DOI: 10.1002/anie.199508111. New Process for the Sulfonation of Phosphane Ligands for Catalysts

New Process for the Sulfonation of Phosphane Ligands for Catalysts

10.1002/anie.199508111

Crossref journal-article

Wiley

Angewandte Chemie International Edition in English (311)

Bibliography

Herrmann, W. A., Albanese, G. P., Manetsberger, R. B., Lappe, P., & Bahrmann, H. (1995). New Process for the Sulfonation of Phosphane Ligands for Catalysts. Angewandte Chemie International Edition in English, 34(7), 811â813. Portico.

Authors 5

Wolfgang A. Herrmann (first)
Guido P. Albanese (additional)
Rainer B. Manetsberger (additional)
Peter Lappe (additional)
Helmut Bahrmann (additional)

References 30 Referenced 99

10.1002/ange.19931051102
10.1002/anie.199315241
10.1016/S0065-3055(08)60019-2
{'key': 'e_1_2_1_1_5', 'first-page': '570', 'volume': '17', 'author': 'Kuntz E. G.', 'year': '1987', 'journal-title': 'CHEMTECH'} / CHEMTECH by Kuntz E. G. (1987)
10.1002/cite.330660704
(b)B.Cornils J.Hibbel W.Konkol B.Lieder J.Much V.Schmid E.Wiebus(Ruhrchemie AG) DE‐B 3234701 1982
{'key': 'e_1_2_1_2_4', 'first-page': '194022k', 'volume': '100', 'year': '1984', 'journal-title': 'Chem. Abstr.'} / Chem. Abstr. (1984)
(a)Y.Tokitoh N.Yoshimura(Kuraray Co.) EP‐A 287066 1988
{'key': 'e_1_2_1_3_3', 'first-page': '78070g', 'volume': '110', 'year': '1989', 'journal-title': 'Chem. Abstr.'} / Chem. Abstr. (1989)
(b)N.Yoshimura M.Tamura T.Higashi K.Hino M.Murasawa(Kuraray Co.) EP‐B 04362226 1991
{'key': 'e_1_2_1_3_5', 'first-page': '158508z', 'volume': '115', 'year': '1991', 'journal-title': 'Chem. Abstr.'} / Chem. Abstr. (1991)
10.1351/pac199466071509
10.1002/ange.19931050721
10.1002/anie.199310581
10.1016/0022-328X(94)84012-1
B.Cornils P.Lappe R.Gärtner H.Springer(Ruhrchemie AG) EP‐A 0107006 1983
{'key': 'e_1_2_1_4_3', 'first-page': '55331t', 'volume': '101', 'year': '1984', 'journal-title': 'Chem. Abstr.'} / Chem. Abstr. (1984)
10.1021/ja00749a021
10.1039/jr9600004315
10.1021/jo00198a004
(a)E. G.Kuntz(Rhǒne‐Poulenc S. A.) FR‐B 2366237 1976
{'key': 'e_1_2_1_7_3', 'first-page': '101944n', 'volume': '87', 'year': '1977', 'journal-title': 'Chem. Abstr.'} / Chem. Abstr. (1977)
(b)E. G.Kuntz(Rhǒne‐Poulenc S. A.) FR‐B 2733516 1978
{'key': 'e_1_2_1_7_5', 'first-page': '152026t', 'volume': '88', 'year': '1978', 'journal-title': 'Chem. Abstr.'} / Chem. Abstr. (1978)
