DOI: 10.1002/anie.199526851. The Formal Potentials of Solid Metal Hexacyanometalates

The Formal Potentials of Solid Metal Hexacyanometalates

10.1002/anie.199526851

Crossref journal-article

Wiley

Angewandte Chemie International Edition in English (311)

Abstract

The first report of the formal potentials of a series of solid metal hexacyanometalates (M+)nM′[M″ (CN)6] is given (M+ = Li+, K+, Na+, Rb+, Cs+; M′ = Ag, Al, Cd, Co, Cr, Cu, Fe, Ga, In, Mn, Ni, Pb; M″ = Cr, Fe, Mn). A linear correlation exists between the ionic potential Φ = z/reff of the nitrogen‐bonded M′ ions and the formal potentials of the hexacyanometalate ions. This results from increased π back bonding when the acid–base interaction between the nitrogen atom of the cyanide ions and the M′ ions is stronger.

Bibliography

Scholz, F., & Dostal, A. (1996). The Formal Potentials of Solid Metal Hexacyanometalates. Angewandte Chemie International Edition in English, 34(23â24), 2685â2687. Portico.

Authors 2

Fritz Scholz (first)
Aleš Dostal (additional)

References 26 Referenced 156

10.1002/9783527615537
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Dates

Type	When
Created	21 years, 7 months ago (Jan. 16, 2004, 10:24 a.m.)
Deposited	2 years ago (Sept. 1, 2023, 11:55 a.m.)
Indexed	6 days, 10 hours ago (Aug. 31, 2025, 6:30 a.m.)
Issued	29 years, 8 months ago (Jan. 5, 1996)
Published	29 years, 8 months ago (Jan. 5, 1996)
Published Online	21 years, 8 months ago (Dec. 22, 2003)
Published Print	29 years, 8 months ago (Jan. 5, 1996)

Funders 0

None

BibTeX

@article{Scholz_1996, title={The Formal Potentials of Solid Metal Hexacyanometalates}, volume={34}, ISSN={0570-0833}, url={http://dx.doi.org/10.1002/anie.199526851}, DOI={10.1002/anie.199526851}, number={23–24}, journal={Angewandte Chemie International Edition in English}, publisher={Wiley}, author={Scholz, Fritz and Dostal, Aleš}, year={1996}, month=jan, pages={2685–2687} }

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