DOI: 10.1002/anie.200602556. Intercalation of Organic Molecules into Vanadium(IV) Benzenedicarboxylate: Adsorbate Structure and Selective Absorption of Organosulfur Compounds

Intercalation of Organic Molecules into Vanadium(IV) Benzenedicarboxylate: Adsorbate Structure and Selective Absorption of Organosulfur Compounds

10.1002/anie.200602556

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Bibliography

Wang, X., Liu, L., & Jacobson, A. J. (2006). Intercalation of Organic Molecules into Vanadium(IV) Benzenedicarboxylate: Adsorbate Structure and Selective Absorption of Organosulfur Compounds. Angewandte Chemie International Edition, 45(39), 6499â6503. Portico.

Authors 3

Xiqu Wang (first)
Lumei Liu (additional)
Allan J. Jacobson (additional)

References 54 Referenced 99

{'key': 'e_1_2_3_2_2', 'volume-title': 'Zeolite Molecular Sieves', 'author': 'Breck D. W.', 'year': '1974'} / Zeolite Molecular Sieves by Breck D. W. (1974)
10.1038/nature00785
10.1107/S0108768189004519
10.1021/jp962029o
10.1021/jp0140522
10.1021/ja0432822
{'key': 'e_1_2_3_8_2', 'volume-title': 'Intercalation Chemistry', 'author': 'Whittingham M. S.', 'year': '1982'} / Intercalation Chemistry by Whittingham M. S. (1982)
10.1039/a809746a
10.1038/46248
10.1002/1521-3757(20020916)114:18<3542::AID-ANGE3542>3.0.CO;2-P
10.1002/1521-3773(20020916)41:18<3392::AID-ANIE3392>3.0.CO;2-V
10.1021/ja017560y
10.1002/ange.200351368
10.1002/anie.200351368
10.1002/ange.200250633
10.1002/anie.200250633
10.1039/b301219k
10.1002/ange.200352982
10.1002/anie.200352982
10.1002/ange.200300610
10.1002/anie.200352730
10.1039/b313997m
10.1021/ja0490267
10.1002/1521-3757(20020118)114:2<291::AID-ANGE291>3.0.CO;2-I
10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO;2-Y
10.1039/b201381a
10.1021/ja0276974
10.1002/chem.200305413
10.1016/j.solidstatesciences.2005.03.007
{'key': 'e_1_2_3_28_2', 'first-page': '191', 'volume': '755', 'author': 'Whitfield T. R.', 'year': '2003', 'journal-title': 'Mater. Res. Soc. Symp. Proc.'} / Mater. Res. Soc. Symp. Proc. by Whitfield T. R. (2003)
10.1021/ja055757a
10.1039/B308903G
10.1126/science.1083440
10.1021/ja038678c
10.1021/ja042802q
10.1021/ja028996w
10.1021/ja054668v
10.1039/b110899a
10.1021/la0355500
10.1039/B511962F
1: Elemental analysis (%) calcd for [V(O)(bdc)](H2bdc)0.71: V 14.6 C 47.08 H 2.37; found: 14.8; C 47.10 H 2.68; crystal data: space groupP212121 a=6.8094(3) b=12.4220(6) c=17.1733(8) Å V=1452.6(1) Å3 Z=4 T=223 K dcalcd=1.593 g cm−3; single‐crystal data were collected on a Siemens SMART/CCD diffractometer (14 526 reflections total 3498 unique Rint=0.0478); the structure was solved and refined with the SHELXTL software package; final refinements converged atR1=0.0394 for all 3498 reflections and 188 parameters.
Thermogravimetric analyses of1carried out in air at 3 °C min−1showed two weight‐loss events. The first between 320 and 400 °C corresponds to the loss of the guest H2bdc. The second between 440 and 480 °C corresponds to the loss of framework bdc. A sample heated at 390 °C for 10 h was confirmed to be identical to MIL‐47 by IR spectroscopy (disappearance of the band at ca. 1700 cm−1characteristic of free CO species) and single‐crystal X‐ray diffraction ([V(O)(bdc)] (2): space groupPnma a=6.8249(8) b=16.073(2) c=13.995(2) T=293 K dcalcd=1.000 g cm−3 R1=0.0443 for all 1904 unique reflections and 67 parameters). After immersing the [V(O)(bdc)] crystals in the corresponding guest liquid in air at room temperature for approximately 1 h a suitable crystal for each intercalation phase was selected and sealed in a capillary together with the guest liquid in air and mounted on a Siemens SMART/CCD diffractometer for X‐ray data collection.3: space groupP212121 a=6.785(1) b=13.031(2) c=16.851(2) Å V=1489.8(4) Å3 Z=4 T=223 K dcalcd=1.445 g cm−3. 12 940 reflections total 3511 unique Rint=0.0698;R1=0.0394 for all 3511 unique reflections and 180 parameters.4: space groupP212121 a=6.786(1) b=12.618(2) c=17.086(3) Å V=1463.0(4) Å3 Z=4 T=223 K dcalcd=1.503 g cm−3; 8691 reflections total 3368 unique Rint=0.0641;R1=0.0695 for all 3368 unique reflections and 174 parameters.5: space groupPnma a=6.796(3) b=18.410(8) c=10.214(4) Å V=1278.0(9) Å3 Z=4 T=223 K dcalc=1.431 g cm−3; 7544 reflections total 1006 unique Rint=0.2022;R1=0.134 for all 1006 unique reflections and 43 parameters. The crystal quality of5is comparatively poor probably because of the large unit‐cell changes during intercalation. CCDC 619387–619391 (1–5 respectively) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
10.1039/b003010o
10.1002/1099-0682(200212)2002:12<3148::AID-EJIC3148>3.0.CO;2-X
10.1039/a900558g
10.1107/S0108768198001463