Assignment of contitution by 2D NMR spectroscopy;W. A.Herrmann G. P.Albanese R. B.Manetsberger R.Schmid W. R.Thiel unpublished results. Characterization of5:1H‐1H‐COSY NMR (D2O): δ = 3.62 (d 2JHH′= 13.8 Hz 2H HH′) 3.66 (d 2JHH= 13.8 Hz 2H HH') 7.20 (d 2JHH= 6.9 Hz 3JPH= 6.8 Hz 1H H16') 7.21 (d 2JHH= 6.9 Hz 3JPH= 6.8 Hz 1H H16') 7.52 (tr 3JHH= 7.7 Hz 2H H15') 7.66 (tr 3JHH= 7.6 Hz 2H H15) 7.71 (d 3JHH= 7.5 Hz 3JPH= 7.2 Hz 1H H16) 7.73 (d 3JHH= 7.5 Hz 3JPH= 7.2 Hz 1H H16) 7.77 (d 3JHH= 9.0 Hz 2H H5) 7.90 (d 3JPH= 5.4 Hz 2H H12'). 7.97(s 2H H3) 7.98 (d 3JPH= 7.53 Hz 2H H14') 8.05 (d 3JPH= 5.8 Hz 2H H12) 8.10 (d 3JHH= 7.71 Hz 2H H14) 8.70 (s 2H H8) 8.98 (d 3JHH= 9.0 Hz 2H H6).
W. A.Herrmann C. W.Kohlpaintner R. B.Manetsberger H.Bahrmann H.Kottmann J. Mol. Catal. in press.
10.1016/0304-5102(89)80226-3 / J. Mol. Catal. by Neibecker D. (1989)
{'key': 'e_1_2_1_11_2', 'volume-title': 'Mechanistic Aspects in Aromatic Sulfonation and Desulfonation', 'author': 'Cerfontain H.', 'year': '1968'} / Mechanistic Aspects in Aromatic Sulfonation and Desulfonation by Cerfontain H. (1968)
{'key': 'e_1_2_1_11_3', 'first-page': '123', 'volume': '6', 'author': 'Cerfontein H.', 'year': '1971', 'journal-title': 'Int. J. Sulfur Chem. Part C'} / Int. J. Sulfur Chem. Part C by Cerfontein H. (1971)
Characterization of3:31P{1H} NMR (D2O): δ = −22.8;1H NMR (D2O): δ = 2.27 (s 9H; CH3) 7.17 (dd 3JHP= 4.0 Hz 4JHH= 1.8 Hz 3H; H6) 7.35 (dd 3JHH= 8.1 Hz 4JHP= 4.7 Hz 3H; H3) 7.79 (dd 4JHH= 1.5 Hz 3JHP= 7.9 Hz 3H H4);13C‐{1H} NMR (D2O); δ = 146.5 (d 3JCP= 25.8 Hz C5) 141.41 (s C1) 133.57 (d 2JCP= 11.0 Hz C2) 131.3 (d 3JCP= 4.8 Hz C3) 129.78 (s C6) 126.88 (s C4) 20.65 (d 3JCP= 20.5 Hz CH3). –Characterization of4:31P{1H} NMR (D2O): δ = −31.99 (s);1H NMR (D2O): δ = 3.78 (s 9H; OCH3) 7.20 (dd 4JHP= 8.9 Hz 3JHH= 4.6 Hz 3H; H3) 7.24 (dd 4JHH= 2.1 Hz 3JHH= 4.6 Hz 3H; H4) 7.93 (dd 4JHH= 2.1 Hz 3JPH= 9.6 Hz 3H; H6);13C{1H} NMR (D2O): δ = 56.24 (s OCH3) 111.41 (s C4) 122.17 (d 3JCP= 11.5 Hz C5) 129.31 (s C6) 131.05 (d 3JCP= 2.9 Hz C3) 136.78 (d 2JCP= 1.0 Hz C1) 163.12 (d 2JCP= 14.8 Hz C2). –Characterization of6:31P{1H} NMR (D2O): δ = 17.42;1H‐1H‐COSY NMR (D2O): δ = 6.90 (dt 3JHH= 1.9 Hz 2H; H8 H9) 7.01 (tt 3JHH= 7.7 Hz 4JHP= 12.0 Hz 4JHH= 1.2 Hz 1H; H16) 7.06 (td 3JHH= 7.7 Hz 4JHP= 3.2 Hz 1H; H15) 7.20 (dd 3JHH= 8.0 Hz 4JHP= 4.4 Hz 1H; H1) 7.32 (dt 3JHH= 7.3 Hz 4JHH= 7.3 Hz 4JHH= 1.9 Hz 2H; H6 H7) 7.43 (dt 3JHP= 14.0 Hz 4JHH= 1.2 Hz 1H; H12) 7.55 (ddd 3JHH= 7.7 Hz 4JHH14= 1.8 Hz 4JHH15= 1.3 Hz 1H; H14) 7.81 (dd 3JHH= 8.0 Hz 4JHH= 2.0 Hz 1H H2) 8.41 (dd 3JHP= 14.0 Hz 4JHH= 2.0 Hz 1H; H4). The numbering of the atoms in3 4 and6is arbitrary.

