039/b600188m
10.1021/ja051259q
10.1039/B409459J
10.1016/j.molstruc.2006.02.064
10.1021/ar000034b
10.1002/1521-3757(20020802)114:15<2945::AID-ANGE2945>3.0.CO;2-4
10.1002/1521-3773(20020802)41:15<2821::AID-ANIE2821>3.0.CO;2-Y
10.1073/pnas.082051899
10.1021/ja9639473
10.1038/46248
Y. Liu M. Eddaoudi unpublished results.
10.1107/S0108768102003890
10.1039/a702287e
10.1021/ja974172g
10.1038/35010088
10.1039/b202749f
10.1002/ange.200460592
10.1002/anie.200460592
10.1021/ic050064g
10.1126/science.1116275
10.1002/ange.200454250
10.1002/anie.200454250
10.1016/j.materresbull.2006.01.022
Preparation of1: 1 3‐H2BDC (30.0 mg 0.174 mmol) In(NO3)3⋅2 H2O (30.0 mg 0.087 mmol) DMF (1 mL) CH3CN (1 mL) imidazole (0.2 mL 0.90 Min DMF) and HNO3(0.2 mL 2.7 Min DMF) were added to a vial and the solution was heated to 85 °C for 12 h and then at 100 °C for 20 h. Colorless cubic crystals were collected and air‐dried (23.5 mg 75 % yield). The as‐synthesized material is insoluble in H2O and common organic solvents. Elemental analysis calcd (%) for1 C32.5H28.5N4.5O15.5In3: C 36.33 H 2.67 N 5.87; found: C 36.15 H 2.82 N 5.92.
Crystallographic data of1: C32.5H28.5In3N4.5O15.5 Mr=1074.56 cubic Pa$\bar 3$ a=19.5514(9) Å V=7473.7(6) Å3 Z=8 ρcalcd=1.910 g cm−3 2θmax=54.98° (−10≤h≤25 −15≤k≤16 −25≤l≤23) T=100 K 20 484 measured reflections R1=0.0520 wR2=0.1319 for 2436 reflections (I>2σ(I)) andR1=0.0649 wR2=0.1387 for 2870 independent reflections (all data) and 177 parameters GOF=1.016. Data were collected on a Bruker SMART‐APEX CCD diffractometer using MoKαradiation (λ=0.71073 Å) operating in theωandφscan mode and corrected for Lorentz and polarization effects. The SADABS program was used for absorption correction. The structures were solved by direct methods and the structure solutions and refinements were based on |F 2|. All non‐hydrogen atoms were refined with anisotropic displacement parameters except the atoms of disordered fragments which were refined isotropically. Hydrogen atoms were placed in calculated positions and given isotropicUvalues 20 % higher than the atom to which they are bonded. All crystallographic calculations were conducted with the SHELXTL software suite. CCDC‐624027 (1) and CCDC‐624028 (2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
10.1021/jo0499773
Preparation of2: 3 3′ 5 5′‐azobenzenetetracarboxylic acid[16](16.0 mg 0.044 mmol) In(NO3)3⋅2 H2O (22.0 mg 0.065 mmol) DMF (1 mL) CH3CN (0.5 mL) piperazine (0.1 mL 0.4 Min DMF) and HNO3(0.28 mL 2.7 Min DMF) were added to a vial and the solution was heated to 85 °C for 12 h. Orange‐colored polyhedral crystals were collected and air‐dried (16.6 mg 72 % yield). The as‐synthesized material is insoluble in H2O and common organic solvents. Elemental analysis calcd (%) for2 C24H21N4O22In3: C 27.15 H 1.99 N 5.28; found: C 27.32 H 2.51 N 5.18.
Crystallographic data of2: C24H21In3N4O22 Mr=1061.91 cubic P$\bar 4$3n a=22.4567(11) Å V=11 325.0(10) Å3 Z=8 ρcalcd=1.246 g cm−3 2θmax=50.02° (−15≤h≤15 0≤k≤18 1≤l≤26) T=100 K 3352 measured reflections R1=0.0680 wR2=0.1760 for 1499 reflections (I>2σ(I)) andR1=0.0855 wR2=0.1844 for 1819 independent reflections (all data) and 156 parameters GOF=1.039.