Dates

Type	When
Created	18 years, 11 months ago (Sept. 13, 2006, 5:54 a.m.)
Deposited	1 year, 10 months ago (Oct. 17, 2023, 3:18 a.m.)
Indexed	1 month, 4 weeks ago (June 24, 2025, 12:47 a.m.)
Issued	18 years, 10 months ago (Sept. 29, 2006)
Published	18 years, 10 months ago (Sept. 29, 2006)
Published Online	18 years, 10 months ago (Sept. 29, 2006)
Published Print	18 years, 10 months ago (Oct. 6, 2006)

Funders 0

None

BibTeX

@article{Wang_2006, title={Intercalation of Organic Molecules into Vanadium(IV) Benzenedicarboxylate: Adsorbate Structure and Selective Absorption of Organosulfur Compounds}, volume={45}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.200602556}, DOI={10.1002/anie.200602556}, number={39}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Wang, Xiqu and Liu, Lumei and Jacobson, Allan J.}, year={2006}, month=sep, pages={6499–6503} }

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      "unstructured": "Thermogravimetric analyses of1carried out in air at 3\u2009\u00b0C\u2009min\u22121showed two weight\u2010loss events. The first between 320 and 400\u2009\u00b0C corresponds to the loss of the guest H2bdc. The second between 440 and 480\u2009\u00b0C corresponds to the loss of framework bdc. A sample heated at 390\u2009\u00b0C for 10 h was confirmed to be identical to MIL\u201047 by IR spectroscopy (disappearance of the band at ca. 1700 cm\u22121characteristic of free \uf8ffC\uf8feO species) and single\u2010crystal X\u2010ray diffraction ([V(O)(bdc)] (2): space groupPnma a=6.8249(8) b=16.073(2) c=13.995(2) T=293 K dcalcd=1.000 g\u2009cm\u22123 R1=0.0443 for all 1904 unique reflections and 67 parameters). After immersing the [V(O)(bdc)] crystals in the corresponding guest liquid in air at room temperature for approximately 1 h a suitable crystal for each intercalation phase was selected and sealed in a capillary together with the guest liquid in air and mounted on a Siemens SMART/CCD diffractometer for X\u2010ray data collection.3: space groupP212121 a=6.785(1) b=13.031(2) c=16.851(2) \u00c5 V=1489.8(4) \u00c53 Z=4 T=223 K dcalcd=1.445 g\u2009cm\u22123. 12\u2009940 reflections total 3511 unique Rint=0.0698;R1=0.0394 for all 3511 unique reflections and 180 parameters.4: space groupP212121 a=6.786(1) b=12.618(2) c=17.086(3) \u00c5 V=1463.0(4) \u00c53 Z=4 T=223 K dcalcd=1.503 g\u2009cm\u22123; 8691 reflections total 3368 unique Rint=0.0641;R1=0.0695 for all 3368 unique reflections and 174 parameters.5: space groupPnma a=6.796(3) b=18.410(8) c=10.214(4) \u00c5 V=1278.0(9) \u00c53 Z=4 T=223 K dcalc=1.431 g\u2009cm\u22123; 7544 reflections total 1006 unique Rint=0.2022;R1=0.134 for all 1006 unique reflections and 43 parameters. The crystal quality of5is comparatively poor probably because of the large unit\u2010cell changes during intercalation. CCDC 619387\u2013619391 (1\u20135 respectively) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif."
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