DOI: 10.1002/anie.199008111. μ‐Hydroxobis(μ‐formato)hexaaquadichromium(<scp>III</scp>), an Intermediate in the Formation of Basic Chromium Carboxylates

μ‐Hydroxobis(μ‐formato)hexaaquadichromium(III), an Intermediate in the Formation of Basic Chromium Carboxylates

10.1002/anie.199008111

Crossref journal-article

Wiley

Angewandte Chemie International Edition in English (311)

Bibliography

Turowski, P. N., Bino, A., & Lippard, S. J. (1990). Î¼âHydroxobis(Î¼âformato)hexaaquadichromium(III), an Intermediate in the Formation of Basic Chromium Carboxylates. Angewandte Chemie International Edition in English, 29(7), 811â812. Portico.

Authors 3

Petra N. Turowski (first)
Avi Bino (additional)
Stephen J. Lippard (additional)

References 25 Referenced 26

{'key': 'e_1_2_1_1_2', 'first-page': '86', 'volume': '4', 'author': 'Schützenberger M. P.', 'year': '1965', 'journal-title': 'Bull. Soc. Chim. Fr.'} / Bull. Soc. Chim. Fr. by Schützenberger M. P. (1965)
10.1002/prac.18940500135
10.1002/cber.19080410324
10.1002/zaac.19100690112
10.1002/zaac.19110690116
10.1038/205694a0
10.1002/9780470166376.ch3
Experimental procedure for1: A solution of 0.60 g (10.0 mmol) of chromium (VI) oxide in 5 mL of water was added dropwise to 50 mL of formic acid (88%). The resulting blue solution was diluted with 50 mL of water and adsorbed on a 1.5 x 7 cm column of Dowex 50X2‐200 cation exchange resin. After washing the column with water the blue ion was removed with 0.5Maqueousp‐toluenesulfonic acid solution. Upon slow evaporation violet crystals of1[p‐CH3C6H4SO3]3· 2H2O were obtained which were separated from solidp‐toluenesulfonic acid by extensively washing with acetone. These crystals (0.53 g 20%) were suitable for X‐ray diffraction studies. Correct elemental analysis (C H S).1H NMR (300 MHz CD3OD): δ = 7.7 (br 6H) 7.24 (s 6H) 4.88 (s 17H + HOD) 2.36 (s 6H); FT‐IR (KBr): ṽ[cm−1] = 3337 3141 2471 1604 1497 1457 1409 1390 1376 1214 1203 1155 1127 1036 1011 813 761 729 718 686 619 565; UV/VIS (H2O): ṽ[nm] = 254(ϵ = 1180 mol−1cm−1/Cr) 410(44) 572(46) 632(sh); magnetic susceptibility: μeff/Cr = 3.54 (290 K. solid state) 3.5 μB(293 K CD3OD solution); crystal data at 295 K: monoclinic space groupC2/c (No. 15) a= 15.920(3) Å b= 17.381(3) Å c= 26.517(4) Å β = 91.77(1)° V= 7334(4) Å3 Mr= 868.73 g mol−1 ϱobsd= 1.57(1) g cm−3 ϱcalcd= 1.573 g cm−1 Z= 8. For 4552 unique observed reflections withF2> 3σ(F2) and 526 variable parameters the current discrepancy indices areR= 0.051 and Rw= 0.067. Further details of the crystal structure determination may be obtained from the Fachinformationszentrum Karlsruhe Gesellschaft für Wissenschaftlich‐technische Information mbH D 7514 Eggenstein‐Leo‐poldshafen 2 (FRG) by quoting the depository number CSD‐54568 the names of the authors and the journal citation.
10.1021/ja00328a064
10.1016/S0898-8838(08)60231-7
10.1002/9780470166208.ch4
(c) en = 1 2‐diaminoethane phen = 1.10‐phenanthroline metacn = 1 4 7‐trimethyl‐1 4 7‐triazacyclononane.
(a) Determined by fit of solid‐state SQUID susceptometry from 6‐300 K to the theoretical expression forH= −2JS1·S2withS1 =S2= 3/2 g= 1.978(1) p= 1.03(1)%;
10.1002/9780470166307.ch4
10.1021/ja00258a023
10.1021/bk-1988-0372.ch008
10.1002/ange.19891010905
10.1002/anie.198911531
{'key': 'e_1_2_1_6_5', 'first-page': '1530', 'volume': '1986', 'author': 'Wieghardt K.', 'journal-title': 'J. Chem. Soc. Chem. Commun.'} / J. Chem. Soc. Chem. Commun. by Wieghardt K.
10.1021/ic00151a008
10.1021/ja00226a053
10.1002/ange.19881000306
10.1002/anie.198803441
{'key': 'e_1_2_1_7_4', 'first-page': '373', 'volume-title': 'Iron Carriers and Iron Proteins', 'author': 'Sanders‐Loehr J.', 'year': '1989'} / Iron Carriers and Iron Proteins by Sanders‐Loehr J. (1989)
10.1021/ic00267a018

Dates

Type	When
Created	21 years, 7 months ago (Dec. 30, 2003, 7:07 p.m.)
Deposited	1 year, 9 months ago (Oct. 22, 2023, 2:52 p.m.)
Indexed	1 year, 7 months ago (Jan. 18, 2024, 11:01 p.m.)
Issued	35 years, 1 month ago (July 1, 1990)
Published	35 years, 1 month ago (July 1, 1990)
Published Online	21 years, 8 months ago (Dec. 22, 2003)
Published Print	35 years, 1 month ago (July 1, 1990)

Funders 0

None

BibTeX

@article{Turowski_1990, title={μ‐Hydroxobis(μ‐formato)hexaaquadichromium(<scp>III</scp>), an Intermediate in the Formation of Basic Chromium Carboxylates}, volume={29}, ISSN={0570-0833}, url={http://dx.doi.org/10.1002/anie.199008111}, DOI={10.1002/anie.199008111}, number={7}, journal={Angewandte Chemie International Edition in English}, publisher={Wiley}, author={Turowski, Petra N. and Bino, Avi and Lippard, Stephen J.}, year={1990}, month=jul, pages={811–812} }

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