Catalysis by Molecular Metal Clusters
10.1002/anie.198301351
Crossref journal-article
Wiley
Angewandte Chemie International Edition in English (311)
Abstract

AbstractMolecular metal clusters form a very large and diverse family. They present the opportunity of modeling the intermediates involved in surface mediated catalytic reactions, of providing a source of very reactive mononuclear metal fragments, and of effecting catalytic cycles in which the cluster remains intact. The last mentioned aspect is the subject of this review article. The state‐of‐the‐art of cluster catalysis is critically analyzed. The possibilities offered by molecular metal catalysts of performing catalytic reactions at multimetal atom sites are also discussed.

Bibliography

Muetterties, E. L., & Krause, M. J. (1983). Catalysis by Molecular Metal Clusters. Angewandte Chemie International Edition in English, 22(2), 135–148. Portico.

Authors 2
  1. Earl L. Muetterties (first)
  2. Michael J. Krause (additional)
References 138 Referenced 135
  1. (a) The catalyst introduced into a reaction system is more accurately described as the catalyst precursor because the active catalytic species may be formed under the reaction conditions. (b) Catalysts are conventional classified as homogenous or heterogenous. However is general classification is at best misleading in that even interfacial catalytic reactions can be homogenous because they occur largely in a single phase although it may be predimonantly two dimensional. (c) This classification obviates the need for imprecise and inelegant descriptions like “heterogenezing of a homogenous catalyst”.e.g.anchoring or immobilizing a molecular catalyst to a unit support does not alter the nature of the catalysis. The effect of supporting the molecular species may however inhibit reactions that normally would occur with the same species in solution although metal atoms are mobile to varying degress on such surfaces. This mobility is sensitive to the nature of the gaseous reactants: CO has a marked tendency to “mobilize” metal atoms.
  2. {'key': 'e_1_2_1_2_2', 'volume-title': 'Chemistry of Catalytic Processes', 'author': 'Gates B. C.', 'year': '1979'} / Chemistry of Catalytic Processes by Gates B. C. (1979)
  3. {'key': 'e_1_2_1_3_2', 'volume-title': 'Homogeneous Catalysis', 'author': 'Parshall G. W.', 'year': '1980'} / Homogeneous Catalysis by Parshall G. W. (1980)
  4. 10.1016/S0022-328X(00)93961-5
  5. 10.1021/cen-v044n034.p056
  6. 10.1080/01614947508079986
  7. 10.1002/bscb.19750841006
  8. 10.1002/bscb.19760850701
  9. 10.1021/cr60318a001
  10. E. L.Muetterties R. M.Wexler Surv. Prog. Chem. in press.
  11. In the characterization of chemisorbed acetylene and hydrogen on Pt(III) the results of IR studies indicated [10] that (1) the surface species was ethylidyne (CH3C) and (2) that the α‐carbon atom was over a three‐fold surface site and symmetrically bonded to three platinum atoms (the CC‐bond vector is normal to the Pt3‐plane). The paradigm for this species in cluster chemistry is [(μ3‐CH3C)Co3(CO)9][11]. A comparative vibrational spectroscopic analysis of this cluster with the data for acetylene/hydrogen chemisorbed on Pt confirmed the ethylidyne hypothesis [12].
  12. 10.1063/1.437772
  13. {'key': 'e_1_2_1_11_2', 'first-page': '98', 'volume': '14', 'author': 'Seyferth D.', 'year': '1976', 'journal-title': 'Adv. Organomet. Chem.'} / Adv. Organomet. Chem. by Seyferth D. (1976)
  14. 10.1039/f29817700397
  15. 10.1021/ja00851a057
  16. 10.1021/ja00788a025
  17. 10.1021/ja00495a074
  18. 10.1021/cen-v060n035.p028
  19. 10.1016/S0022-328X(00)88636-2