10.1006/jssc.2000.8723
M. O'Keeffe Reticular Chemistry Structure Resource http://rcsr.anu.edu.au/.
10.1021/ja991985r
10.1016/S0009-2614(00)01003-4
10.1063/1.1421639
10.1021/ja056639q
10.1002/adma.200500867
10.1016/j.jssc.2005.07.002
10.1021/ja0542690
10.1021/j100336a017
10.1021/jp952982d
10.1021/ja028341v
10.1103/RevModPhys.52.393

Dates

Type	When
Created	18 years, 4 months ago (March 27, 2007, 5:20 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 11:35 a.m.)
Indexed	1 day, 9 hours ago (Aug. 20, 2025, 8:25 a.m.)
Issued	18 years, 3 months ago (April 23, 2007)
Published	18 years, 3 months ago (April 23, 2007)
Published Online	18 years, 3 months ago (April 23, 2007)
Published Print	18 years, 3 months ago (April 27, 2007)

Funders 0

None

BibTeX

@article{Liu_2007, title={Assembly of Metal–Organic Frameworks (MOFs) Based on Indium‐Trimer Building Blocks: A Porous MOF with soc Topology and High Hydrogen Storage}, volume={46}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.200604306}, DOI={10.1002/anie.200604306}, number={18}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Liu, Yunling and Eubank, Jarrod F. and Cairns, Amy J. and Eckert, Juergen and Kravtsov, Victor Ch. and Luebke, Ryan and Eddaoudi, Mohamed}, year={2007}, month=apr, pages={3278–3283} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        20
      ]
    ],
    "date-time": "2025-08-20T12:25:29Z",
    "timestamp": 1755692729207
  },
  "reference-count": 72,
  "publisher": "Wiley",
  "issue": "18",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2007,
            3,
            27
          ]
        ],
        "date-time": "2007-03-27T00:00:00Z",
        "timestamp": 1174953600000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2007,
        4,
        27
      ]
    ]
  },
  "DOI": "10.1002/anie.200604306",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2007,
        3,
        27
      ]
    ],
    "date-time": "2007-03-27T09:20:40Z",
    "timestamp": 1174987240000
  },
  "page": "3278-3283",
  "source": "Crossref",
  "is-referenced-by-count": 648,
  "title": "Assembly of Metal\u2013Organic Frameworks (MOFs) Based on Indium\u2010Trimer Building Blocks: A Porous MOF with soc Topology and High Hydrogen Storage",
  "prefix": "10.1002",
  "volume": "46",
  "author": [
    {
      "given": "Yunling",
      "family": "Liu",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Jarrod\u2005F.",
      "family": "Eubank",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Amy\u2005J.",
      "family": "Cairns",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Juergen",
      "family": "Eckert",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Victor\u2005Ch.",
      "family": "Kravtsov",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Ryan",
      "family": "Luebke",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Mohamed",
      "family": "Eddaoudi",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2007,
        4,
        23
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_2_1_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_2_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ar040153h"
    },
    {
      "key": "e_1_2_2_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200300636"
    },
    {
      "key": "e_1_2_2_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/38985"
    },
    {
      "key": "e_1_2_2_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/(SICI)1521-3757(19991115)111:22<3466::AID-ANGE3466>3.0.CO;2-M"
    },
    {
      "key": "e_1_2_2_5_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO;2-U"
    },
    {
      "key": "e_1_2_2_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cr9900432"
    },
    {
      "key": "e_1_2_2_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ar010142d"
    },
    {
      "key": "e_1_2_2_8_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ar040163i"
    },
    {
      "key": "e_1_2_2_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja052431t"
    },
    {
      "key": "e_1_2_2_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.200300610"
    },
    {
      "key": "e_1_2_2_11_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200300610"
    },
    {
      "key": "e_1_2_2_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ar9703138"
    },
    {
      "key": "e_1_2_2_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ar0001012"
    },
    {
      "key": "e_1_2_2_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.200461408"
    },
    {
      "key": "e_1_2_2_14_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200461408"
    },
    {
      "key": "e_1_2_2_15_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.1083440"
    },
    {
      "key": "e_1_2_2_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja051168t"
    },
    {
      "key": "e_1_2_2_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/B308903G"
    },
    {
      "key": "e_1_2_2_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.200460712"
    },
    {
      "key": "e_1_2_2_19_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200460712"
    },
    {
      "key": "e_1_2_2_20_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.1101982"
    },
    {
      "key": "e_1_2_2_21_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.1120411"
    },
    {
      "key": "e_1_2_2_22_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/b600188m"
    },
    {
      "key": "e_1_2_2_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja051259q"
    },
    {
      "key": "e_1_2_2_25_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/B409459J"
    },
    {
      "key": "e_1_2_2_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.molstruc.2006.02.064"
    },
    {
      "key": "e_1_2_2_27_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ar000034b"
    },
    {
      "key": "e_1_2_2_28_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_29_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/1521-3757(20020802)114:15<2945::AID-ANGE2945>3.0.CO;2-4"
    },
    {
      "key": "e_1_2_2_29_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/1521-3773(20020802)41:15<2821::AID-ANIE2821>3.0.CO;2-Y"
    },
    {
      "key": "e_1_2_2_30_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1073/pnas.082051899"
    },
    {
      "key": "e_1_2_2_31_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja9639473"
    },
    {
      "key": "e_1_2_2_32_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/46248"
    },
    {
      "key": "e_1_2_2_33_2",
      "unstructured": "Y. Liu M. Eddaoudi unpublished results."
