DOI: 10.1002/ange.201006424. Chemie mit Methan: Studieren geht über Probieren!

Chemie mit Methan: Studieren geht über Probieren!

10.1002/ange.201006424

Crossref journal-article

Wiley

Angewandte Chemie (311)

Abstract

AbstractKonzeptionelle Überlegungen zu und mechanistische Aspekte von vier scheinbar einfachen chemischen Umsetzungen, die in der Chemie von Methan von Bedeutung sind, werden in diesem Aufsatz behandelt: 1) die metallvermittelte Dehydrierung unter Bildung von Metallcarbenkomplexen, 2) die Wasserstoffabstraktion als Schlüsselschritt der oxidativen Dimerisierung von Methan, 3) der Mechanismus der CH4→CH3OH‐Umwandlung, und 4) die Reihenfolge der C‐H‐ und O‐H‐Bindungsaktivierung und die Frage nach dem geschwindigkeitsbestimmenden Schritt in der selektiven Oxidation von Methanol zu Formaldehyd. Moderne Gasphasenexperimente, in Verbindung mit Elektronenstrukturrechnungen, liefern Einblicke in elementare Reaktionsschritte auf molekularer Ebene und enthüllen reaktionsmechanistische Details. Die Ergebnisse dieser Untersuchungen werden, wo dies angebracht erscheint, mit Beobachtungen aus entsprechenden Studien in Lösung oder auf Oberflächen verglichen.

Bibliography

Schwarz, H. (2011). Chemie mit Methan: Studieren geht Ã¼ber Probieren! Angewandte Chemie, 123(43), 10276â10297. Portico.

Authors 1

Helmut Schwarz (first)

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10.1021/cr980452i
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10.1103/PhysRevB.80.075424
10.1103/PhysRevLett.104.035503
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10.1007/s00214-010-0732-8
10.1039/b925294k
10.1039/c0cp01171a
10.1021/ar100093z
10.1039/c0cs00165a
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Drei weitere wichtige Aufsätze verdienen es erwähnt zu werden:
10.1038/nature07371
10.1039/c003079c
10.1021/ar1001473

Dates

Type	When
Created	14 years, 2 months ago (June 8, 2011, 8:53 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 6:51 p.m.)
Indexed	3 months, 1 week ago (May 22, 2025, 4:07 a.m.)
Issued	14 years, 2 months ago (June 8, 2011)
Published	14 years, 2 months ago (June 8, 2011)
Published Online	14 years, 2 months ago (June 8, 2011)
Published Print	13 years, 10 months ago (Oct. 17, 2011)

Funders 0

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BibTeX

@article{Schwarz_2011, title={Chemie mit Methan: Studieren geht über Probieren!}, volume={123}, ISSN={1521-3757}, url={http://dx.doi.org/10.1002/ange.201006424}, DOI={10.1002/ange.201006424}, number={43}, journal={Angewandte Chemie}, publisher={Wiley}, author={Schwarz, Helmut}, year={2011}, month=jun, pages={10276–10297} }

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  "abstract": "<jats:title>Abstract</jats:title><jats:p>Konzeptionelle \u00dcberlegungen zu und mechanistische Aspekte von vier scheinbar einfachen chemischen Umsetzungen, die in der Chemie von Methan von Bedeutung sind, werden in diesem Aufsatz behandelt: 1)\u2005die metallvermittelte Dehydrierung unter Bildung von Metallcarbenkomplexen, 2)\u2005die Wasserstoffabstraktion als Schl\u00fcsselschritt der oxidativen Dimerisierung von Methan, 3)\u2005der Mechanismus der CH<jats:sub>4</jats:sub>\u2192CH<jats:sub>3</jats:sub>OH\u2010Umwandlung, und 4)\u2005die Reihenfolge der C\u2010H\u2010 und O\u2010H\u2010Bindungsaktivierung und die Frage nach dem geschwindigkeitsbestimmenden Schritt in der selektiven Oxidation von Methanol zu Formaldehyd. Moderne Gasphasenexperimente, in Verbindung mit Elektronenstrukturrechnungen, liefern Einblicke in elementare Reaktionsschritte auf molekularer Ebene und enth\u00fcllen reaktionsmechanistische Details. Die Ergebnisse dieser Untersuchungen werden, wo dies angebracht erscheint, mit Beobachtungen aus entsprechenden Studien in L\u00f6sung oder auf Oberfl\u00e4chen verglichen.</jats:p>",
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