DOI: 10.1002/ange.201307319. Nitrogen‐Doped Carbon Nanosheets with Size‐Defined Mesopores as Highly Efficient Metal‐Free Catalyst for the Oxygen Reduction Reaction

Nitrogen‐Doped Carbon Nanosheets with Size‐Defined Mesopores as Highly Efficient Metal‐Free Catalyst for the Oxygen Reduction Reaction

10.1002/ange.201307319

Crossref journal-article

Wiley

Angewandte Chemie (311)

Abstract

AbstractNitrogen‐doped carbon nanosheets (NDCN) with size‐defined mesopores are reported as highly efficient metal‐free catalyst for the oxygen reduction reaction (ORR). A uniform and tunable mesoporous structure of NDCN is prepared using a templating approach. Such controlled mesoporous structure in the NDCN exerts an essential influence on the electrocatalytic performance in both alkaline and acidic media for the ORR. The NDCN catalyst with a pore diameter of 22 nm exhibits a more positive ORR onset potential than that of Pt/C (−0.01 V vs. −0.02 V) and a high diffusion‐limited current approaching that of Pt/C (5.45 vs. 5.78 mA cm−2) in alkaline medium. Moreover, the catalyst shows pronounced electrocatalytic activity and long‐term stability towards the ORR under acidic conditions. The unique planar mesoporous shells of the NDCN provide exposed highly electroactive and stable catalytic sites, which boost the electrocatalytic activity of metal‐free NDCN catalyst.

Bibliography

Wei, W., Liang, H., Parvez, K., Zhuang, X., Feng, X., & MÃ¼llen, K. (2014). NitrogenâDoped Carbon Nanosheets with SizeâDefined Mesopores as Highly Efficient MetalâFree Catalyst for the Oxygen Reduction Reaction. Angewandte Chemie, 126(6), 1596â1600. Portico.

Authors 6

Wei Wei (first)
Haiwei Liang (additional)
Khaled Parvez (additional)
Xiaodong Zhuang (additional)
Xinliang Feng (additional)
Klaus Müllen (additional)

References 60 Referenced 235

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{'key': 'e_1_2_2_15_2', 'first-page': '491604', 'author': 'Ramaswamy N.', 'year': '2012', 'journal-title': 'Adv. Phys. Chem.'} / Adv. Phys. Chem. by Ramaswamy N. (2012)
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Dates

Type	When
Created	11 years, 7 months ago (Jan. 23, 2014, 6:15 p.m.)
Deposited	1 year, 10 months ago (Oct. 17, 2023, 3:59 p.m.)
Indexed	3 months, 1 week ago (May 20, 2025, 9:52 a.m.)
Issued	11 years, 7 months ago (Jan. 23, 2014)
Published	11 years, 7 months ago (Jan. 23, 2014)
Published Online	11 years, 7 months ago (Jan. 23, 2014)
Published Print	11 years, 6 months ago (Feb. 3, 2014)

Funders 0

None

BibTeX

@article{Wei_2014, title={Nitrogen‐Doped Carbon Nanosheets with Size‐Defined Mesopores as Highly Efficient Metal‐Free Catalyst for the Oxygen Reduction Reaction}, volume={126}, ISSN={1521-3757}, url={http://dx.doi.org/10.1002/ange.201307319}, DOI={10.1002/ange.201307319}, number={6}, journal={Angewandte Chemie}, publisher={Wiley}, author={Wei, Wei and Liang, Haiwei and Parvez, Khaled and Zhuang, Xiaodong and Feng, Xinliang and Müllen, Klaus}, year={2014}, month=jan, pages={1596–1600} }

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