Dates

Type	When
Created	21 years, 7 months ago (Jan. 16, 2004, 9:27 a.m.)
Deposited	1 year, 10 months ago (Oct. 26, 2023, 12:50 a.m.)
Indexed	1 month, 2 weeks ago (July 8, 2025, 7:30 a.m.)
Issued	30 years, 4 months ago (April 13, 1995)
Published	30 years, 4 months ago (April 13, 1995)
Published Online	21 years, 8 months ago (Dec. 22, 2003)
Published Print	30 years, 4 months ago (April 13, 1995)

Funders 0

None

BibTeX

@article{Herrmann_1995, title={New Process for the Sulfonation of Phosphane Ligands for Catalysts}, volume={34}, ISSN={0570-0833}, url={http://dx.doi.org/10.1002/anie.199508111}, DOI={10.1002/anie.199508111}, number={7}, journal={Angewandte Chemie International Edition in English}, publisher={Wiley}, author={Herrmann, Wolfgang A. and Albanese, Guido P. and Manetsberger, Rainer B. and Lappe, Peter and Bahrmann, Helmut}, year={1995}, month=apr, pages={811–813} }

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      "unstructured": "Assignment of contitution by 2D NMR spectroscopy;W. A.Herrmann G. P.Albanese R. B.Manetsberger R.Schmid W. R.Thiel unpublished results. Characterization of5:1H\u20101H\u2010COSY NMR (D2O): \u03b4 = 3.62 (d 2JHH\u2032= 13.8 Hz 2H HH\u2032) 3.66 (d 2JHH= 13.8 Hz 2H HH') 7.20 (d 2JHH= 6.9 Hz 3JPH= 6.8 Hz 1H H16') 7.21 (d 2JHH= 6.9 Hz 3JPH= 6.8 Hz 1H H16') 7.52 (tr 3JHH= 7.7 Hz 2H H15') 7.66 (tr 3JHH= 7.6 Hz 2H H15) 7.71 (d 3JHH= 7.5 Hz 3JPH= 7.2 Hz 1H H16) 7.73 (d 3JHH= 7.5 Hz 3JPH= 7.2 Hz 1H H16) 7.77 (d 3JHH= 9.0 Hz 2H H5) 7.90 (d 3JPH= 5.4 Hz 2H H12'). 7.97(s 2H H3) 7.98 (d 3JPH= 7.53 Hz 2H H14') 8.05 (d 3JPH= 5.8 Hz 2H H12) 8.10 (d 3JHH= 7.71 Hz 2H H14) 8.70 (s 2H H8) 8.98 (d 3JHH= 9.0 Hz 2H H6)."
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      "key": "e_1_2_1_12_2",
      "unstructured": "Characterization of3:31P{1H} NMR (D2O): \u03b4 = \u221222.8;1H NMR (D2O): \u03b4 = 2.27 (s 9H; CH3) 7.17 (dd 3JHP= 4.0 Hz 4JHH= 1.8 Hz 3H; H6) 7.35 (dd 3JHH= 8.1 Hz 4JHP= 4.7 Hz 3H; H3) 7.79 (dd 4JHH= 1.5 Hz 3JHP= 7.9 Hz 3H H4);13C\u2010{1H} NMR (D2O); \u03b4 = 146.5 (d 3JCP= 25.8 Hz C5) 141.41 (s C1) 133.57 (d 2JCP= 11.0 Hz C2) 131.3 (d 3JCP= 4.8 Hz C3) 129.78 (s C6) 126.88 (s C4) 20.65 (d 3JCP= 20.5 Hz CH3). \u2013Characterization of4:31P{1H} NMR (D2O): \u03b4 = \u221231.99 (s);1H NMR (D2O): \u03b4 = 3.78 (s 9H; OCH3) 7.20 (dd 4JHP= 8.9 Hz 3JHH= 4.6 Hz 3H; H3) 7.24 (dd 4JHH= 2.1 Hz 3JHH= 4.6 Hz 3H; H4) 7.93 (dd 4JHH= 2.1 Hz 3JPH= 9.6 Hz 3H; H6);13C{1H} NMR (D2O): \u03b4 = 56.24 (s OCH3) 111.41 (s C4) 122.17 (d 3JCP= 11.5 Hz C5) 129.31 (s C6) 131.05 (d 3JCP= 2.9 Hz C3) 136.78 (d 2JCP= 1.0 Hz C1) 163.12 (d 2JCP= 14.8 Hz C2). \u2013Characterization of6:31P{1H} NMR (D2O): \u03b4 = 17.42;1H\u20101H\u2010COSY NMR (D2O): \u03b4 = 6.90 (dt 3JHH= 1.9 Hz 2H; H8 H9) 7.01 (tt 3JHH= 7.7 Hz 4JHP= 12.0 Hz 4JHH= 1.2 Hz 1H; H16) 7.06 (td 3JHH= 7.7 Hz 4JHP= 3.2 Hz 1H; H15) 7.20 (dd 3JHH= 8.0 Hz 4JHP= 4.4 Hz 1H; H1) 7.32 (dt 3JHH= 7.3 Hz 4JHH= 7.3 Hz 4JHH= 1.9 Hz 2H; H6 H7) 7.43 (dt 3JHP= 14.0 Hz 4JHH= 1.2 Hz 1H; H12) 7.55 (ddd 3JHH= 7.7 Hz 4JHH14= 1.8 Hz 4JHH15= 1.3 Hz 1H; H14) 7.81 (dd 3JHH= 8.0 Hz 4JHH= 2.0 Hz 1H H2) 8.41 (dd 3JHP= 14.0 Hz 4JHH= 2.0 Hz 1H; H4). The numbering of the atoms in3 4 and6is arbitrary."
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