    },
    {
      "key": "e_1_2_2_34_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1107/S0108768102003890"
    },
    {
      "key": "e_1_2_2_35_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_36_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/a702287e"
    },
    {
      "key": "e_1_2_2_37_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja974172g"
    },
    {
      "key": "e_1_2_2_38_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/35010088"
    },
    {
      "key": "e_1_2_2_39_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/b202749f"
    },
    {
      "key": "e_1_2_2_40_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.200460592"
    },
    {
      "key": "e_1_2_2_40_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200460592"
    },
    {
      "key": "e_1_2_2_41_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ic050064g"
    },
    {
      "key": "e_1_2_2_42_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.1116275"
    },
    {
      "key": "e_1_2_2_43_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.200454250"
    },
    {
      "key": "e_1_2_2_43_3",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200454250"
    },
    {
      "key": "e_1_2_2_44_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.materresbull.2006.01.022"
    },
    {
      "key": "e_1_2_2_45_2",
      "unstructured": "Preparation of1: 1 3\u2010H2BDC (30.0\u2005mg 0.174\u2005mmol) In(NO3)3\u22c52\u2009H2O (30.0\u2005mg 0.087\u2005mmol) DMF (1\u2005mL) CH3CN (1\u2005mL) imidazole (0.2\u2005mL 0.90\u2009Min DMF) and HNO3(0.2\u2005mL 2.7\u2009Min DMF) were added to a vial and the solution was heated to 85\u2009\u00b0C for 12\u2005h and then at 100\u2009\u00b0C for 20\u2005h. Colorless cubic crystals were collected and air\u2010dried (23.5\u2005mg 75\u2009% yield). The as\u2010synthesized material is insoluble in H2O and common organic solvents. Elemental analysis calcd (%) for1 C32.5H28.5N4.5O15.5In3: C 36.33 H 2.67 N 5.87; found: C 36.15 H 2.82 N 5.92."
    },
    {
      "key": "e_1_2_2_46_2",
      "unstructured": "Crystallographic data of1: C32.5H28.5In3N4.5O15.5 Mr=1074.56 cubic Pa$\\bar 3$ a=19.5514(9)\u2005\u00c5 V=7473.7(6)\u2005\u00c53 Z=8 \u03c1calcd=1.910\u2005g\u2009cm\u22123 2\u03b8max=54.98\u00b0 (\u221210\u2264h\u226425 \u221215\u2264k\u226416 \u221225\u2264l\u226423) T=100\u2005K 20\u2009484 measured reflections R1=0.0520 wR2=0.1319 for 2436 reflections (I>2\u03c3(I)) andR1=0.0649 wR2=0.1387 for 2870 independent reflections (all data) and 177 parameters GOF=1.016. Data were collected on a Bruker SMART\u2010APEX CCD diffractometer using MoK\u03b1radiation (\u03bb=0.71073\u2005\u00c5) operating in the\u03c9and\u03c6scan mode and corrected for Lorentz and polarization effects. The SADABS program was used for absorption correction. The structures were solved by direct methods and the structure solutions and refinements were based on |F\u20092|. All non\u2010hydrogen atoms were refined with anisotropic displacement parameters except the atoms of disordered fragments which were refined isotropically. Hydrogen atoms were placed in calculated positions and given isotropicUvalues 20\u2009% higher than the atom to which they are bonded. All crystallographic calculations were conducted with the SHELXTL software suite. CCDC\u2010624027 (1) and CCDC\u2010624028 (2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif."
