Novel Bonding Mode for a Cyanometalate Ligand: Synthesis and Crystal Structure of the Mn4Pd4 Cluster [(OC)Pd(μ‐NC)Mn(η‐C5H4Me)(CO)2]4 Containing an Orthogonal Arrangement of Helical Units
10.1002/anie.199011401
Crossref journal-article
Wiley
Angewandte Chemie International Edition in English (311)
Abstract

AbstractNo Absract.

Bibliography

Braunstein, P., Oswald, B., Tiripicchio, A., & Camellini, M. T. (1990). Novel Bonding Mode for a Cyanometalate Ligand: Synthesis and Crystal Structure of the Mn4Pd4 Cluster [(OC)Pd(μ‐NC)Mn(η‐C5H4Me)(CO)2]4 Containing an Orthogonal Arrangement of Helical Units. Angewandte Chemie International Edition in English, 29(10), 1140–1143. Portico.

Authors 4
  1. Pierre Braunstein (first)
  2. Benoît Oswald (additional)
  3. Antonio Tiripicchio (additional)
  4. Marisa Tiripicchio Camellini (additional)
References 43 Referenced 50
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  28. Crystal structure determination of7C2H5OH:C40H28Mn4N4O12Pd4. C2H5OH M= 1448.10 triclinic space groupP1 a= 13.324(6) b= 18.377(8) c= 10.954(6) Å α = 101.90(2) β = 109.90(2) γ = 90.98(2)° V= 2457(2) Å3 Z= 2 Qcalcd= 1.958 g cm−3 graphite‐monochromated MoKαradiation λ = 0.71073 Å μ = 24.28 cm−1. The intensity data were collected on a Philips PW 1100 diffractometer using the ω−2θ scan technique at room temperature. A decay of about 30% of the initial intensity of a standard reflection measured after 50 reflections was observed during the data collection and corrected. 7135 unique reflections 3 < θ < 25° 2635 withI> 2σ(I) used in the refinement. The structure was solved by Patterson and Fourier methods and refined by full‐matrix least‐squares fit procedures with anisotropic thermal parameters in the last cycles of refinement for all the non‐hydrogen atoms except the carbon atoms of the methylcyclopentadienyl rings and the atoms of the molecule of solvation. The hydrogen atoms were introduced in calculated positions but their parameters were not refined. The SHELX‐76 and SHELXS‐86 system of computer programs was used[12]. TheRandRwvalues were 0.0578 and 0.0852 respectively. Further details of the crystal structure analysis may be obtained from the Fachinformationszentrum Karlsruhe Gesellschaft für wissenschaftlich‐technische Information mbH D‐7514 Eggenstein‐Leopoldshafen 2 (FRG) on quoting the depository number CSD‐54697 the names of the authors and the journal citation.
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  43. The authors are grateful toJ.‐P. MageandP. Verley(Groupe IAO Centre de calcul du CNRS Strasbourg) for the computer‐generated color drawing of7in Figure 3 which was obtained by using the actual atomic coordinates of the Pd Mn C and N atoms and the CATIA software.
Dates
Type When
Created 21 years, 7 months ago (Dec. 31, 2003, 3:57 a.m.)
Deposited 1 year, 10 months ago (Oct. 22, 2023, 3:07 p.m.)
Indexed 1 month, 3 weeks ago (June 30, 2025, 7:26 a.m.)
Issued 34 years, 10 months ago (Oct. 1, 1990)
Published 34 years, 10 months ago (Oct. 1, 1990)
Published Online 21 years, 8 months ago (Dec. 22, 2003)
Published Print 34 years, 10 months ago (Oct. 1, 1990)
Funders 0

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@article{Braunstein_1990, title={Novel Bonding Mode for a Cyanometalate Ligand: Synthesis and Crystal Structure of the Mn4Pd4 Cluster [(OC)Pd(μ‐NC)Mn(η‐C5H4Me)(CO)2]4 Containing an Orthogonal Arrangement of Helical Units}, volume={29}, ISSN={0570-0833}, url={http://dx.doi.org/10.1002/anie.199011401}, DOI={10.1002/anie.199011401}, number={10}, journal={Angewandte Chemie International Edition in English}, publisher={Wiley}, author={Braunstein, Pierre and Oswald, Benoît and Tiripicchio, Antonio and Camellini, Marisa Tiripicchio}, year={1990}, month=oct, pages={1140–1143} }