DOI: 10.1002/anie.200504128. Hydrothermal Chemistry of the Copper–Triazolate System: A Microporous Metal–Organic Framework Constructed from Magnetic {Cu3(μ3‐OH)(triazolate)3}2+ Building Blocks, and Related Materials

Hydrothermal Chemistry of the Copper–Triazolate System: A Microporous Metal–Organic Framework Constructed from Magnetic {Cu3(μ3‐OH)(triazolate)3}2+ Building Blocks, and Related Materials

10.1002/anie.200504128

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Bibliography

Ouellette, W., Yu, M. H., OâConnor, C. J., Hagrman, D., & Zubieta, J. (2006). Hydrothermal Chemistry of the CopperâTriazolate System: A Microporous MetalâOrganic Framework Constructed from Magnetic {Cu3(Î¼3âOH)(triazolate)3}2+ Building Blocks, and Related Materials. Angewandte Chemie International Edition, 45(21), 3497â3500. Portico.

Authors 5

Wayne Ouellette (first)
Ming Hui Yu (additional)
Charles J. O'Connor (additional)
Douglas Hagrman (additional)
Jon Zubieta (additional)

References 39 Referenced 154

10.1039/B417013J
10.1002/ange.200462201
10.1002/anie.200462201
10.1002/ange.200462711
10.1002/anie.200462711
10.1021/ja042802q
10.1038/35010088
10.1016/S0010-8545(03)00117-6
10.1126/science.1067208
10.1002/anie.200300636
The literature on organic–inorganic hybrid materials is voluminous. Some recent reviews and representative articles include:
10.1016/B0-08-043748-6/06192-2 / Comprehensive Coordination Chemistry II, Vol. 7 by Kitagawa S. (2003)
10.1002/ange.200300588
10.1002/anie.200300588
10.1002/anie.200300636
10.1016/j.cct.2003.08.005
10.1039/b200393g
10.1016/S0010-8545(03)00049-3
10.1016/S0010-8545(03)00030-4
10.1016/S0010-8545(00)00266-6
10.1126/science.279.5347.44
10.1021/ja042222t
10.1002/ange.200352627
10.1002/anie.200352627
10.1021/ic020179
10.1021/ja054913a
10.1021/ic049201k
10.1039/a804689a
10.1039/a903368h
10.1039/b404269g
10.1021/ic990385q
10.1007/BF00645633
1⋅4.5 H2O: C6H26Cu3N9O11.5 Mr=598.98 cubic Fd$\bar 3$c a=24.7233(4) Å V=15 111.9(4) Å3 Z=32 ρcalcd=2.106 g cm−3 R1=0.0317 wR2=0.0798 (855 reflections all data). The diffuse disordered H2O molecules of crystallization were modeled using the SQUEEZE routine of the program PLATON.[28]The μ3‐OH−group is disordered across the Cu3plane.2: C6H7Br4Cu5N9O Mr=858.54 cubic Fd$\bar 3$c a=24.5326(6) Å V=14 764.9(6) Å Z=32 ρcalcd=3.086 g cm−3(ρfound=3.10 g cm−3by flotation) R1=0.0694 wR2=0.1630 (690 reflections all data). The {CuBr2${\}{{n- \hfill \atop n\hfill}}}$subunit is disordered over two sets of sites.3: C6H12Cl2Cu5N9O3 Mr=646.84 orthorhombic Pnma a=11.6389(6) b=9.9663(5) c=12.3013(6) Å V=1426.9(1) Å3 Z=4 ρcalcd=3.670 g cm−3 R1=0.0570 wR2=0.1451 (1787 reflections all data). The diffuse disordered H2O of crystallization was modeled using the SQUEEZE routine of the program PLATON.[28]Full experimental details are provided in the Supporting Information. CCDC‐289564 (1⋅4.5 H2O) CCDC‐289565 (2) and CCDC‐289566 (3⋅3 H2O) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
The temperature‐dependent magnetic data were fit to Equations (1)–(3). The best fit gaveg=2.15 J/kB=−569 K z J′/kB=−149 K χTI=0.0009 emu Oe−1 mol−1 andp=0.017. The coefficient of determination for the least‐squares fitting wasR2=0.99925.
10.1002/9780470166307.ch4
10.1016/S0010-8545(00)80080-6
10.1039/b501040c
10.1107/S0021889802022112

Dates

Type	When
Created	19 years, 4 months ago (April 20, 2006, 5:23 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 3:52 p.m.)
Indexed	4 weeks, 2 days ago (July 23, 2025, 8:04 a.m.)
Issued	19 years, 3 months ago (May 10, 2006)
Published	19 years, 3 months ago (May 10, 2006)
Published Online	19 years, 3 months ago (May 10, 2006)
Published Print	19 years, 3 months ago (May 19, 2006)

Funders 0

None

BibTeX

@article{Ouellette_2006, title={Hydrothermal Chemistry of the Copper–Triazolate System: A Microporous Metal–Organic Framework Constructed from Magnetic {Cu3(μ3‐OH)(triazolate)3}2+ Building Blocks, and Related Materials}, volume={45}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.200504128}, DOI={10.1002/anie.200504128}, number={21}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Ouellette, Wayne and Yu, Ming Hui and O’Connor, Charles J. and Hagrman, Douglas and Zubieta, Jon}, year={2006}, month=may, pages={3497–3500} }

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