    },
    {
      "key": "e_1_2_2_47_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jo0499773"
    },
    {
      "key": "e_1_2_2_48_2",
      "unstructured": "Preparation of2: 3 3\u2032 5 5\u2032\u2010azobenzenetetracarboxylic acid[16](16.0\u2005mg 0.044\u2005mmol) In(NO3)3\u22c52\u2009H2O (22.0\u2005mg 0.065\u2005mmol) DMF (1\u2005mL) CH3CN (0.5\u2005mL) piperazine (0.1\u2005mL 0.4\u2009Min DMF) and HNO3(0.28\u2005mL 2.7\u2009Min DMF) were added to a vial and the solution was heated to 85\u2009\u00b0C for 12\u2005h. Orange\u2010colored polyhedral crystals were collected and air\u2010dried (16.6\u2005mg 72\u2009% yield). The as\u2010synthesized material is insoluble in H2O and common organic solvents. Elemental analysis calcd (%) for2 C24H21N4O22In3: C 27.15 H 1.99 N 5.28; found: C 27.32 H 2.51 N 5.18."
    },
    {
      "key": "e_1_2_2_49_2",
      "unstructured": "Crystallographic data of2: C24H21In3N4O22 Mr=1061.91 cubic P$\\bar 4$3n a=22.4567(11)\u2005\u00c5 V=11\u2009325.0(10)\u2005\u00c53 Z=8 \u03c1calcd=1.246\u2005g\u2009cm\u22123 2\u03b8max=50.02\u00b0 (\u221215\u2264h\u226415 0\u2264k\u226418 1\u2264l\u226426) T=100\u2005K 3352 measured reflections R1=0.0680 wR2=0.1760 for 1499 reflections (I>2\u03c3(I)) andR1=0.0855 wR2=0.1844 for 1819 independent reflections (all data) and 156 parameters GOF=1.039."
    },
    {
      "key": "e_1_2_2_50_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1006/jssc.2000.8723"
    },
    {
      "key": "e_1_2_2_51_2",
      "unstructured": "M. O'Keeffe Reticular Chemistry Structure Resource http://rcsr.anu.edu.au/."
    },
    {
      "key": "e_1_2_2_52_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja991985r"
    },
    {
      "key": "e_1_2_2_53_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_54_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0009-2614(00)01003-4"
    },
    {
      "key": "e_1_2_2_55_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.1421639"
    },
    {
      "key": "e_1_2_2_56_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_57_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja056639q"
    },
    {
      "key": "e_1_2_2_58_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.200500867"
    },
    {
      "key": "e_1_2_2_59_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jssc.2005.07.002"
    },
    {
      "key": "e_1_2_2_60_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja0542690"
    },
    {
      "key": "e_1_2_2_61_2",
      "unstructured": "\u00a0"
    },
    {
      "key": "e_1_2_2_62_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/j100336a017"
    },
    {
      "key": "e_1_2_2_63_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp952982d"
    },
    {
      "key": "e_1_2_2_64_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja028341v"
    },
    {
      "key": "e_1_2_2_65_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/RevModPhys.52.393"
    }
  ],
  "container-title": "Angewandte Chemie International Edition",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fanie.200604306",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.200604306",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        16
      ]
    ],
    "date-time": "2023-10-16T15:35:15Z",
    "timestamp": 1697470515000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/anie.200604306"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2007,
        4,
        23
      ]
    ]
  },
  "references-count": 72,
  "journal-issue": {
    "issue": "18",
    "published-print": {
      "date-parts": [
        [
          2007,
          4,
          27
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/anie.200604306"
  ],
  "URL": "http://dx.doi.org/10.1002/anie.200604306",
  "relation": {},
  "ISSN": [
    "1433-7851",
    "1521-3773"
  ],
  "subject": [],
  "container-title-short": "Angew Chem Int Ed",
  "published": {
    "date-parts": [
      [
        2007,
        4,
        23
      ]
    ]
  }
}