  20. {'key': 'e_1_2_1_16_3', 'first-page': '545', 'volume-title': 'Transition Metal Clusters', 'author': 'Whyman R.', 'year': '1980'} / Transition Metal Clusters by Whyman R. (1980)
  21. (c)B. F. G.Johnsonin [16b] p. 471;
  22. (d)K.Wadein [16b] p. 193;
  23. 10.1016/S0022-328X(00)91219-1
  24. 10.1002/9780470166260.ch3
  25. 10.1016/S0065-2792(08)60329-5
  26. (h)A. J.Deemingin [16b] p. 391;
  27. {'key': 'e_1_2_1_16_10', 'volume-title': 'Organic Synthesis via Metal Carbonyls', 'author': 'Hübel W.', 'year': '1968'} / Organic Synthesis via Metal Carbonyls by Hübel W. (1968)
  28. 10.1016/S0065-3055(08)60309-3
  29. 10.1002/cber.19821151003
  30. 10.1021/ic50142a040
  31. (m)J. S.Bradley Phil. Trans. R. Soc. London in press;
  32. 10.1016/S0022-328X(00)93954-8
  33. 10.1021/ja00518a018
  34. 10.1021/ja00518a019
  35. 10.1021/ja00518a020
  36. 10.1021/ja00518a021
  37. 10.1007/BFb0047779
  38. ηxand μxindicate the number of ligand atoms bonded to the metal atom and how many metal atoms are bonded to one ligand respectively: μ without an index signifies that the ligand bridges two metal atoms.
  39. {'key': 'e_1_2_1_19_2', 'first-page': '807', 'volume': '1974', 'author': 'Deeming A. J.', 'journal-title': 'J. Chem. Soc. Chem. Commun.'} / J. Chem. Soc. Chem. Commun. by Deeming A. J.
  40. 10.1016/S0022-328X(00)91427-X
  41. 10.1002/cber.19821150703
  42. 10.1002/cber.19821150702
  43. {'key': 'e_1_2_1_22_2', 'first-page': '861', 'volume': '1968', 'author': 'Johnson B. F. G.', 'journal-title': 'Chem. Commun.'} / Chem. Commun. by Johnson B. F. G.
  44. 10.1146/annurev.pc.33.100182.000513
  45. A. M.Stolzenberg E. L.Muetterties J. Am. Chem. Soc. in press.
  46. N. J.Coville A. M.Stolzenberg E. L.Muetterties J. Am. Chem. Soc. in press.
  47. 10.1021/ja00420a052
  48. (a)C. U.Pittman Jr. R.Ryan W. D.Wilson G.Wileman M.AbsiHalabi the Division of Petroleum Chemistry Am. Chem. Soc. Meet. San Francisco August 24 1980 p. 714;
  49. 10.1016/S0022-328X(00)94243-8
  50. 10.1021/ja00840a068
  51. 10.1021/ja00470a057
  52. 10.1111/j.1749-6632.1980.tb53636.x
  53. 10.1021/ic50084a034
  54. 10.1016/S0022-328X(00)84665-3
  55. 10.1021/ja00421a059
  56. {'key': 'e_1_2_1_33_2', 'first-page': '870', 'volume': '1979', 'author': 'Yoshida T.', 'journal-title': 'J. Chem. Soc. Chem. Commun.'} / J. Chem. Soc. Chem. Commun. by Yoshida T.
  57. 10.1021/ja00464a060
  58. 10.1021/ja00518a056
  59. W.Walker J. B.Cropley US‐Pat. 3940432 (1976) Union Carbide;
  60. E. S.Brown US‐Pat. 3974259 (1976) Union Carbide;
  61. J. L.Vidal Z. C.Mester W.Walker US‐Pat. 4115428 (1978) Union Carbide.
  62. R. M.Laine B. R.Cho R. B.Wilson Jr. J. C1Molecules1(1983) in press.
  63. 10.1021/ja00480a075
  64. 10.1021/ja00443a049
  65. 10.1021/ja00842a061
  66. 10.1021/jo01304a053
  67. 10.1016/0304-5102(82)80034-5
  68. 10.1016/0304-5102(77)85011-6
  69. 10.1021/ic50191a001
  70. 10.1016/S0022-328X(00)84730-0
  71. 10.1016/S0022-328X(00)83702-X
  72. {'key': 'e_1_2_1_45_2', 'first-page': '107', 'volume': '55', 'author': 'Heil B.', 'year': '1968', 'journal-title': 'Acta Chim. Acad. Sci. Hung.'} / Acta Chim. Acad. Sci. Hung. by Heil B. (1968)
  73. 10.1016/S0020-1693(00)89030-1
  74. 10.1016/S0020-1693(00)94118-5
  75. 10.1021/ja00467a038
  76. {'key': 'e_1_2_1_48_2', 'first-page': '709', 'volume': '1972', 'author': 'Chini P.', 'journal-title': 'J. Chem. Soc. Chem. Commun.'} / J. Chem. Soc. Chem. Commun. by Chini P.
  77. 10.1016/S0065-3055(08)60320-2
  78. 10.1021/ja00539a054
  79. 10.1021/ja00488a057
  80. {'key': 'e_1_2_1_52_2', 'first-page': '753', 'volume': '1980', 'author': 'Shvo Y.', 'journal-title': 'J. Chem. Soc. Chem. Commun.'} / J. Chem. Soc. Chem. Commun. by Shvo Y.
  81. 10.1021/ja00399a077
  82. 10.1016/S0022-328X(00)98124-5
  83. 10.1021/ja00383a044
