DOI: 10.1002/anie.197000501. Reactions with Addition Compounds Containing Activated Formic Acid

Reactions with Addition Compounds Containing Activated Formic Acid

10.1002/anie.197000501

Crossref journal-article

Wiley

Angewandte Chemie International Edition in English (311)

Abstract

AbstractAddition compounds of formic acid with tertiary organic bases in ratios higher than that required for salt formation (3:1 and 2:1 adducts) contain formic acid in a highly activated form. In particular, the 3:1 adducts of formic acid with trimethylamine and triethylamine are liquid reducing agents that are convenient to handle and are suitable for use in many selective reductions. These addition compounds have a surprisingly strong reducing action on sulfur dioxide, which is rapidly converted, even at low concentrations, into crystalline rhombic sulfur. Sulfones and polysulfones can be prepared in good yields by three‐component reactions from activated formic acid, sulfur dioxide, and polarized vinyl compounds.

Bibliography

Wagner, K. (1970). Reactions with Addition Compounds Containing Activated Formic Acid. Angewandte Chemie International Edition in English, 9(1), 50â54. Portico.

Authors 1

K. Wagner (first)

References 19 Referenced 32

R.Wietzel German Pat. – 12 q I.19.30 (5) (1930) I. G. Farben.
10.1021/ja01338a041
H.Holtschmidt unpublished.
H.HoltschmidtandK.Wagner DBP 1132118 (Feb. 1 1961) Farbenfabriken Bayer.
H.HoltschmidtandK.Wagner unpublished.
K.WagnerandH.Holtschmidt German Pat. 1233398 (March 14 1964) Farbenfabriken Bayer
10.1021/ja01232a022
10.1063/1.1750309
M.Pestemer N.Joop andK.Wagner unpublished.
K.Wagner unpublished.
K.Wagner US‐Pat. 3397963 (April 1 1965) Farbenfabriken Bayer.
R.Haszeldine R.Farmer andH.Goldwhite Brit. Pat. 1019891 (Feb. 9 1966);
{'key': 'e_1_2_1_12_3', 'first-page': '12549', 'volume': '64', 'year': '1966', 'journal-title': 'Chem. Abstr.'} / Chem. Abstr. (1966)
K.Wagner German Pat. Appl. P 1793243.3 (April 21 1968) Farbenfabriken Bayer.
{'key': 'e_1_2_1_14_2', 'first-page': '142', 'volume': '2', 'author': 'Adadurow I. E.', 'year': '1931', 'journal-title': 'Ž. fiz. Chim.'} / Ž. fiz. Chim. by Adadurow I. E. (1931)
{'key': 'e_1_2_1_14_3', 'first-page': 'I 1240', 'volume': '1933', 'journal-title': 'Chem. Zbl.'} / Chem. Zbl.
K.Wagner German Pat. Appl. P 1442692.7 (April 4 1964);
US‐Pat. 3397963 (April 1 1965).
K.Wagner DBP 1222048 (Dec. 8 1964) Farbenfabriken Bayer.

Dates

Type	When
Created	21 years, 8 months ago (Dec. 31, 2003, 3:15 p.m.)
Deposited	1 year, 10 months ago (Oct. 19, 2023, 4:54 a.m.)
Indexed	1 year, 9 months ago (Nov. 23, 2023, 10:19 p.m.)
Issued	55 years, 8 months ago (Jan. 1, 1970)
Published	55 years, 8 months ago (Jan. 1, 1970)
Published Online	21 years, 8 months ago (Dec. 22, 2003)
Published Print	55 years, 8 months ago (Jan. 1, 1970)

Funders 0

None

BibTeX

@article{Wagner_1970, title={Reactions with Addition Compounds Containing Activated Formic Acid}, volume={9}, ISSN={0570-0833}, url={http://dx.doi.org/10.1002/anie.197000501}, DOI={10.1002/anie.197000501}, number={1}, journal={Angewandte Chemie International Edition in English}, publisher={Wiley}, author={Wagner, K.}, year={1970}, month=jan, pages={50–54} }

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