DOI: 10.1002/anie.197309541. Asymmetric Syntheses with the Aid of Homogeneous Transition Metal Catalysts

Asymmetric Syntheses with the Aid of Homogeneous Transition Metal Catalysts

10.1002/anie.197309541

Crossref journal-article

Wiley

Angewandte Chemie International Edition in English (311)

Abstract

AbstractThe progress made in the field of homogeneous catalysis during the last five to six years has led, inter alia, to the development of highly selective catalysts for asymmetric syntheses. Homogeneous asymmetric hydrogenation, using well defined transition metal catalysts, may be achieved with optical yields of 85 to 90% or more. Catalytic reactions, in which the chiral centers are generated by CC bond formation, can result in optical yields of 70 to 80%. The hydrogenation catalysts consist primarily of rhodium(I) complexes containing “Homer phosphanes”, phosphanes with chiral C atoms, or optically active amides. Catalysts which induce optical activity through the formation of CC bonds have been developed from π‐allylnickel halides, Lewis acids, and phosphanes containing chiral C atoms. The results obtained signify a breakthrough in an area of catalysis previously restricted to syntheses involving enzymes.

Bibliography

BogdanoviÄ, B., Henc, B., LÃ¶sler, A., Meister, B., Pauling, H., & Wilke, G. (1973). Asymmetric Syntheses with the Aid of Homogeneous Transition Metal Catalysts. Angewandte Chemie International Edition in English, 12(12), 954â964. Portico.

Authors 6

Borislav Bogdanović (first)
Biserka Henc (additional)
Arnold Lösler (additional)
Burkhard Meister (additional)
Horst Pauling (additional)
Günther Wilke (additional)

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Dates

Type	When
Created	21 years, 8 months ago (Dec. 31, 2003, 7:44 a.m.)
Deposited	1 year, 10 months ago (Oct. 19, 2023, 6:44 a.m.)
Indexed	2 months, 2 weeks ago (June 23, 2025, 5:23 p.m.)
Issued	51 years, 9 months ago (Dec. 1, 1973)
Published	51 years, 9 months ago (Dec. 1, 1973)
Published Online	21 years, 8 months ago (Dec. 22, 2003)
Published Print	51 years, 9 months ago (Dec. 1, 1973)

Funders 0

None

BibTeX

@article{Bogdanovi__1973, title={Asymmetric Syntheses with the Aid of Homogeneous Transition Metal Catalysts}, volume={12}, ISSN={0570-0833}, url={http://dx.doi.org/10.1002/anie.197309541}, DOI={10.1002/anie.197309541}, number={12}, journal={Angewandte Chemie International Edition in English}, publisher={Wiley}, author={Bogdanović, Borislav and Henc, Biserka and Lösler, Arnold and Meister, Burkhard and Pauling, Horst and Wilke, Günther}, year={1973}, month=dec, pages={954–964} }

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