  84. 10.1021/ja00450a062
  85. 10.1021/ja00514a011
  86. 10.1021/ar00062a001
  87. 10.1021/ja00369a058
  88. 10.1021/ja00467a038
  89. 10.1016/S0020-1693(00)83715-9
  90. 10.1021/ja00475a019
  91. 10.1021/ic50219a054
  92. 10.1021/ja00441a082
  93. V. W.Day D. L.Thorn E. L.Muetterties unpublished results.
  94. 10.1021/ic50213a026
  95. 10.1021/ja00842a061
  96. 10.1021/ja00431a051
  97. 10.1021/ja00445a014
  98. 10.1021/ic50208a024
  99. 10.1080/03602458108068076
  100. 10.1080/03602458108068066
  101. {'key': 'e_1_2_1_72_2', 'first-page': '919', 'volume': '1976', 'author': 'Manassero M.', 'journal-title': 'J. Chem. Soc. Chem. Commun.'} / J. Chem. Soc. Chem. Commun. by Manassero M.
  102. 10.1016/S0022-328X(00)83498-1
  103. 10.1021/ja00533a051
  104. 10.1021/ja00533a052
  105. 10.1021/ja00396a032
  106. 10.1021/ja00504a013
  107. (b)R. D.Adams Acc. Chem. Res. in press.
  108. 10.1021/ic50206a021
  109. {'key': 'e_1_2_1_78_2', 'first-page': '1395', 'volume': '1982', 'author': 'Nicholls J. N.', 'journal-title': 'J. Chem. Soc. Dalton Trans.'} / J. Chem. Soc. Dalton Trans. by Nicholls J. N.
  110. R. L.Pruett W. W.Walker US‐Pat. 3833634 (1974) 3957857 (1976) Union Carbide.
  111. 10.1021/ja00421a059
  112. 10.1021/ic50225a092
  113. C.Masters J. A.Van Doorn DOS 2644185 (1975) Shell Ltd.
  114. 10.1007/978-1-4613-2958-9_12
  115. 10.1021/ja00450a065
  116. 10.1021/ic50222a054
  117. 10.1021/ic50222a055
  118. 10.1039/cs9811000455
  119. {'key': 'e_1_2_1_88_2', 'volume-title': 'Nitrogen Fixation', 'author': 'Newton W. E.', 'year': '1980'} / Nitrogen Fixation by Newton W. E. (1980)
  120. J.Kouba E. L.Muetterties V. W.Day unpublished results.
  121. {'key': 'e_1_2_1_90_2', 'first-page': '610', 'volume': '1982', 'author': 'Johnson B. F. G.', 'journal-title': 'J. Chem. Soc. Chem. Commun.'} / J. Chem. Soc. Chem. Commun. by Johnson B. F. G.
  122. {'key': 'e_1_2_1_91_2', 'first-page': '84', 'volume': '1', 'author': 'Buen M. J.', 'year': '1982', 'journal-title': 'Organometallics'} / Organometallics by Buen M. J. (1982)
  123. 10.1021/om00066a022
  124. 10.1021/ja00466a074
  125. 10.1073/pnas.76.5.2099
  126. 10.1007/978-1-4613-2958-9_33
  127. 10.1021/ic50220a040
  128. 10.1021/ic50204a018
  129. 10.1021/ja00511a016
  130. 10.1021/ja00408a039
  131. 10.1021/om00061a030
  132. 10.1021/ja00379a040
  133. (b)R. R.Burch A. J.Shusterman E. L.Muetterties R. G.Teller J. M.Williams J. Am. Chem. Soc. in press.
  134. 10.1021/ja00373a066
  135. 10.1021/om00069a034
  136. 10.1021/om00062a034
  137. {'key': 'e_1_2_1_105_2', 'first-page': '1104', 'volume': '1981', 'author': 'Frost P. W.', 'journal-title': 'J. Chem. Soc. Chem. Commun.'} / J. Chem. Soc. Chem. Commun. by Frost P. W.
  138. {'key': 'e_1_2_1_106_2', 'first-page': '716', 'volume': '1981', 'author': 'Gregson D.', 'journal-title': 'J. Chem. Soc. Chem. Commun.'} / J. Chem. Soc. Chem. Commun. by Gregson D.
Dates
Type When
Created 21 years, 7 months ago (Dec. 31, 2003, 3:31 a.m.)
Deposited 1 year, 10 months ago (Oct. 18, 2023, 9:16 p.m.)
Indexed 1 month, 3 weeks ago (June 30, 2025, 7:26 a.m.)
Issued 42 years, 6 months ago (Feb. 1, 1983)
Published 42 years, 6 months ago (Feb. 1, 1983)
Published Online 21 years, 8 months ago (Dec. 22, 2003)
Published Print 42 years, 6 months ago (Feb. 1, 1983)
Funders 0

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@article{Muetterties_1983, title={Catalysis by Molecular Metal Clusters}, volume={22}, ISSN={0570-0833}, url={http://dx.doi.org/10.1002/anie.198301351}, DOI={10.1002/anie.198301351}, number={2}, journal={Angewandte Chemie International Edition in English}, publisher={Wiley}, author={Muetterties, Earl L. and Krause, Michael J.}, year={1983}, month=feb, pages={135–148} }