DOI: 10.1002/anie.199207871. Synthesis and Structure of the Cluster [NaAu12Se8]3−: An Inorganic Cryptand Complex

Synthesis and Structure of the Cluster [NaAu12Se8]3−: An Inorganic Cryptand Complex

10.1002/anie.199207871

Crossref journal-article

Wiley

Angewandte Chemie International Edition in English (311)

Bibliography

Huang, S., & Kanatzidis, M. G. (1992). Synthesis and Structure of the Cluster [NaAu12Se8]3â: An Inorganic Cryptand Complex. Angewandte Chemie International Edition in English, 31(6), 787â789. Portico.

Authors 2

Song‐Ping Huang (first)
Mercouri G. Kanatzidis (additional)

References 26 Referenced 46

10.1080/02603599008048650
10.1016/0010-8545(90)85011-G
10.1016/0010-8545(90)80023-M
10.1021/ja00240a045
10.1021/ja00176a053
10.1021/ic00325a026
10.1021/ic00018a036
10.1021/ic00007a007
10.1021/ic00310a004
10.1515/znb-1991-0806 / Z. Naturforsch. B by Fenske D. (1991)
10.1002/ange.19850970906
10.1002/anie.198507421
10.1016/S0277-5387(00)84930-X
Crystal data for (Et4N)3[NaAu12Se8]: triclinicP1 Z= 2 a= 11.956(4) b= 12.733(4) c= 10.784(3) Å α = 103.94(3) β = 108.96(3) γ = 113.63(2)° V= 1285(2) Å3at 23 °C. 2θmax(MoKα) = 45.0°. Number of reflections measured 3557. Number of reflections havingF> 3σ(F): 1872. ρcaled= 4.40 g cm–3. An empirical absorption correction based on Ψ scans and a DIFABS correction [11] after isotropic refinement of all atoms were applied μ = 396 cm–1. The minimum and maximum transmission was 0.75 and 1.39 respectively. The structure has an asymmetric unit of (Et4N)1.5[Na0.5Au6Se4]. In addition to the Na+ion one of the tetrahedral Et4N+cations was found to occupy a crystallographic inversion center causing positional disorder of the ethyl groups on this cation site. The refinement of the atoms in this cation was carried out with a disorder model where all the C sites except for a terminal one (i.e. C16) are half‐occupied. C16 could not be found but its position was calculated and included in the structure factor calculation. The structure was solved by direct methods with the program MITHRIL and refined with TEXSAN single crystal analysis software. FinalR= 0.072 andRw= 0.084. Further details of the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe Gesellschaft für wissenschaftlich‐technische Information mbH D‐W‐7514 Eggenstein‐Leopoldshafen 2 (FRG) on quoting the depository number CSD‐56044 the names of the authors and the journal citation.
10.1107/S0108767383000252
10.1002/ange.19850970518
10.1002/anie.198504321
M. G.Kanatzidis S.‐P.Huang Phosphorous Sulfur Silicon Relat. Elem. in press.
10.1002/ange.19840960912
10.1002/anie.198407151
10.1002/ange.19840960412
10.1002/anie.198403111
10.1021/ic50186a032
10.1021/ic00285a022
10.1021/ja00159a028
10.1021/ja00227a064

Dates

Type	When
Created	21 years, 7 months ago (Dec. 30, 2003, 6:12 p.m.)
Deposited	1 year, 10 months ago (Oct. 23, 2023, 5:03 a.m.)
Indexed	1 year, 9 months ago (Oct. 30, 2023, 7:38 p.m.)
Issued	33 years, 2 months ago (June 1, 1992)
Published	33 years, 2 months ago (June 1, 1992)
Published Online	21 years, 8 months ago (Dec. 22, 2003)
Published Print	33 years, 2 months ago (June 1, 1992)

Funders 0

None

BibTeX

@article{Huang_1992, title={Synthesis and Structure of the Cluster [NaAu12Se8]3−: An Inorganic Cryptand Complex}, volume={31}, ISSN={0570-0833}, url={http://dx.doi.org/10.1002/anie.199207871}, DOI={10.1002/anie.199207871}, number={6}, journal={Angewandte Chemie International Edition in English}, publisher={Wiley}, author={Huang, Song‐Ping and Kanatzidis, Mercouri G.}, year={1992}, month=jun, pages={787–789} }

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