DOI: 10.1002/anie.200603070. A Heterogeneous Silica‐Supported Scandium/Ionic Liquid Catalyst System for Organic Reactions in Water

A Heterogeneous Silica‐Supported Scandium/Ionic Liquid Catalyst System for Organic Reactions in Water

10.1002/anie.200603070

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Bibliography

Gu, Y., Ogawa, C., Kobayashi, J., Mori, Y., & Kobayashi, S. (2006). A Heterogeneous SilicaâSupported Scandium/Ionic Liquid Catalyst System for Organic Reactions in Water. Angewandte Chemie International Edition, 45(43), 7217â7220. Portico.

Authors 5

Yanlong Gu (first)
Chikako Ogawa (additional)
Juta Kobayashi (additional)
Yuichiro Mori (additional)
Shū Kobayashi (additional)

References 63 Referenced 139

{'key': 'e_1_2_2_2_2', 'volume-title': 'Organic Synthesis in Water', 'year': '1998'} / Organic Synthesis in Water (1998)
{'key': 'e_1_2_2_3_2', 'volume-title': 'Organic Reactions in Aqueous', 'author': 'Li C.‐J.', 'year': '1997'} / Organic Reactions in Aqueous by Li C.‐J. (1997)
10.1021/cr010122p
10.1021/cr030009u
{'key': 'e_1_2_2_7_2', 'volume-title': 'Selectivities in Lewis Acid Promoted Reactions', 'year': '1989'} / Selectivities in Lewis Acid Promoted Reactions (1989)
{'key': 'e_1_2_2_8_2', 'volume-title': 'Lewis Acids in Organic Synthesis', 'year': '2000'} / Lewis Acids in Organic Synthesis (2000)
10.1246/cl.1991.2187
10.1021/jo00092a017
10.1021/ja980715q
10.1002/chem.200600385
10.1021/ar000145a
10.1002/1521-3765(20020916)8:18<4185::AID-CHEM4185>3.0.CO;2-6 / Chem. Eur. J. by Kobayashi S. (2002)
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10.1016/S0040-4039(98)01081-8
10.1021/ja001420r
10.1002/(SICI)1521-3757(20000204)112:3<578::AID-ANGE578>3.0.CO;2-W
10.1002/(SICI)1521-3773(20000204)39:3<567::AID-ANIE567>3.0.CO;2-G
10.1021/jo960003n
10.1016/S0040-4039(00)00257-4
10.1002/1521-3757(20000717)112:14<2614::AID-ANGE2614>3.0.CO;2-Y
10.1002/1521-3773(20000717)39:14<2498::AID-ANIE2498>3.0.CO;2-C
10.1021/cm0101531
10.1021/ja0302578
10.1016/j.tet.2004.06.083
Reviews of ILs and recent works on ILs related to materials chemistry:
10.1021/cr980032t
10.1007/s100980050036
10.1002/1521-3757(20001103)112:21<3926::AID-ANGE3926>3.0.CO;2-U
10.1002/1521-3773(20001103)39:21<3772::AID-ANIE3772>3.0.CO;2-5
10.1039/b107270f
10.1021/cr010338r
10.1016/S0926-860X(01)00834-1
10.1002/ange.200460091
10.1002/anie.200460091
10.1021/ja038405h
10.1021/jp056006y
Scandium Lewis acids are often used in organic synthesis. See:
10.1002/(SICI)1099-0690(199901)1999:1<15::AID-EJOC15>3.0.CO;2-B
10.1021/cr010289i
10.1038/29959
10.1016/j.micromeso.2004.10.038
Although supported ionic liquid catalysis has been investigated recently there are no examples of the combination of silica‐supported metal catalysts with ionic liquids. It is reported that silica gel supported ionic liquids and additional nonsupported ionic liquids form ionic‐liquid phases on the surface of silica gel owing to interactions between supported and nonsupported ionic liquids. See
10.1021/ja0279242
10.1002/ange.200461534
10.1002/anie.200461534
10.1039/b502528a
10.1002/adsc.200505227
10.1002/chem.200400683
See theSupporting Information.
Other examples are shown in theSupporting Information.
10.1002/ange.19901020218
10.1002/anie.199002051
10.1002/cber.19921250528
10.1021/ja047896i
The product was obtained in 28 % yield with 66 %eeunder the following conditions:4(6.5 mol %) [HBIm]NTf2(50 wt % 20 mol %) Silica‐Sc‐IL (0.24 mmol g−1 5 mol %) H2O 35 °C 24 h.

Dates

Type	When
Created	18 years, 10 months ago (Oct. 6, 2006, 6:58 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 9:49 a.m.)
Indexed	1 week, 4 days ago (Aug. 23, 2025, 1:02 a.m.)
Issued	18 years, 10 months ago (Oct. 30, 2006)
Published	18 years, 10 months ago (Oct. 30, 2006)
Published Online	18 years, 10 months ago (Oct. 30, 2006)
Published Print	18 years, 9 months ago (Nov. 6, 2006)

Funders 0

None

BibTeX

@article{Gu_2006, title={A Heterogeneous Silica‐Supported Scandium/Ionic Liquid Catalyst System for Organic Reactions in Water}, volume={45}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.200603070}, DOI={10.1002/anie.200603070}, number={43}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Gu, Yanlong and Ogawa, Chikako and Kobayashi, Juta and Mori, Yuichiro and Kobayashi, Shū}, year={2006}, month=oct, pages={7217–7220} }

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