DOI: 10.1002/ange.200802659. Molekulare Katalysatoren für die Oxidation von Wasser zu Disauerstoff

Molekulare Katalysatoren für die Oxidation von Wasser zu Disauerstoff

10.1002/ange.200802659

Crossref journal-article

Wiley

Angewandte Chemie (311)

Abstract

AbstractWasseroxidation: Ein guter Katalysator für die Umsetzung von Wasser zu Sauerstoff ist für die nachhaltige Umwandlung von Sonnenenergie essenziell. Die Schlüsselfaktoren für die Leistungsfähigkeit erfolgreicher molekularer Katalysatoren und die Notwendigkeit für ein katalytisches System auf Festkörperbasis werden erläutert, und die ersten Versuche, molekulare Katalysatoren für die Wasseroxidation auf Trägermaterial herzustellen, werden analysiert.magnified imageIn den letzten vier Jahren wurden wir Zeugen einer Revolution auf dem Gebiet der katalytischen Wasseroxidation: Definierte Moleküle eröffnen neue Möglichkeiten, robustere und effizientere Katalysatoren maßzuschneidern. Angestoßen wurde diese Revolution durch zwei Faktoren: den dringenden Bedarf an sauberen und erneuerbaren Kraftstoffen und das dem Menschen innewohnende Verlangen, die Reaktionen der Natur nachzuahmen – in diesem Fall die des sauerstofferzeugenden Komplexes (OEC) des Photosystems II (PSII). Im Folgenden geben wir einen kurzen Überblick über die wohlbekannten Grundlagen der Oxidation von Wasser zu Disauerstoff und präsentieren anschließend die neuen Entwicklungen auf diesem Forschungsfeld, die neuen Ansätze, Katalysatordesign und ‐leistung zu verbessern, und die Fragen, die diese Entwicklungen insbesondere aus mechanistischer Sicht aufwerfen. Schließlich werden wir noch die Herausforderungen diskutieren, denen sich das Forschungsfeld gegenübersieht.

Bibliography

Sala, X., Romero, I., RodrÃguez, M., Escriche, L., & Llobet, A. (2009). Molekulare Katalysatoren fÃ¼r die Oxidation von Wasser zu Disauerstoff. Angewandte Chemie, 121(16), 2882â2893. Portico.

Authors 5

Xavier Sala (first)
Isabel Romero (additional)
Montserrat Rodríguez (additional)
Lluís Escriche (additional)
Antoni Llobet (additional)

References 107 Referenced 108

10.1021/ic800155g
10.1016/j.ccr.2007.09.002
10.1038/35104607
10.1038/452400a
10.1016/j.ccr.2007.07.021
10.1146/annurev.physchem.55.091602.094446
10.1021/cr0500030
10.1002/ange.200600917
10.1002/anie.200600917
10.1111/j.1751-1097.1970.tb06017.x
10.1016/j.bbabio.2007.02.022
10.1126/science.1093087
10.1126/science.1096767
10.1126/science.1128186
10.1021/cr0204294
10.1021/ct060018l
10.1038/nature04224
10.1126/science.1117551
10.1021/ic020731v
10.1016/j.molcata.2006.02.008
10.1016/0020-1693(94)03963-1
10.1021/ic010064q
10.1021/ja00400a083
10.1021/ja00027a025
10.1021/ic035298j
10.1002/ejic.200300137
10.1021/ja0528230
10.1021/ja057733
10.1021/ja00378a053
10.1021/ja00299a017
10.1002/9780470125793.ch8
Quantum CAChe version 6.1.12.33 Fujitsu Ltd. Kanagawa Japan 1999.
10.1021/ic00315a013
10.1021/ic00222a008
10.1149/1.2221205
10.1016/0022-0728(94)03578-Q
10.1021/ja00256a010
10.1039/c39880000872
10.1021/ic970908z
10.1021/ic00292a008
10.1021/ja00267a019
10.1021/ja068630
10.1021/ja0495821
10.1021/ic700911y
10.1021/ic00344a048
10.1021/ic970393b
10.1021/ja993235n
10.1021/ic00032a017
10.1021/ic00098a010
10.1016/0020-1693(94)04085-0
10.1021/ja993914y
10.1021/ja010594l
10.1021/ja030594g
10.1021/ja0462427
10.1021/ja053710j
{'key': 'e_1_2_12_67_2', 'volume-title': 'Essentials of Computational Chemistry', 'author': 'Cramer C. J.', 'year': '2002'} / Essentials of Computational Chemistry by Cramer C. J. (2002)
10.1021/jp066765w
10.1021/ja0486824
10.1021/ic026114o
10.1021/ic0346836
N. Planas X. Sala A. Llobet unveröffentlichte Ergebnisse.
10.1021/ja054791m
10.1021/jo051937r
10.1021/ic7010875
10.1016/0304-5102(90)85039-K
10.1023/A:1018583801694
10.1002/(SICI)1521-3757(20000417)112:8<1539::AID-ANGE1539>3.0.CO;2-Y
10.1002/(SICI)1521-3773(20000417)39:8<1479::AID-ANIE1479>3.0.CO;2-4
10.1021/ja074478f
10.1021/ic00292a008
{'key': 'e_1_2_12_84_2', 'first-page': '1300', 'volume-title': 'Chemistry of the Elements', 'author': 'Greenwood N. N.', 'year': '1984'} / Chemistry of the Elements by Greenwood N. N. (1984)
10.1021/ja077837f
10.1002/ange.200705652
10.1002/anie.200705652
10.1021/ic9711271
10.1021/ic00296a049
10.1016/S1381-1169(98)00334-3
10.1021/cr980108l
10.1021/ja068630
10.1021/ar00163a004
10.1002/ange.200704912
10.1002/anie.200704912
10.1002/1521-4095(20020605)14:11<826::AID-ADMA826>3.0.CO;2-C
{'key': 'e_1_2_12_99_2', 'volume': '556', 'author': 'Llop J.', 'year': '2003', 'journal-title': 'Dalton Trans.'} / Dalton Trans. by Llop J. (2003)
10.1021/cr941154y
10.1021/ar50023a001
10.1126/science.1162018

Dates

Type	When
Created	16 years, 7 months ago (Jan. 22, 2009, 8:22 a.m.)
Deposited	1 year, 10 months ago (Oct. 16, 2023, 7:13 p.m.)
Indexed	3 months, 2 weeks ago (May 15, 2025, 8:03 p.m.)
Issued	16 years, 5 months ago (March 30, 2009)
Published	16 years, 5 months ago (March 30, 2009)
Published Online	16 years, 5 months ago (March 30, 2009)
Published Print	16 years, 4 months ago (April 6, 2009)

Funders 0

None

BibTeX

@article{Sala_2009, title={Molekulare Katalysatoren für die Oxidation von Wasser zu Disauerstoff}, volume={121}, ISSN={1521-3757}, url={http://dx.doi.org/10.1002/ange.200802659}, DOI={10.1002/ange.200802659}, number={16}, journal={Angewandte Chemie}, publisher={Wiley}, author={Sala, Xavier and Romero, Isabel and Rodríguez, Montserrat and Escriche, Lluís and Llobet, Antoni}, year={2009}, month=mar, pages={2882–2893} }

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