DOI: 10.1002/ange.201408354. N‐Heterocyclic Carbene–Phosphinidyne Transition Metal Complexes

N‐Heterocyclic Carbene–Phosphinidyne Transition Metal Complexes

10.1002/ange.201408354

Crossref journal-article

Wiley

Angewandte Chemie (311)

Abstract

AbstractThe N‐heterocyclic carbene–phosphinidene adduct IPrPSiMe3 is introduced as a synthon for the preparation of terminal carbene–phosphinidyne transition metal complexes of the type [(IPrP)MLn] (MLn=(η6‐p‐cymene)RuCl) and (η5‐C5Me5)RhCl). Their spectroscopic and structural characteristics, namely low‐field 31P NMR chemical shifts and short metal–phosphorus bonds, show their similarity with arylphosphinidene complexes. The formally mononegative IPrP ligand is also capable of bridging two or three metal atoms as demonstrated by the preparation of bi‐ and trimetallic RuAu, RhAu, Rh2, and Rh2Au complexes.

Bibliography

Doddi, A., Bockfeld, D., Bannenberg, T., Jones, P. G., & Tamm, M. (2014). NâHeterocyclic CarbeneâPhosphinidyne Transition Metal Complexes. Angewandte Chemie, 126(49), 13786â13790. Portico.

Authors 5

Adinarayana Doddi (first)
Dirk Bockfeld (additional)
Thomas Bannenberg (additional)
Peter G. Jones (additional)
Matthias Tamm (additional)

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X‐ray crystallographic analysis performed several times on crystals of8resulted in crystallographic data of only modest quality. Therefore the structure is not included in the main text (see Figure S40 and Table S6 in the SI). Nevertheless the data are sufficient to demonstrate the connectivity thereby confirming the presence of a bent Rh‐P‐C moiety (110.2(2)°). The Rh–P bond length of 2.1968(16) Å falls in the range found for rhodium–phosphinidene complexes for example Rh–P 2.1903(4) Å in [(η5‐C5Me5)(PPh3)Rh(PMes*)].[26b]
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Dates

Type	When
Created	10 years, 10 months ago (Oct. 6, 2014, 4:31 p.m.)
Deposited	1 year, 10 months ago (Oct. 17, 2023, 6:31 p.m.)
Indexed	1 year, 1 month ago (July 24, 2024, 5:07 a.m.)
Issued	10 years, 10 months ago (Oct. 6, 2014)
Published	10 years, 10 months ago (Oct. 6, 2014)
Published Online	10 years, 10 months ago (Oct. 6, 2014)
Published Print	10 years, 8 months ago (Dec. 1, 2014)

Funders 0

None

BibTeX

@article{Doddi_2014, title={N‐Heterocyclic Carbene–Phosphinidyne Transition Metal Complexes}, volume={126}, ISSN={1521-3757}, url={http://dx.doi.org/10.1002/ange.201408354}, DOI={10.1002/ange.201408354}, number={49}, journal={Angewandte Chemie}, publisher={Wiley}, author={Doddi, Adinarayana and Bockfeld, Dirk and Bannenberg, Thomas and Jones, Peter G. and Tamm, Matthias}, year={2014}, month=oct, pages={13786–13790} }

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