DOI: 10.1002/anie.199113121. Formation of Colloidal Transition Metals in Organic Phases and Their Application in Catalysis

Formation of Colloidal Transition Metals in Organic Phases and Their Application in Catalysis

10.1002/anie.199113121

Crossref journal-article

Wiley

Angewandte Chemie International Edition in English (311)

Abstract

Reduction of metal salts with tetraalkylammonium hydrotriorganoborates in organic phases yields a very narrow size range of metal colloids of the elements of groups 6–11. Adsorbed on carrier surfaces, these colloids are highly active hydrogenation catalysts whose activity can be further increased by doping with low‐valent organotitanium compounds.

Bibliography

BÃ¶nnemann, H., Brijoux, W., Brinkmann, R., JouÃen, T., Korall, B., & Dinjus, E. (1991). Formation of Colloidal Transition Metals in Organic Phases and Their Application in Catalysis. Angewandte Chemie International Edition in English, 30(10), 1312â1314. Portico.

Authors 6

Helmut Bönnemann (first)
Werner Brijoux (additional)
Rainer Brinkmann (additional)
Thomas Joußen (additional)
Barbara Korall (additional)
Eckard Dinjus (additional)

References 9 Referenced 348

10.1007/978-94-009-2113-9_1
G.Lagaly Ullmanns Encycl. Ind. Chem. 5. Aufl. Vol. A 7 (1986) 341–367.
10.1002/ange.19891010607
10.1002/anie.198907801
R.Köster Methoden Org. Chem. (Houben‐Weyl)4th Ed. Band XIII/3b (1983)789.
Hydrogen pressure 1 bar temperature 40°C ± 0.5° concentration of substrate 1.04 molL−1 catalyst used 0.3–1 g stirring rate 2000 revolutions per minute solvent 100 mL ethanol DAB 7.
{'key': 'e_1_2_1_6_2', 'first-page': '1667', 'volume': '1987', 'author': 'Cloke F. G. N.', 'journal-title': 'J. Chem. Soc. Chem. Commun.'} / J. Chem. Soc. Chem. Commun. by Cloke F. G. N.
{'key': 'e_1_2_1_6_3', 'first-page': '1419', 'volume': '1975', 'author': 'Anthony M. T.', 'journal-title': 'J. Chem. Soc. Dalton Trans.'} / J. Chem. Soc. Dalton Trans. by Anthony M. T.
{'key': 'e_1_2_1_6_4', 'first-page': '730', 'volume': '1978', 'author': 'Hawker P. N.', 'journal-title': 'J. Chem. Soc. Chem. Commun.'} / J. Chem. Soc. Chem. Commun. by Hawker P. N.

Dates

Type	When
Created	21 years, 8 months ago (Dec. 30, 2003, 7:10 p.m.)
Deposited	1 year, 10 months ago (Oct. 23, 2023, 3:09 a.m.)
Indexed	1 month, 3 weeks ago (July 11, 2025, 6:22 a.m.)
Issued	33 years, 11 months ago (Oct. 1, 1991)
Published	33 years, 11 months ago (Oct. 1, 1991)
Published Online	21 years, 8 months ago (Dec. 22, 2003)
Published Print	33 years, 11 months ago (Oct. 1, 1991)

Funders 0

None

BibTeX

@article{B_nnemann_1991, title={Formation of Colloidal Transition Metals in Organic Phases and Their Application in Catalysis}, volume={30}, ISSN={0570-0833}, url={http://dx.doi.org/10.1002/anie.199113121}, DOI={10.1002/anie.199113121}, number={10}, journal={Angewandte Chemie International Edition in English}, publisher={Wiley}, author={Bönnemann, Helmut and Brijoux, Werner and Brinkmann, Rainer and Joußen, Thomas and Korall, Barbara and Dinjus, Eckard}, year={1991}, month=oct, pages={1312–1314} }

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