DOI: 10.1002/ange.19961081930. Hydroformylierungskatalyse: In‐situ‐Charakterisierung eines zweikernigen Dihydridorhodium(<scp>II</scp>)‐Komplexes mit der bisher größten gemessenen Rh‐H‐NMR‐Kopplungskonstante

Hydroformylierungskatalyse: In‐situ‐Charakterisierung eines zweikernigen Dihydridorhodium(II)‐Komplexes mit der bisher größten gemessenen Rh‐H‐NMR‐Kopplungskonstante

10.1002/ange.19961081930

Crossref journal-article

Wiley

Angewandte Chemie (311)

Abstract

Der katalytisch aktive Komplex der homogen katalysierten, regioselektiven Hydroformylierung ist möglicherweise das zweikernige Komplex‐Dikation 1. Bemerkenswert ist die 1J(Rh,H)‐Kopplungskonstante von 164 Hz, die als typisch für zweikernige RhII‐Komplexe mit terminalen Hydridoliganden angesehen werden kann.magnified image

Bibliography

Matthews, R. C., Howell, D. K., Peng, W., Train, S. G., Dale Treleaven, W., & Stanley, G. G. (1996). Hydroformylierungskatalyse: InâsituâCharakterisierung eines zweikernigen Dihydridorhodium(II)âKomplexes mit der bisher grÃ¶Ãten gemessenen RhâHâNMRâKopplungskonstante. Angewandte Chemie, 108(19), 2402â2405. Portico.

Authors 6

Rhonda C. Matthews (first)
Donna K. Howell (additional)
Wei‐Jun Peng (additional)
Spencer G. Train (additional)
W. Dale Treleaven (additional)
George G. Stanley (additional)

References 39 Referenced 18

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g)G.Suss‐Fink G.Herrmann J. Chem. Soc. Chem. Commun.1985 735. (10.1039/C39850000735)
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10.1021/om00094a026
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In anderen FT‐IR‐Spektren ist die Aufspaltung der Bande für das verbrückende CO‐Molekül deutlicher zu erkennen.
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Diese Kopplung wurde bei unterschiedlichen1H‐NMR‐Frequenzen (250 300 400 und 500 MHz). bei unterschiedlichen Temperaturen (– 20 bis +60°C) und sowohl durch Breitband‐ als auch durch selektive31P‐Entkopplungsexperimente bestätigt. Ein1H‐NMR‐Experiment mit103Rh‐Entkopplung konnten wir noch nicht durchführen.
10.1021/om00016a013
10.1021/ja00408a039

Dates

Type	When
Created	18 years, 1 month ago (July 16, 2007, 10:24 a.m.)
Deposited	1 year, 10 months ago (Oct. 31, 2023, 8:36 a.m.)
Indexed	1 year, 10 months ago (Nov. 1, 2023, 3:37 a.m.)
Issued	28 years, 11 months ago (Oct. 7, 1996)
Published	28 years, 11 months ago (Oct. 7, 1996)
Published Online	19 years, 7 months ago (Jan. 31, 2006)
Published Print	28 years, 11 months ago (Oct. 7, 1996)

Funders 0

None

BibTeX

@article{Matthews_1996, title={Hydroformylierungskatalyse: In‐situ‐Charakterisierung eines zweikernigen Dihydridorhodium(<scp>II</scp>)‐Komplexes mit der bisher größten gemessenen Rh‐H‐NMR‐Kopplungskonstante}, volume={108}, ISSN={1521-3757}, url={http://dx.doi.org/10.1002/ange.19961081930}, DOI={10.1002/ange.19961081930}, number={19}, journal={Angewandte Chemie}, publisher={Wiley}, author={Matthews, Rhonda C. and Howell, Donna K. and Peng, Wei‐Jun and Train, Spencer G. and Dale Treleaven, W. and Stanley, George G.}, year={1996}, month=oct, pages={2402–2405} }

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