DOI: 10.1002/anie.200454002. A Dodecameric Water Cluster Built around a Cyclic Quasiplanar Hexameric Core in an Organic Supramolecular Complex of a Cryptand

A Dodecameric Water Cluster Built around a Cyclic Quasiplanar Hexameric Core in an Organic Supramolecular Complex of a Cryptand

10.1002/anie.200454002

Crossref journal-article

Wiley

Angewandte Chemie International Edition (311)

Bibliography

Ghosh, S. K., & Bharadwaj, P. K. (2004). A Dodecameric Water Cluster Built around a Cyclic Quasiplanar Hexameric Core in an Organic Supramolecular Complex of a Cryptand. Angewandte Chemie International Edition, 43(27), 3577â3580. Portico.

Authors 2

Sujit K. Ghosh (first)
Parimal K. Bharadwaj (additional)

References 49 Referenced 222

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Crystal data for1: Colorless hexagonal crystal dimensions 0.18×0.16×0.13 mm trigonal space groupR$\bar 3$ Z=3 a=14.023(5) b=14.023 (5) c=33.249(5) Å V=5662.3(2) Å3 ρcalcd=0.199 g cm−3 T=100 K μ=0.015 mm−1 θmax=28.32° 3139 reflections collected of which 2834 were unique.R1=0.0684 wR2=0.2004 with a GOF of 1.050 forI>2σ(I); residual electron density: 1.347 and −0.854 e Å−3. The X‐ray data were collected on a Bruker SMART APEX CCD diffractometer using graphite monochromated MoKαradiation (0.71069 Å). The following programs were used during data collection and refinement: SMART (version 5.628 to acquire frame data) SAINT (version 6.45 to determine final unit parameters and intregate frame data). The structure was solved by direct methods and refined onF2using SHELX‐97 (G. M. Sheldrick Program for the solution and refinement of crystal structures University of Göttingen Germany 1997) package. The hydrogen atoms connected to the OW3 could not be located in the difference Fourier maps with certainty although other H atoms could be located. The non‐hydrogen atoms were refined anisotropically. H atoms were not refined. CCDC‐230380 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre 12 Union Road Cambridge CB2 1EZ UK; fax: (+44) 1223‐336‐033; or deposit@ccdc.cam.ac.uk).
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Dates

Type	When
Created	21 years, 2 months ago (June 29, 2004, 1:01 p.m.)
Deposited	1 year, 10 months ago (Oct. 10, 2023, 7:54 p.m.)
Indexed	3 weeks, 3 days ago (Aug. 12, 2025, 5:25 p.m.)
Issued	21 years, 2 months ago (June 29, 2004)
Published	21 years, 2 months ago (June 29, 2004)
Published Online	21 years, 2 months ago (June 29, 2004)
Published Print	21 years, 2 months ago (July 5, 2004)

Funders 0

None

BibTeX

@article{Ghosh_2004, title={A Dodecameric Water Cluster Built around a Cyclic Quasiplanar Hexameric Core in an Organic Supramolecular Complex of a Cryptand}, volume={43}, ISSN={1521-3773}, url={http://dx.doi.org/10.1002/anie.200454002}, DOI={10.1002/anie.200454002}, number={27}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Ghosh, Sujit K. and Bharadwaj, Parimal K.}, year={2004}, month=jun, pages={3577–3580} }

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