DOI: 10.1002/anie.199108761. The Structure of IF

The Structure of IF

10.1002/anie.199108761

Crossref journal-article

Wiley

Angewandte Chemie International Edition in English (311)

Abstract

The square‐antiprismatic structure of IF corresponds to that of XeF. This shows that the extra lone pair of XeF is located in a stereochemically inactive orbital. The counterion NO⊕(NOF)2 is a polymer in which the charge‐carrying N atom is surrounded by one O and four F atoms in a square‐pyramidal arrangement.

Bibliography

Mahjoub, A., & Seppelt, K. (1991). The Structure of IF. Angewandte Chemie International Edition in English, 30(7), 876â878. Portico.

Authors 2

Ali‐Reza Mahjoub (first)
Konrad Seppelt (additional)

References 22 Referenced 27

10.1016/0020-1650(74)80084-X
10.1063/1.1673876
10.1126/science.173.4003.1238
10.1002/ange.19891011108
10.1002/anie.198915261
10.1021/ic00316a001
10.1021/ic00321a027
In this sense even the anions of the type [TeX6]2(X = Cl Br I) and [SeX6]2⊖(X = Cl Br) and similar antimony and bismuth anions represent no exception from the electron‐pair repulsion model. High crystal symmetry (at least the presence of one symmetry center for the central atom) generates dynamically distorted structures. With lower symmetry the structures are even statically distorted:
10.1515/znb-1985-1215 / Z. Naturforsch. by Abriel W. (1985)
10.1515/znb-1987-0405 / Z. Naturforsch. by Abriel W. (1987)
10.1515/znb-1987-1012 / Z. Naturforsch. by Abriel W. (1987)
10.1107/S0108768186097896
10.1002/ange.19840961211
10.1002/anie.198409631
10.1039/qr9571100339
10.1002/ange.19670792003
10.1002/anie.196708191
10.1107/S056774087400584X
10.1016/0022-328X(86)84034-7
{'key': 'e_1_2_1_7_2', 'first-page': '7621', 'volume': '112', 'author': 'Wilson W. W.', 'year': '1990', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. by Wilson W. W. (1990)
{'key': 'e_1_2_1_8_2', 'first-page': '5', 'volume': '170', 'author': 'Bärninghausen H.', 'year': '1985', 'journal-title': 'Z. Kristallogr.'} / Z. Kristallogr. by Bärninghausen H. (1985)
M.Eitel Dissertation Universität Karlsruhe 1985.

Dates

Type	When
Created	21 years, 8 months ago (Dec. 30, 2003, 7:16 p.m.)
Deposited	1 year, 10 months ago (Oct. 23, 2023, 1:12 a.m.)
Indexed	1 year, 2 months ago (July 2, 2024, 8:35 a.m.)
Issued	34 years, 2 months ago (July 1, 1991)
Published	34 years, 2 months ago (July 1, 1991)
Published Online	21 years, 8 months ago (Dec. 22, 2003)
Published Print	34 years, 2 months ago (July 1, 1991)

Funders 0

None

BibTeX

@article{Mahjoub_1991, title={The Structure of IF}, volume={30}, ISSN={0570-0833}, url={http://dx.doi.org/10.1002/anie.199108761}, DOI={10.1002/anie.199108761}, number={7}, journal={Angewandte Chemie International Edition in English}, publisher={Wiley}, author={Mahjoub, Ali‐Reza and Seppelt, Konrad}, year={1991}, month=jul, pages={876–878} }

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