DOI: 10.1002/anie.198607401. A Radical Anion Salt of 2,5‐Dimethyl‐<i>N,N</i>′‐dicyanoquinonediimine with Extremely High Electrical Conductivity

A Radical Anion Salt of 2,5‐Dimethyl‐N,N′‐dicyanoquinonediimine with Extremely High Electrical Conductivity

10.1002/anie.198607401

Crossref journal-article

Wiley

Angewandte Chemie International Edition in English (311)

Bibliography

AumÃ¼ller, A., Erk, P., Klebe, G., HÃ¼nig, S., von SchÃ¼tz, J. U., & Werner, H. (1986). A Radical Anion Salt of 2,5âDimethylâN,Nâ²âdicyanoquinonediimine with Extremely High Electrical Conductivity. Angewandte Chemie International Edition in English, 25(8), 740â741. Portico.

Authors 6

Alexander Aumüller (first)
Peter Erk (additional)
Gerhard Klebe (additional)
Siegfried Hünig (additional)
Jost Ulrich von Schütz (additional)
Hans‐Peter Werner (additional)

References 21 Referenced 401

10.1021/ja00784a066
10.1051/jphys:0197900400120119900
10.1107/S0567740871003996
{'key': 'e_1_2_1_2_3', 'volume': '1967', 'author': 'Silverman I.', 'year': '1941', 'journal-title': 'J. Chem. Soc. B'} / J. Chem. Soc. B by Silverman I. (1941)
10.1016/S0040-4039(00)94784-1
10.1021/jo00156a048
10.1021/jo00909a019
10.1002/ange.19840960620
10.1002/anie.198404471
10.1002/jlac.198619860114
{'key': 'e_1_2_1_5_2', 'first-page': '1216', 'volume': '1985', 'author': 'Hünig S.', 'journal-title': 'Liebigs Ann. Chem.'} / Liebigs Ann. Chem. by Hünig S.
10.1002/ange.19840960621
10.1002/anie.198404491
Procedure: Boiling solutions of 2 5‐DM‐DCNQI (184 mg 1.00 mmol) in CH3CN (20 mL) and CuI (128 mg 672 mmol) in CH3CN (10 mL) were combined allowed to cool and the black precipitate filtered off under suction. Yield: 188 mg (87%) (2 5‐DM‐DCNQI)2Cu; m.p. 229°C (decomp.); correct C H N analyses.
Procedure: A solution of 2 5‐DM‐DCNQI (46 mg 250 mmol) and CuBr2(223 mg 1.00 mmol) in CH3CN (60 mL) was electrolyzed with a current density of 53 μA cm−1for 72 h in a cell furnished with diaphragms and Pt electrodes. 17 mg (30%) of up to 6‐cm long black needles of [2 5‐DM‐DCNQI]2Cu separated at the cathode. M.p. 229°C (decomp.); correct C H N analysis.
Four‐point conductivity measurements with vaporized gold strips perpendicular to the crystal axis. Measurements of the anisotropy of the conductivity with reduced contact dimensions are presently under way.
{'key': 'e_1_2_1_10_2', 'first-page': '108', 'volume-title': 'Quantum Theory of Solids', 'author': 'Peierls R. E.', 'year': '1955'} / Quantum Theory of Solids by Peierls R. E. (1955)
10.1515/zna-1978-0312 / Z. Naturforsch. A by Afifiy H. H. (1978)
10.1107/S0567740875002634
Further details of the crystal structure investigation are available on request from the Fachinformationszentrum Energie Physik Mathematik GmbH D‐7514 Eggenstein‐Leopoldshafen 2 on quoting the depository number CSD‐51963 the names of the authors and the full citation of the journal.
J. U.von Schütz H. P.Werner H. C.Wolf A.Aumüller P.Erk S.Hünig Proc. Colloq. AMPERE23(1986) in press.

Dates

Type	When
Created	21 years, 7 months ago (Dec. 31, 2003, 4:19 a.m.)
Deposited	1 year, 10 months ago (Sept. 26, 2023, 8:29 p.m.)
Indexed	6 hours, 45 minutes ago (Aug. 24, 2025, 6:54 p.m.)
Issued	39 years ago (Aug. 1, 1986)
Published	39 years ago (Aug. 1, 1986)
Published Online	21 years, 8 months ago (Dec. 22, 2003)
Published Print	39 years ago (Aug. 1, 1986)

Funders 0

None

BibTeX

@article{Aum_ller_1986, title={A Radical Anion Salt of 2,5‐Dimethyl‐N,N′‐dicyanoquinonediimine with Extremely High Electrical Conductivity}, volume={25}, ISSN={0570-0833}, url={http://dx.doi.org/10.1002/anie.198607401}, DOI={10.1002/anie.198607401}, number={8}, journal={Angewandte Chemie International Edition in English}, publisher={Wiley}, author={Aumüller, Alexander and Erk, Peter and Klebe, Gerhard and Hünig, Siegfried and von Schütz, Jost Ulrich and Werner, Hans‐Peter}, year={1986}, month=aug, pages={740–741} }

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